Organic electroluminescent materials and devices

ABSTRACT

A compound including a ligand LA of Formula Iis disclosed.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Application No. 62/680,283, filed Jun. 4, 2018, and U.S.Provisional Application No. 62/683,797, filed Jun. 12, 2018, the entirecontents of which are incorporated herein by reference.

FIELD

The present invention relates to compounds for use as emitters, anddevices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becomingincreasingly desirable for a number of reasons. Many of the materialsused to make such devices are relatively inexpensive, so organicopto-electronic devices have the potential for cost advantages overinorganic devices. In addition, the inherent properties of organicmaterials, such as their flexibility, may make them well suited forparticular applications such as fabrication on a flexible substrate.Examples of organic opto-electronic devices include organic lightemitting diodes/devices (OLEDs), organic phototransistors, organicphotovoltaic cells, and organic photodetectors. For OLEDs, the organicmaterials may have performance advantages over conventional materials.For example, the wavelength at which an organic emissive layer emitslight may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage isapplied across the device. OLEDs are becoming an increasinglyinteresting technology for use in applications such as flat paneldisplays, illumination, and backlighting. Several OLED materials andconfigurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full colordisplay. Industry standards for such a display call for pixels adaptedto emit particular colors, referred to as “saturated” colors. Inparticular, these standards call for saturated red, green, and bluepixels. Alternatively the OLED can be designed to emit white light. Inconventional liquid crystal displays emission from a white backlight isfiltered using absorption filters to produce red, green and blueemission. The same technique can also be used with OLEDs. The white OLEDcan be either a single EML device or a stack structure. Color may bemeasured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine)iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond fromnitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as wellas small molecule organic materials that may be used to fabricateorganic opto-electronic devices. “Small molecule” refers to any organicmaterial that is not a polymer, and “small molecules” may actually bequite large. Small molecules may include repeat units in somecircumstances. For example, using a long chain alkyl group as asubstituent does not remove a molecule from the “small molecule” class.Small molecules may also be incorporated into polymers, for example as apendent group on a polymer backbone or as a part of the backbone. Smallmolecules may also serve as the core moiety of a dendrimer, whichconsists of a series of chemical shells built on the core moiety. Thecore moiety of a dendrimer may be a fluorescent or phosphorescent smallmolecule emitter. A dendrimer may be a “small molecule,” and it isbelieved that all dendrimers currently used in the field of OLEDs aresmall molecules.

As used herein, “top” means furthest away from the substrate, while“bottom” means closest to the substrate. Where a first layer isdescribed as “disposed over” a second layer, the first layer is disposedfurther away from substrate. There may be other layers between the firstand second layer, unless it is specified that the first layer is “incontact with” the second layer. For example, a cathode may be describedas “disposed over” an anode, even though there are various organiclayers in between.

As used herein, “solution processible” means capable of being dissolved,dispersed, or transported in and/or deposited from a liquid medium,either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed thatthe ligand directly contributes to the photoactive properties of anemissive material. A ligand may be referred to as “ancillary” when it isbelieved that the ligand does not contribute to the photoactiveproperties of an emissive material, although an ancillary ligand mayalter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled inthe art, a first “Highest Occupied Molecular Orbital” (HOMO) or “LowestUnoccupied Molecular Orbital” (LUMO) energy level is “greater than” or“higher than” a second HOMO or LUMO energy level if the first energylevel is closer to the vacuum energy level. Since ionization potentials(IP) are measured as a negative energy relative to a vacuum level, ahigher HOMO energy level corresponds to an IP having a smaller absolutevalue (an IP that is less negative). Similarly, a higher LUMO energylevel corresponds to an electron affinity (EA) having a smaller absolutevalue (an EA that is less negative). On a conventional energy leveldiagram, with the vacuum level at the top, the LUMO energy level of amaterial is higher than the HOMO energy level of the same material. A“higher” HOMO or LUMO energy level appears closer to the top of such adiagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled inthe art, a first work function is “greater than” or “higher than” asecond work function if the first work function has a higher absolutevalue. Because work functions are generally measured as negative numbersrelative to vacuum level, this means that a “higher” work function ismore negative. On a conventional energy level diagram, with the vacuumlevel at the top, a “higher” work function is illustrated as furtheraway from the vacuum level in the downward direction. Thus, thedefinitions of HOMO and LUMO energy levels follow a different conventionthan work functions.

More details on OLEDs, and the definitions described above, can be foundin U.S. Pat. No. 7,279,704, which is incorporated herein by reference inits entirety.

SUMMARY

Disclosed herein is a novel transition metal compound having a firstligand with a unique configuration of fused rings that makes thecompound useful as emitters in OLEDs. A compound comprising a firstligand L_(A) of Formula I

is disclosed. In Formula I, X¹ to X⁸ are each independently C or N,where no more than two N atoms are bonded to each other. At least onepair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and isjoined to a structure G of Formula II

where A is selected from the group consisting of C(CH₃)₂, O, S, Se, andNR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independentlyhydrogen or a substituent selected from the group consisting of thegeneral substituents defined above. Any two substituents may be joinedor fused together to form a ring. The ligand L_(A) is complexed to ametal M. M is optionally coordinated to other ligands. The ligand L_(A)is optionally linked with other ligands to comprise a tridentate,tetradentate, pentadentate, or hexadentate ligand.

An OLED comprising the compound of the present disclosure in an organiclayer therein is also disclosed.

A consumer product comprising the OLED is also disclosed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does nothave a separate electron transport layer.

FIG. 3 shows a plot of the photoluminescence spectrum of an inventiveexample Compound A in PMMA film.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed betweenand electrically connected to an anode and a cathode. When a current isapplied, the anode injects holes and the cathode injects electrons intothe organic layer(s). The injected holes and electrons each migratetoward the oppositely charged electrode. When an electron and holelocalize on the same molecule, an “exciton,” which is a localizedelectron-hole pair having an excited energy state, is formed. Light isemitted when the exciton relaxes via a photoemissive mechanism. In somecases, the exciton may be localized on an excimer or an exciplex.Non-radiative mechanisms, such as thermal relaxation, may also occur,but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from theirsinglet states (“fluorescence”) as disclosed, for example, in U.S. Pat.No. 4,769,292, which is incorporated by reference in its entirety.Fluorescent emission generally occurs in a time frame of less than 10nanoseconds.

More recently, OLEDs having emissive materials that emit light fromtriplet states (“phosphorescence”) have been demonstrated. Baldo et al.,“Highly Efficient Phosphorescent Emission from OrganicElectroluminescent Devices,” Nature, vol. 395, 151-154, 1998;(“Baldo-I”) and Baldo et al., “Very high-efficiency green organiclight-emitting devices based on electrophosphorescence,” Appl. Phys.Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated byreference in their entireties. Phosphorescence is described in moredetail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporatedby reference.

FIG. 1 shows an organic light emitting device 100. The figures are notnecessarily drawn to scale. Device 100 may include a substrate 110, ananode 115, a hole injection layer 120, a hole transport layer 125, anelectron blocking layer 130, an emissive layer 135, a hole blockinglayer 140, an electron transport layer 145, an electron injection layer150, a protective layer 155, a cathode 160, and a barrier layer 170.Cathode 160 is a compound cathode having a first conductive layer 162and a second conductive layer 164. Device 100 may be fabricated bydepositing the layers described, in order. The properties and functionsof these various layers, as well as example materials, are described inmore detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which areincorporated by reference.

More examples for each of these layers are available. For example, aflexible and transparent substrate-anode combination is disclosed inU.S. Pat. No. 5,844,363, which is incorporated by reference in itsentirety. An example of a p-doped hole transport layer is m-MTDATA dopedwith F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. PatentApplication Publication No. 2003/0230980, which is incorporated byreference in its entirety. Examples of emissive and host materials aredisclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which isincorporated by reference in its entirety. An example of an n-dopedelectron transport layer is BPhen doped with Li at a molar ratio of 1:1,as disclosed in U.S. Patent Application Publication No. 2003/0230980,which is incorporated by reference in its entirety. U.S. Pat. Nos.5,703,436 and 5,707,745, which are incorporated by reference in theirentireties, disclose examples of cathodes including compound cathodeshaving a thin layer of metal such as Mg:Ag with an overlyingtransparent, electrically-conductive, sputter-deposited ITO layer. Thetheory and use of blocking layers is described in more detail in U.S.Pat. No. 6,097,147 and U.S. Patent Application Publication No.2003/0230980, which are incorporated by reference in their entireties.Examples of injection layers are provided in U.S. Patent ApplicationPublication No. 2004/0174116, which is incorporated by reference in itsentirety. A description of protective layers may be found in U.S. PatentApplication Publication No. 2004/0174116, which is incorporated byreference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210,a cathode 215, an emissive layer 220, a hole transport layer 225, and ananode 230. Device 200 may be fabricated by depositing the layersdescribed, in order. Because the most common OLED configuration has acathode disposed over the anode, and device 200 has cathode 215 disposedunder anode 230, device 200 may be referred to as an “inverted” OLED.Materials similar to those described with respect to device 100 may beused in the corresponding layers of device 200. FIG. 2 provides oneexample of how some layers may be omitted from the structure of device100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided byway of non-limiting example, and it is understood that embodiments ofthe invention may be used in connection with a wide variety of otherstructures. The specific materials and structures described areexemplary in nature, and other materials and structures may be used.Functional OLEDs may be achieved by combining the various layersdescribed in different ways, or layers may be omitted entirely, based ondesign, performance, and cost factors. Other layers not specificallydescribed may also be included. Materials other than those specificallydescribed may be used. Although many of the examples provided hereindescribe various layers as comprising a single material, it isunderstood that combinations of materials, such as a mixture of host anddopant, or more generally a mixture, may be used. Also, the layers mayhave various sublayers. The names given to the various layers herein arenot intended to be strictly limiting. For example, in device 200, holetransport layer 225 transports holes and injects holes into emissivelayer 220, and may be described as a hole transport layer or a holeinjection layer. In one embodiment, an OLED may be described as havingan “organic layer” disposed between a cathode and an anode. This organiclayer may comprise a single layer, or may further comprise multiplelayers of different organic materials as described, for example, withrespect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used,such as OLEDs comprised of polymeric materials (PLEDs) such as disclosedin U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated byreference in its entirety. By way of further example, OLEDs having asingle organic layer may be used. OLEDs may be stacked, for example asdescribed in U.S. Pat. No. 5,707,745 to Forrest et al, which isincorporated by reference in its entirety. The OLED structure maydeviate from the simple layered structure illustrated in FIGS. 1 and 2.For example, the substrate may include an angled reflective surface toimprove out-coupling, such as a mesa structure as described in U.S. Pat.No. 6,091,195 to Forrest et al., and/or a pit structure as described inU.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated byreference in their entireties.

Unless otherwise specified, any of the layers of the various embodimentsmay be deposited by any suitable method. For the organic layers,preferred methods include thermal evaporation, ink-jet, such asdescribed in U.S. Pat. Nos. 6,013,982 and 6,087,196, which areincorporated by reference in their entireties, organic vapor phasedeposition (OVPD), such as described in U.S. Pat. No. 6,337,102 toForrest et al., which is incorporated by reference in its entirety, anddeposition by organic vapor jet printing (OVJP), such as described inU.S. Pat. No. 7,431,968, which is incorporated by reference in itsentirety. Other suitable deposition methods include spin coating andother solution based processes. Solution based processes are preferablycarried out in nitrogen or an inert atmosphere. For the other layers,preferred methods include thermal evaporation. Preferred patterningmethods include deposition through a mask, cold welding such asdescribed in U.S. Pat. Nos. 6,294,398 and 6,468,819, which areincorporated by reference in their entireties, and patterning associatedwith some of the deposition methods such as ink-jet and organic vaporjet printing (OVJP). Other methods may also be used. The materials to bedeposited may be modified to make them compatible with a particulardeposition method. For example, substituents such as alkyl and arylgroups, branched or unbranched, and preferably containing at least 3carbons, may be used in small molecules to enhance their ability toundergo solution processing. Substituents having 20 carbons or more maybe used, and 3-20 carbons is a preferred range. Materials withasymmetric structures may have better solution processibility than thosehaving symmetric structures, because asymmetric materials may have alower tendency to recrystallize. Dendrimer substituents may be used toenhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the presentinvention may further optionally comprise a barrier layer. One purposeof the barrier layer is to protect the electrodes and organic layersfrom damaging exposure to harmful species in the environment includingmoisture, vapor and/or gases, etc. The barrier layer may be depositedover, under or next to a substrate, an electrode, or over any otherparts of a device including an edge. The barrier layer may comprise asingle layer, or multiple layers. The barrier layer may be formed byvarious known chemical vapor deposition techniques and may includecompositions having a single phase as well as compositions havingmultiple phases. Any suitable material or combination of materials maybe used for the barrier layer. The barrier layer may incorporate aninorganic or an organic compound or both. The preferred barrier layercomprises a mixture of a polymeric material and a non-polymeric materialas described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos.PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporatedby reference in their entireties. To be considered a “mixture”, theaforesaid polymeric and non-polymeric materials comprising the barrierlayer should be deposited under the same reaction conditions and/or atthe same time. The weight ratio of polymeric to non-polymeric materialmay be in the range of 95:5 to 5:95. The polymeric material and thenon-polymeric material may be created from the same precursor material.In one example, the mixture of a polymeric material and a non-polymericmaterial consists essentially of polymeric silicon and inorganicsilicon.

Devices fabricated in accordance with embodiments of the invention canbe incorporated into a wide variety of electronic component modules (orunits) that can be incorporated into a variety of electronic products orintermediate components. Examples of such electronic products orintermediate components include display screens, lighting devices suchas discrete light source devices or lighting panels, etc. that can beutilized by the end-user product manufacturers. Such electroniccomponent modules can optionally include the driving electronics and/orpower source(s). Devices fabricated in accordance with embodiments ofthe invention can be incorporated into a wide variety of consumerproducts that have one or more of the electronic component modules (orunits) incorporated therein. A consumer product comprising an OLED thatincludes the compound of the present disclosure in the organic layer inthe OLED is disclosed. Such consumer products would include any kind ofproducts that include one or more light source(s) and/or one or more ofsome type of visual displays. Some examples of such consumer productsinclude flat panel displays, curved displays, computer monitors, medicalmonitors, televisions, billboards, lights for interior or exteriorillumination and/or signaling, heads-up displays, fully or partiallytransparent displays, flexible displays, rollable displays, foldabledisplays, stretchable displays, laser printers, telephones, mobilephones, tablets, phablets, personal digital assistants (PDAs), wearabledevices, laptop computers, digital cameras, camcorders, viewfinders,micro-displays (displays that are less than 2 inches diagonal), 3-Ddisplays, virtual reality or augmented reality displays, vehicles, videowalls comprising multiple displays tiled together, theater or stadiumscreen, a light therapy device, and a sign. Various control mechanismsmay be used to control devices fabricated in accordance with the presentinvention, including passive matrix and active matrix. Many of thedevices are intended for use in a temperature range comfortable tohumans, such as 18 degrees C. to 30 degrees C., and more preferably atroom temperature (20-25 degrees C.), but could be used outside thistemperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications indevices other than OLEDs. For example, other optoelectronic devices suchas organic solar cells and organic photodetectors may employ thematerials and structures. More generally, organic devices, such asorganic transistors, may employ the materials and structures.

The terms “halo,” “halogen,” and “halide” are used interchangeably andrefer to fluorine, chlorine, bromine, and iodine.

The term “acyl” refers to a substituted carbonyl radical (C(O)—R_(s)).

The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R_(s) or—C(O)—O—R_(s)) radical.

The term “ether” refers to an —OR_(s) radical.

The terms “sulfanyl” or “thio-ether” are used interchangeably and referto a —SR_(s) radical.

The term “sulfinyl” refers to a —S(O)—R_(s) radical.

The term “sulfonyl” refers to a —SO₂—R_(s) radical.

The term “phosphino” refers to a —P(R_(s))₃ radical, wherein each R_(s)can be same or different.

The term “silyl” refers to a —Si(R_(s))₃ radical, wherein each R_(s) canbe same or different.

In each of the above, R_(s) can be hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, andcombination thereof. Preferred R_(s) is selected from the groupconsisting of alkyl, cycloalkyl, aryl, heteroaryl, and combinationthereof.

The term “alkyl” refers to and includes both straight and branched chainalkyl radicals. Preferred alkyl groups are those containing from one tofifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl,butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl,2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl,2,2-dimethylpropyl, and the like. Additionally, the alkyl group isoptionally substituted.

The term “cycloalkyl” refers to and includes monocyclic, polycyclic, andspiro alkyl radicals. Preferred cycloalkyl groups are those containing 3to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl,cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl,adamantyl, and the like. Additionally, the cycloalkyl group isoptionally substituted.

The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or acycloalkyl radical, respectively, having at least one carbon atomreplaced by a heteroatom. Optionally the at least one heteroatom isselected from O, S, N, P, B, Si and Se, preferably, O, S or N.Additionally, the heteroalkyl or heterocycloalkyl group is optionallysubstituted.

The term “alkenyl” refers to and includes both straight and branchedchain alkene radicals. Alkenyl groups are essentially alkyl groups thatinclude at least one carbon-carbon double bond in the alkyl chain.Cycloalkenyl groups are essentially cycloalkyl groups that include atleast one carbon-carbon double bond in the cycloalkyl ring. The term“heteroalkenyl” as used herein refers to an alkenyl radical having atleast one carbon atom replaced by a heteroatom. Optionally the at leastone heteroatom is selected from O, S, N, P, B, Si, and Se, preferably,O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups arethose containing two to fifteen carbon atoms. Additionally, the alkenyl,cycloalkenyl, or heteroalkenyl group is optionally substituted.

The term “alkynyl” refers to and includes both straight and branchedchain alkyne radicals. Preferred alkynyl groups are those containing twoto fifteen carbon atoms. Additionally, the alkynyl group is optionallysubstituted.

The terms “aralkyl” or “arylalkyl” are used interchangeably and refer toan alkyl group that is substituted with an aryl group. Additionally, thearalkyl group is optionally substituted.

The term “heterocyclic group” refers to and includes aromatic andnon-aromatic cyclic radicals containing at least one heteroatom.Optionally the at least one heteroatom is selected from O, S, N, P, B,Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals maybe used interchangeably with heteroaryl. Preferred hetero-non-aromaticcyclic groups are those containing 3 to 7 ring atoms which includes atleast one hetero atom, and includes cyclic amines such as morpholino,piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers,such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and thelike. Additionally, the heterocyclic group may be optionallysubstituted.

The term “aryl” refers to and includes both single-ring aromatichydrocarbyl groups and polycyclic aromatic ring systems. The polycyclicrings may have two or more rings in which two carbons are common to twoadjoining rings (the rings are “fused”) wherein at least one of therings is an aromatic hydrocarbyl group, e.g., the other rings can becycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.Preferred aryl groups are those containing six to thirty carbon atoms,preferably six to twenty carbon atoms, more preferably six to twelvecarbon atoms. Especially preferred is an aryl group having six carbons,ten carbons or twelve carbons. Suitable aryl groups include phenyl,biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene,anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene,perylene, and azulene, preferably phenyl, biphenyl, triphenyl,triphenylene, fluorene, and naphthalene. Additionally, the aryl group isoptionally substituted.

The term “heteroaryl” refers to and includes both single-ring aromaticgroups and polycyclic aromatic ring systems that include at least oneheteroatom. The heteroatoms include, but are not limited to O, S, N, P,B, Si, and Se. In many instances, O, S, or N are the preferredheteroatoms. Hetero-single ring aromatic systems are preferably singlerings with 5 or 6 ring atoms, and the ring can have from one to sixheteroatoms. The hetero-polycyclic ring systems can have two or morerings in which two atoms are common to two adjoining rings (the ringsare “fused”) wherein at least one of the rings is a heteroaryl, e.g.,the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles,and/or heteroaryls. The hetero-polycyclic aromatic ring systems can havefrom one to six heteroatoms per ring of the polycyclic aromatic ringsystem. Preferred heteroaryl groups are those containing three to thirtycarbon atoms, preferably three to twenty carbon atoms, more preferablythree to twelve carbon atoms. Suitable heteroaryl groups includedibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene,benzofuran, benzothiophene, benzoselenophene, carbazole,indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole,triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole,thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine,oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole,indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline,isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine,phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine,phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine,preferably dibenzothiophene, dibenzofuran, dibenzoselenophene,carbazole, indolocarbazole, imidazole, pyridine, triazine,benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine,and aza-analogs thereof. Additionally, the heteroaryl group isoptionally substituted.

Of the aryl and heteroaryl groups listed above, the groups oftriphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran,dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine,pyrazine, pyrimidine, triazine, and benzimidazole, and the respectiveaza-analogs of each thereof are of particular interest.

The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl,and heteroaryl, as used herein, are independently unsubstituted, orindependently substituted, with one or more general substituents.

In many instances, the general substituents are selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, andcombinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy,aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinationsthereof.

In yet other instances, the more preferred general substituents areselected from the group consisting of deuterium, fluorine, alkyl,cycloalkyl, aryl, heteroaryl, and combinations thereof.

The terms “substituted” and “substitution” refer to a substituent otherthan H that is bonded to the relevant position, e.g., a carbon ornitrogen. For example, when R¹ represents mono-substitution, then one R¹must be other than H (i.e., a substitution). Similarly, when R¹represents di-substitution, then two of R¹ must be other than H.Similarly, when R¹ represents no substitution, R¹, for example, can be ahydrogen for available valencies of ring atoms, as in carbon atoms forbenzene and the nitrogen atom in pyrrole, or simply represents nothingfor ring atoms with fully filled valencies, e.g., the nitrogen atom inpyridine. The maximum number of substitutions possible in a ringstructure will depend on the total number of available valencies in thering atoms.

As used herein, “combinations thereof” indicates that one or moremembers of the applicable list are combined to form a known orchemically stable arrangement that one of ordinary skill in the art canenvision from the applicable list. For example, an alkyl and deuteriumcan be combined to form a partial or fully deuterated alkyl group; ahalogen and alkyl can be combined to form a halogenated alkylsubstituent; and a halogen, alkyl, and aryl can be combined to form ahalogenated arylalkyl. In one instance, the term substitution includes acombination of two to four of the listed groups. In another instance,the term substitution includes a combination of two to three groups. Inyet another instance, the term substitution includes a combination oftwo groups. Preferred combinations of substituent groups are those thatcontain up to fifty atoms that are not hydrogen or deuterium, or thosewhich include up to forty atoms that are not hydrogen or deuterium, orthose that include up to thirty atoms that are not hydrogen ordeuterium. In many instances, a preferred combination of substituentgroups will include up to twenty atoms that are not hydrogen ordeuterium.

The “aza” designation in the fragments described herein, i.e.aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more ofthe C—H groups in the respective aromatic ring can be replaced by anitrogen atom, for example, and without any limitation, azatriphenyleneencompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. Oneof ordinary skill in the art can readily envision other nitrogen analogsof the aza-derivatives described above, and all such analogs areintended to be encompassed by the terms as set forth herein.

As used herein, “deuterium” refers to an isotope of hydrogen. Deuteratedcompounds can be readily prepared using methods known in the art. Forexample, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, andU.S. Pat. Application Pub. No. US 2011/0037057, which are herebyincorporated by reference in their entireties, describe the making ofdeuterium-substituted organometallic complexes. Further reference ismade to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt etal., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which areincorporated by reference in their entireties, describe the deuterationof the methylene hydrogens in benzyl amines and efficient pathways toreplace aromatic ring hydrogens with deuterium, respectively.

It is to be understood that when a molecular fragment is described asbeing a substituent or otherwise attached to another moiety, its namemay be written as if it were a fragment (e.g. phenyl, phenylene,naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g.benzene, naphthalene, dibenzofuran). As used herein, these differentways of designating a substituent or attached fragment are considered tobe equivalent.

In some instance, a pair of adjacent substituents can be optionallyjoined or fused into a ring. The preferred ring is a five, six, orseven-membered carbocyclic or heterocyclic ring, includes both instanceswhere the portion of the ring formed by the pair of substituents issaturated and where the portion of the ring formed by the pair ofsubstituents is unsaturated. As used herein, “adjacent” means that thetwo substituents involved can be on the same ring next to each other, oron two neighboring rings having the two closest available substitutablepositions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in anaphthalene, as long as they can form a stable fused ring system.

According to an embodiment, a compound comprising a first ligand L_(A)of Formula I

is disclosed. In Formula I, X¹ to X⁸ are each independently C or N,where no more than two N atoms are bonded to each other. At least onepair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and isjoined to a structure G of Formula II

where A is selected from the group consisting of C(CH₃)₂, O, S, Se, andNR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independentlyhydrogen or a substituent selected from the group consisting of thegeneral substituents defined above. Any two substituents may be joinedor fused together to form a ring. The ligand L_(A) is complexed to ametal M. M is optionally coordinated to other ligands. The ligand L_(A)is optionally linked with other ligands to comprise a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In some embodiments, each R^(A), R^(B), R^(C), and R^(D) isindependently selected from the group consisting of the preferredgeneral substituents defined above.

In some embodiments, X¹ to X⁸ are each C. In some embodiments, at leastone of X¹ to X⁸ is N.

In some embodiments, A in Formula II is O or S.

In some embodiments, M is selected from the group consisting of Ru, Os,Pd, Pt, Ir, Cu, and Au. In some embodiments, M is Ir or Pt. Preferably,Ir is Ir(III) and Pt is Pt(I).

In some embodiments where M is selected from the group consisting of Ru,Os, Pd, Pt, Ir, Cu, and Au, the compound further comprises a substitutedor unsubstituted acetylacetonate ligand.

In some embodiments, Formula II is substituted or unsubstituted

In some embodiments, only one pair of X¹ and X², X² and X³, X⁶ and X⁷,and X⁷ and X⁸ is C—C, and is joined to the structure G.

In some embodiments, the first ligand L_(A) is of the formula

In some embodiments, the first ligand L_(A) is selected from the groupconsisting of:

where X⁹ to X¹² are each independently C or N; and where no more thantwo N atoms are bonded to each other.

In some embodiments of the compound, the first ligand L_(A) is selectedfrom the group consisting of ligands L_(A1-O) to L_(A384-O), L_(A1-S) toL_(A384-S), L_(A1-C) to L_(A383-C), and L_(A384-C) that are based on thestructure

where the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,

where for ligands L_(A1-O) to L_(A384-O), A in the structure G is O,

where for ligands L_(A1-S) to L_(A384-S), A in the structure G is S,

where for ligands L_(A1-C) to L_(A384-C), A in the structure G isC(CH₃)₂, where X³, R⁶, R⁸, and G are defined for A1 to A384 as shownbelow:

X³ R⁶ R⁸ G A1 CH H H G¹ A2 CH H H G³ A3 CH H H G⁵ A4 CH H H G⁷ A5 CH H HG⁹ A6 CH H H G¹¹ A7 N H H G¹ A8 N H H G³ A9 N H H G⁵ A10 N H H G⁷ A11 NH H G⁹ A12 N H H G¹¹ A13 CR^(B1) H H G¹ A14 CR^(B3) H H G¹ A15 CR^(B5) HH G¹ A16 CR^(B7) H H G¹ A17 CR^(B9) H H G¹ A18 CR^(B11) H H G¹ A19CR^(B13) H H G¹ A20 CR^(B15) H H G¹ A21 CR^(B17) H H G¹ A22 CR^(B19) H HG¹ A23 CR^(B21) H H G¹ A24 CR^(B23) H H G¹ A25 CR^(B25) H H G¹ A26CR^(B27) H H G¹ A27 CR^(B29) H H G¹ A28 CR^(B31) H H G¹ A29 CR^(B33) H HG¹ A30 CR^(B35) H H G¹ A31 CR^(B37) H H G¹ A32 CR^(B39) H H G¹ A33CR^(B41) H H G¹ A34 CR^(B43) H H G¹ A35 CR^(B45) H H G¹ A36 CR^(B47) H HG¹ A37 CR^(B49) H H G¹ A38 CR^(B51) H H G¹ A39 CR^(B53) H H G¹ A40CR^(B55) H H G¹ A41 CR^(B57) H H G¹ A42 CR^(B59) H H G¹ A43 CR^(B1) H HG² A44 CR^(B3) H H G² A45 CR^(B5) H H G² A46 CR^(B7) H H G² A47 CR^(B9)H H G² A48 CR^(B11) H H G² A49 CR^(B13) H H G² A50 CR^(B15) H H G² A51CR^(B17) H H G² A52 CR^(B19) H H G² A53 CR^(B21) H H G² A54 CR^(B23) H HG² A55 CR^(B25) H H G² A56 CR^(B27) H H G² A57 CR^(B29) H H G² A58CR^(B31) H H G² A59 CR^(B33) H H G² A60 CR^(B35) H H G² A61 CR^(B37) H HG² A62 CR^(B39) H H G² A63 CR^(B41) H H G² A64 CR^(B43) H H G² A65CR^(B45) H H G² A66 CR^(B47) H H G² A67 CR^(B49) H H G² A68 CR^(B51) H HG² A69 CR^(B53) H H G² A70 CR^(B55) H H G² A71 CR^(B57) H H G² A72CR^(B59) H H G² A73 CR^(B1) H H G³ A74 CR^(B3) H H G³ A75 CR^(B5) H H G³A76 CR^(B7) H H G³ A77 CR^(B9) H H G³ A78 CR^(B11) H H G³ A79 CR^(B13) HH G³ A80 CR^(B15) H H G³ A81 CR^(B17) H H G³ A82 CR^(B19) H H G³ A83CR^(B21) H H G³ A84 CR^(B23) H H G³ A85 CR^(B25) H H G³ A86 CR^(B27) H HG³ A87 CR^(B29) H H G³ A88 CR^(B31) H H G³ A89 CR^(B33) H H G³ A90CR^(B35) H H G³ A91 CR^(B37) H H G³ A92 CR^(B39) H H G³ A93 CR^(B41) H HG³ A94 CR^(B43) H H G³ A95 CR^(B45) H H G³ A96 CR^(B47) H H G³ A97CR^(B49) H H G³ A98 CR^(B51) H H G³ A99 CR^(B53) H H G³ A100 CR^(B55) HH G³ A101 CR^(B57) H H G³ A102 CR^(B59) H H G³ A103 CR^(B1) H H G⁴ A104CR^(B3) H H G⁴ A105 CR^(B5) H H G⁴ A106 CR^(B7) H H G⁴ A107 CR^(B9) H HG⁴ A108 CR^(B11) H H G⁴ A109 CR^(B13) H H G⁴ A110 CR^(B15) H H G⁴ A111CR^(B17) H H G⁴ A112 CR^(B19) H H G⁴ A113 CR^(B21) H H G⁴ A114 CR^(B23)H H G⁴ A115 CR^(B25) H H G⁴ A116 CR^(B27) H H G⁴ A117 CR^(B29) H H G⁴A118 CR^(B31) H H G⁴ A119 CR^(B33) H H G⁴ A120 CR^(B35) H H G⁴ A121CR^(B37) H H G⁴ A122 CR^(B39) H H G⁴ A123 CR^(B41) H H G⁴ A124 CR^(B43)H H G⁴ A125 CR^(B45) H H G⁴ A126 CR^(B47) H H G⁴ A127 CR^(B49) H H G⁴A128 CR^(B51) H H G⁴ A129 CH H H G² A130 CH H H G⁴ A131 CH H H G⁶ A132CH H H G⁸ A133 CH H H G¹⁰ A134 CH H H G¹² A135 N H H G² A136 N H H G⁴A137 N H H G⁶ A138 N H H G⁸ A139 N H H G¹⁰ A140 N H H G¹² A141 CR^(B2) HH G¹ A142 CR^(B4) H H G¹ A143 CR^(B6) H H G¹ A144 CR^(B8) H H G¹ A145CR^(B10) H H G¹ A146 CR^(B12) H H G¹ A147 CR^(B14) H H G¹ A148 CR^(B16)H H G¹ A149 CR^(B18) H H G¹ A150 CR^(B20) H H G¹ A151 CR^(B22) H H G¹A152 CR^(B24) H H G¹ A153 CR^(B26) H H G¹ A154 CR^(B28) H H G¹ A155CR^(B30) H H G¹ A156 CR^(B32) H H G¹ A157 CR^(B34) H H G¹ A158 CR^(B36)H H G¹ A159 CR^(B38) H H G¹ A160 CR^(B40) H H G¹ A161 CR^(B42) H H G¹A162 CR^(B44) H H G¹ A163 CR^(B46) H H G¹ A164 CR^(B48) H H G¹ A165CR^(B50) H H G¹ A166 CR^(B52) H H G¹ A167 CR^(B54) H H G¹ A168 CR^(B56)H H G¹ A169 CR^(B58) H H G¹ A170 CR^(B60) H H G¹ A171 CR^(B2) H H G²A172 CR^(B4) H H G² A173 CR^(B6) H H G² A174 CR^(B8) H H G² A175CR^(B10) H H G² A176 CR^(B12) H H G² A177 CR^(B14) H H G² A178 CR^(B16)H H G² A179 CR^(B18) H H G² A180 CR^(B20) H H G² A181 CR^(B22) H H G²A182 CR^(B24) H H G² A183 CR^(B26) H H G² A184 CR^(B28) H H G² A185CR^(B30) H H G² A186 CR^(B32) H H G² A187 CR^(B34) H H G² A188 CR^(B36)H H G² A189 CR^(B38) H H G² A190 CR^(B40) H H G² A191 CR^(B42) H H G²A192 CR^(B44) H H G² A193 CR^(B46) H H G² A194 CR^(B48) H H G² A195CR^(B50) H H G² A196 CR^(B52) H H G² A197 CR^(B54) H H G² A198 CR^(B56)H H G² A199 CR^(B58) H H G² A200 CR^(B60) H H G² A201 CR^(B2) H H G³A202 CR^(B4) H H G³ A203 CR^(B6) H H G³ A204 CR^(B8) H H G³ A205CR^(B10) H H G³ A206 CR^(B12) H H G³ A207 CR^(B14) H H G³ A208 CR^(B16)H H G³ A209 CR^(B18) H H G³ A210 CR^(B20) H H G³ A211 CR^(B22) H H G³A212 CR^(B24) H H G³ A213 CR^(B26) H H G³ A214 CR^(B28) H H G³ A215CR^(B30) H H G³ A216 CR^(B32) H H G³ A217 CR^(B34) H H G³ A218 CR^(B36)H H G³ A219 CR^(B38) H H G³ A220 CR^(B40) H H G³ A221 CR^(B42) H H G³A222 CR^(B44) H H G³ A223 CR^(B46) H H G³ 224 CR^(B48) H H G³ A225CR^(B50) H H G³ A226 CR^(B52) H H G³ A227 CR^(B54) H H G³ A228 CR^(B56)H H G³ A229 CR^(B58) H H G³ A230 CR^(B60) H H G³ A231 CR^(B2) H H G⁴A232 CR^(B4) H H G⁴ A233 CR^(B6) H H G⁴ A234 CR^(B8) H H G⁴ A235CR^(B10) H H G⁴ A236 CR^(B12) H H G⁴ A237 CR^(B14) H H G⁴ A238 CR^(B16)H H G⁴ A239 CR^(B18) H H G⁴ A240 CR^(B20) H H G⁴ A241 CR^(B22) H H G⁴A242 CR^(B24) H H G⁴ A243 CR^(B26) H H G⁴ A244 CR^(B28) H H G⁴ A245CR^(B30) H H G⁴ A246 CR^(B32) H H G⁴ A247 CR^(B34) H H G⁴ A248 CR^(B36)H H G⁴ A249 CR^(B38) H H G⁴ A250 CR^(B40) H H G⁴ A251 CR^(B42) H H G⁴A252 CR^(B44) H H G⁴ A253 CR^(B46) H H G⁴ A254 CR^(B48) H H G⁴ A255CR^(B50) H H G⁴ A256 CR^(B52) H H G⁴ A257 CR^(B55) H H G⁴ A258 CR^(B57)H H G⁴ A259 CR^(B59) H H G⁴ A260 CR^(B1) H H G⁵ A261 CR^(B3) H H G⁵ A262CR^(B5) H H G⁵ A263 CR^(B7) H H G⁵ A264 CR^(B9) H H G⁵ A265 CR^(B11) H HG⁵ A266 CR^(B13) H H G⁵ A267 CR^(B15) H H G⁵ A268 CR^(B17) H H G⁵ A269CR^(B19) H H G⁵ A270 CR^(B21) H H G⁵ A271 CR^(B23) H H G⁵ A272 CR^(B25)H H G⁵ A273 CR^(B27) H H G⁵ A274 CR^(B29) H H G⁵ A275 CR^(B31) H H G⁵A276 CR^(B33) H H G⁵ A277 CR^(B35) H H G⁵ A278 CR^(B37) H H G⁵ A279CR^(B39) H H G⁵ A280 CR^(B41) H H G⁵ A281 CR^(B43) H H G⁵ A282 CR^(B45)H H G⁵ A283 CR^(B47) H H G⁵ A284 CR^(B49) H H G⁵ A285 CR^(B51) H H G⁵A286 CR^(B53) H H G⁵ A287 CR^(B55) H H G⁵ A288 CR^(B57) H H G⁵ A289CR^(B59) H H G⁵ A290 CR^(B1) H H G⁶ A291 CR^(B3) H H G⁶ A292 CR^(B5) H HG⁶ A293 CR^(B7) H H G⁶ A294 CR^(B9) H H G⁶ A295 CR^(B11) H H G⁶ A296CR^(B13) H H G⁶ A297 CR^(B15) H H G⁶ A298 CR^(B17) H H G⁶ A299 CR^(B19)H H G⁶ A300 CR^(B21) H H G⁶ A301 CR^(B23) H H G⁶ A302 CR^(B25) H H G⁶A303 CR^(B27) H H G⁶ A304 CR^(B29) H H G⁶ A305 CR^(B31) H H G⁶ A306CR^(B33) H H G⁶ A307 CR^(B35) H H G⁶ A308 CR^(B37) H H G⁶ A309 CR^(B39)H H G⁶ A310 CR^(B41) H H G⁶ A311 CR^(B43) H H G⁶ A312 CR^(B45) H H G⁶A313 CR^(B47) H H G⁶ A314 CR^(B49) H H G⁶ A315 CR^(B51) H H G⁶ A316CR^(B53) H H G⁶ A317 CR^(B55) H H G⁶ A318 CR^(B57) H H G⁶ A319 CR^(B59)H H G⁶ A320 CR^(B56) H H G⁴ A321 CR^(B58) H H G⁴ A322 CR^(B60) H H G⁴A323 CR^(B2) H H G⁵ A324 CR^(B4) H H G⁵ A325 CR^(B6) H H G⁵ A326 CR^(B8)H H G⁵ A327 CR^(B10) H H G⁵ A328 CR^(B12) H H G⁵ A329 CR^(B14) H H G⁵A330 CR^(B16) H H G⁵ A331 CR^(B18) H H G⁵ A332 CR^(B20) H H G⁵ A333CR^(B22) H H G⁵ A334 CR^(B24) H H G⁵ A335 CR^(B26) H H G⁵ A336 CR^(B28)H H G⁵ A337 CR^(B30) H H G⁵ A338 CR^(B32) H H G⁵ A339 CR^(B34) H H G⁵A340 CR^(B36) H H G⁵ A341 CR^(B38) H H G⁵ A342 CR^(B40) H H G⁵ A343CR^(B42) H H G⁵ A344 CR^(B44) H H G⁵ A345 CR^(B46) H H G⁵ A346 CR^(B48)H H G⁵ A347 CR^(B50) H H G⁵ A348 CR^(B52) H H G⁵ A349 CR^(B54) H H G⁵A350 CR^(B56) H H G⁵ A351 CR^(B58) H H G⁵ A352 CR^(B60) H H G⁵ A353CR^(B1) H H G⁶ A354 CR^(B4) H H G⁶ A355 CR^(B7) H H G⁶ A356 CR^(B10) H HG⁶ A357 CR^(B13) H H G⁶ A358 CR^(B16) H H G⁶ A359 CR^(B19) H H G⁶ A360CR^(B22) H H G⁶ A361 CR^(B25) H H G⁶ A362 CR^(B28) H H G⁶ A363 CR^(B31)H H G⁶ A364 CR^(B34) H H G⁶ A365 CR^(B37) H H G⁶ A366 CR^(B40) H H G⁶A367 CR^(B43) H H G⁶ A368 CR^(B46) H H G⁶ A369 CR^(B49) H H G⁶ A370CR^(B52) H H G⁶ A371 CR^(B55) H H G⁶ A372 CR^(B58) H H G⁶ A373 CR^(B61)H H G⁶ A374 CR^(B64) H H G⁶ A375 CR^(B67) H H G⁶ A376 CR^(B70) H H G⁶A377 CR^(B73) H H G⁶ A378 CR^(B76) H H G⁶ A379 CR^(B79) H H G⁶ A380CR^(B82) H H G⁶ A381 CR^(B85) H H G⁶ A382 CR^(B88) H H G⁶ A383 CR^(B53)H H G⁴ A384 CR^(B54) H H G⁴ligands L_(A385-O) to L_(A420-O), L_(A385-S) to L_(A420-S), andL_(A385-C) to L_(A419-C), and L_(A420-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,

wherein for ligands L_(A385-O) to L_(A420-O), A in the structure G is O,

wherein for ligands L_(A385-S) to L_(A420-S), A in the structure G is S,

wherein for ligands L_(A385-C) to L_(A420-C), A in the structure G isC(CH₃)₂, wherein R⁶, R⁸, and G are defined for A385 to A420 as shownbelow:

R⁶ R⁸ G A385 H H G¹³ A386 H H G¹⁵ A387 H H G¹⁷ A388 H H G¹⁹ A389 H H G²¹A390 H H G²³ A391 CH₃ CH₃ G¹³ A392 CH₃ CH₃ G¹⁵ A393 CH₃ CH₃ G¹⁷ A394 CH₃CH₃ G¹⁹ A395 CH₃ CH₃ G²¹ A396 CH₃ CH₃ G²³ A397 CH₃ CH₃ G¹³ A398 CH₃ CH₃G¹⁵ A399 CH₃ CH₃ G¹⁷ A400 CH₃ CH₃ G¹⁹ A401 CH₃ CH₃ G²¹ A402 CH₃ CH₃ G²³A403 H H G¹⁴ A404 H H G¹⁶ A405 H H G¹⁸ A406 H H G²⁰ A407 H H G²² A408 HH G²⁴ A409 CH₃ CH₃ G¹⁴ A410 CH₃ CH₃ G¹⁶ A411 CH₃ CH₃ G¹⁸ A412 CH₃ CH₃G²⁰ A413 CH₃ CH₃ G²² A414 CH₃ CH₃ G²⁴ A415 CH₃ CH₃ G¹⁴ A416 CH₃ CH₃ G¹⁶A417 CH₃ CH₃ G¹⁸ A418 CH₃ CH₃ G²⁰ A419 CH₃ CH₃ G²² A420 CH₃ CH₃ G²⁴ligands L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), L_(A421-C)to L_(A1151-C), and L_(A1152-C) that are based on the structure

where the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,

where for ligands L_(A421-O) to L_(A1152-O), A in the structure G is O,

where for ligands L_(A421-S) to L_(A1152-S), A in the structure G is S,and

where for ligands L_(A421-C) to L_(A1152-C), A in the structure G isC(CH₃)₂, where R², R³, and G are defined for A421 to A1152 as shownbelow:

R² R³ G A421 H H G³⁷ A422 H H G³⁹ A423 H H G⁴¹ A424 H H G⁴³ A425 H H G⁴⁵A426 H H G⁴⁷ A427 CH₃ R^(B1) G³⁷ A428 CH₃ R^(B3) G³⁷ A429 CH₃ R^(B5) G³⁷A430 CH₃ R^(B7) G³⁷ A431 CH₃ R^(B9) G³⁷ A432 CH₃ R^(B11) G³⁷ A433 CH₃R^(B13) G³⁷ A434 CH₃ R^(B15) G³⁷ A435 CH₃ R^(B17) G³⁷ A436 CH₃ R^(B19)G³⁷ A437 CH₃ R^(B21) G³⁷ A438 CH₃ R^(B23) G³⁷ A439 CH₃ R^(B25) G³⁷ A440CH₃ R^(B27) G³⁷ A441 CH₃ R^(B29) G³⁷ A442 CH₃ R^(B31) G³⁷ A443 CH₃R^(B33) G³⁷ A444 CH₃ R^(B35) G³⁷ A445 CH₃ R^(B37) G³⁷ A446 CH₃ R^(B39)G³⁷ A447 CH₃ R^(B41) G³⁷ A448 CH₃ R^(B43) G³⁷ A449 CH₃ R^(B45) G³⁷ A450CH₃ R^(B47) G³⁷ A451 CH₃ R^(B49) G³⁷ A452 CH₃ R^(B51) G³⁷ A453 CH₃R^(B53) G³⁷ A454 CH₃ R^(B55) G³⁷ A455 CH₃ R^(B57) G³⁷ A456 CH₃ R^(B59)G³⁷ A457 R^(B1) CH₃ G³⁷ A458 R^(B3) CH₃ G³⁷ A459 R^(B5) CH₃ G³⁷ A460R^(B7) CH₃ G³⁷ A461 R^(B9) CH₃ G³⁷ A462 R^(B11) CH₃ G³⁷ A463 R^(B13) CH₃G³⁷ A464 R^(B15) CH₃ G³⁷ A465 R^(B17) CH₃ G³⁷ A466 R^(B19) CH₃ G³⁷ A467R^(B21) CH₃ G³⁷ A468 R^(B23) CH₃ G³⁷ A469 R^(B25) CH₃ G³⁷ A470 R^(B27)CH₃ G³⁷ A471 R^(B29) CH₃ G³⁷ A472 R^(B31) CH₃ G³⁷ A473 R^(B33) CH₃ G³⁷A474 R^(B35) CH₃ G³⁷ A475 R^(B37) CH₃ G³⁷ A476 R^(B39) CH₃ G³⁷ A477R^(B41) CH₃ G³⁷ A478 R^(B43) CH₃ G³⁷ A479 R^(B45) CH₃ G³⁷ A480 R^(B47)CH₃ G³⁷ A481 R^(B49) CH₃ G³⁷ A482 R^(B51) CH₃ G³⁷ A483 R^(B53) CH₃ G³⁷A484 R^(B55) CH₃ G³⁷ A485 R^(B57) CH₃ G³⁷ A486 R^(B59) CH₃ G³⁷ A487 CH₃R^(B1) G³⁸ A488 CH₃ R^(B3) G³⁸ A489 CH₃ R^(B5) G³⁸ A490 CH₃ R^(B7) G³⁸A491 CH₃ R^(B9) G³⁸ A492 CH₃ R^(B11) G³⁸ A493 CH₃ R^(B13) G³⁸ A494 CH₃R^(B15) G³⁸ A495 CH₃ R^(B17) G³⁸ A496 CH₃ R^(B19) G³⁸ A497 CH₃ R^(B21)G³⁸ A498 CH₃ R^(B23) G³⁸ A499 CH₃ R^(B25) G³⁸ A500 CH₃ R^(B27) G³⁸ A501CH₃ R^(B29) G³⁸ A502 CH₃ R^(B31) G³⁸ A503 CH₃ R^(B33) G³⁸ A504 CH₃R^(B35) G³⁸ A505 CH₃ R^(B37) G³⁸ A506 CH₃ R^(B39) G³⁸ A507 CH₃ R^(B41)G³⁸ A508 CH₃ R^(B43) G³⁸ A509 CH₃ R^(B45) G³⁸ A510 CH₃ R^(B47) G³⁸ A511CH₃ R^(B49) G³⁸ A512 CH₃ R^(B51) G³⁸ A513 CH₃ R^(B53) G³⁸ A514 CH₃R^(B55) G³⁸ A515 CH₃ R^(B57) G³⁸ A516 CH₃ R^(B59) G³⁸ A517 R^(B1) CH₃G³⁸ A518 R^(B3) CH₃ G³⁸ A519 R^(B5) CH₃ G³⁸ A520 R^(B7) CH₃ G³⁸ A521R^(B9) CH₃ G³⁸ A522 R^(B11) CH₃ G³⁸ A523 R^(B13) CH₃ G³⁸ A524 R^(B15)CH₃ G³⁸ A525 R^(B17) CH₃ G³⁸ A526 R^(B19) CH₃ G³⁸ A527 R^(B21) CH₃ G³⁸A528 R^(B23) CH₃ G³⁸ A529 R^(B25) CH₃ G³⁸ A530 R^(B27) CH₃ G³⁸ A531R^(B29) CH₃ G³⁸ A532 R^(B31) CH₃ G³⁸ A533 R^(B33) CH₃ G³⁸ A534 R^(B35)CH₃ G³⁸ A535 R^(B37) CH₃ G³⁸ A536 R^(B39) CH₃ G³⁸ A537 R^(B41) CH₃ G³⁸A538 R^(B43) CH₃ G³⁸ A539 R^(B45) CH₃ G³⁸ A540 R^(B47) CH₃ G³⁸ A541R^(B49) CH₃ G³⁸ A542 R^(B51) CH₃ G³⁸ A543 R^(B53) CH₃ G³⁸ A544 R^(B55)CH₃ G³⁸ A545 R^(B57) CH₃ G³⁸ A546 R^(B59) CH₃ G³⁸ A547 CH₃ R^(B1) G³⁹A548 CH₃ R^(B3) G³⁹ A549 CH₃ R^(B5) G³⁹ A550 CH₃ R^(B7) G³⁹ A551 CH₃R^(B9) G³⁹ A552 CH₃ R^(B11) G³⁹ A553 CH₃ R^(B13) G³⁹ A554 CH₃ R^(B15)G³⁹ A555 CH₃ R^(B17) G³⁹ A556 CH₃ R^(B19) G³⁹ A557 CH₃ R^(B21) G³⁹ A558CH₃ R^(B23) G³⁹ A559 CH₃ R^(B25) G³⁹ A560 CH₃ R^(B27) G³⁹ A561 CH₃R^(B29) G³⁹ A562 CH₃ R^(B31) G³⁹ A563 CH₃ R^(B33) G³⁹ A564 CH₃ R^(B35)G³⁹ A565 CH₃ R^(B37) G³⁹ A566 CH₃ R^(B39) G³⁹ A567 CH₃ R^(B41) G³⁹ A568CH₃ R^(B43) G³⁹ A569 CH₃ R^(B45) G³⁹ A570 CH₃ R^(B47) G³⁹ A571 CH₃R^(B49) G³⁹ A572 CH₃ R^(B51) G³⁹ A573 CH₃ R^(B53) G³⁹ A574 CH₃ R^(B55)G³⁹ A575 CH₃ R^(B57) G³⁹ A576 CH₃ R^(B59) G³⁹ A577 R^(B1) CH₃ G³⁹ A578R^(B3) CH₃ G³⁹ A579 R^(B5) CH₃ G³⁹ A580 R^(B7) CH₃ G³⁹ A581 R^(B9) CH₃G³⁹ A582 R^(B11) CH₃ G³⁹ A583 R^(B13) CH₃ G³⁹ A584 R^(B15) CH₃ G³⁹ A585R^(B17) CH₃ G³⁹ A586 R^(B19) CH₃ G³⁹ A587 R^(B21) CH₃ G³⁹ A588 R^(B23)CH₃ G³⁹ A589 R^(B25) CH₃ G³⁹ A590 R^(B27) CH₃ G³⁹ A591 R^(B29) CH₃ G³⁹A592 R^(B31) CH₃ G³⁹ A593 R^(B33) CH₃ G³⁹ A594 R^(B35) CH₃ G³⁹ A595R^(B37) CH₃ G³⁹ A596 R^(B39) CH₃ G³⁹ A597 R^(B41) CH₃ G³⁹ A598 R^(B43)CH₃ G³⁹ A599 R^(B45) CH₃ G³⁹ A600 R^(B47) CH₃ G³⁹ A601 R^(B49) CH₃ G³⁹A602 R^(B51) CH₃ G³⁹ A603 R^(B53) CH₃ G³⁹ A604 R^(B55) CH₃ G³⁹ A605R^(B57) CH₃ G³⁹ A606 R^(B59) CH₃ G³⁹ A607 CH₃ R^(B1) G⁴⁰ A608 CH₃ R^(B3)G⁴⁰ A609 CH₃ R^(B5) G⁴⁰ A610 CH₃ R^(B7) G⁴⁰ A611 CH₃ R^(B9) G⁴⁰ A612 CH₃R^(B11) G⁴⁰ A613 CH₃ R^(B13) G⁴⁰ A614 CH₃ R^(B15) G⁴⁰ A615 CH₃ R^(B17)G⁴⁰ A616 CH₃ R^(B19) G⁴⁰ A617 CH₃ R^(B21) G⁴⁰ A618 CH₃ R^(B23) G⁴⁰ A619CH₃ R^(B25) G⁴⁰ A620 CH₃ R^(B27) G⁴⁰ A621 CH₃ R^(B29) G⁴⁰ A622 CH₃R^(B31) G⁴⁰ A623 CH₃ R^(B33) G⁴⁰ A624 CH₃ R^(B35) G⁴⁰ A625 CH₃ R^(B37)G⁴⁰ A626 CH₃ R^(B39) G⁴⁰ A627 CH₃ R^(B41) G⁴⁰ A628 CH₃ R^(B43) G⁴⁰ A629CH₃ R^(B45) G⁴⁰ A630 CH₃ R^(B47) G⁴⁰ A631 CH₃ R^(B49) G⁴⁰ A632 CH₃R^(B51) G⁴⁰ A633 CH₃ R^(B53) G⁴⁰ A634 CH₃ R^(B55) G⁴⁰ A635 CH₃ R^(B57)G⁴⁰ A636 CH₃ R^(B59) G⁴⁰ A637 R^(B1) CH₃ G⁴⁰ A638 R^(B3) CH₃ G⁴⁰ A639R^(B5) CH₃ G⁴⁰ A640 R^(B7) CH₃ G⁴⁰ A641 R^(B9) CH₃ G⁴⁰ A642 R^(B11) CH₃G⁴⁰ A643 R^(B13) CH₃ G⁴⁰ A644 R^(B15) CH₃ G⁴⁰ A645 R^(B17) CH₃ G⁴⁰ A646R^(B19) CH₃ G⁴⁰ A647 R^(B21) CH₃ G⁴⁰ A648 R^(B23) CH₃ G⁴⁰ A649 R^(B25)CH₃ G⁴⁰ A650 R^(B27) CH₃ G⁴⁰ A651 R^(B29) CH₃ G⁴⁰ A652 R^(B31) CH₃ G⁴⁰A653 R^(B33) CH₃ G⁴⁰ A654 R^(B35) CH₃ G⁴⁰ A655 R^(B37) CH₃ G⁴⁰ A656R^(B39) CH₃ G⁴⁰ A657 R^(B41) CH₃ G⁴⁰ A658 R^(B43) CH₃ G⁴⁰ A659 R^(B45)CH₃ G⁴⁰ A660 R^(B47) CH₃ G⁴⁰ A661 R^(B49) CH₃ G⁴⁰ A662 R^(B51) CH₃ G⁴⁰A663 R^(B53) CH₃ G⁴⁰ A664 R^(B55) CH₃ G⁴⁰ A665 H H G³⁸ A666 H H G⁴⁰ A667H H G⁴² A668 H H G⁴⁴ A669 H H G⁴⁶ A670 H H G⁴⁸ A671 CH₃ R^(B2) G³⁷ A672CH₃ R^(B4) G³⁷ A673 CH₃ R^(B6) G³⁷ A674 CH₃ R^(B8) G³⁷ A675 CH₃ R^(B10)G³⁷ A676 CH₃ R^(B12) G³⁷ A677 CH₃ R^(B14) G³⁷ A678 CH₃ R^(B16) G³⁷ A679CH₃ R^(B18) G³⁷ A680 CH₃ R^(B20) G³⁷ A681 CH₃ R^(B22) G³⁷ A682 CH₃R^(B24) G³⁷ A683 CH₃ R^(B26) G³⁷ A684 CH₃ R^(B28) G³⁷ A685 CH₃ R^(B30)G³⁷ A686 CH₃ R^(B32) G³⁷ A687 CH₃ R^(B34) G³⁷ A688 CH₃ R^(B36) G³⁷ A689CH₃ R^(B38) G³⁷ A690 CH₃ R^(B40) G³⁷ A691 CH₃ R^(B42) G³⁷ A692 CH₃R^(B44) G³⁷ A693 CH₃ R^(B46) G³⁷ A694 CH₃ R^(B48) G³⁷ A695 CH₃ R^(B50)G³⁷ A696 CH₃ R^(B52) G³⁷ A697 CH₃ R^(B54) G³⁷ A698 CH₃ R^(B56) G³⁷ A699CH₃ R^(B58) G³⁷ A700 CH₃ R^(B60) G³⁷ A701 R^(B2) CH₃ G³⁷ A702 R^(B4) CH₃G³⁷ A703 R^(B6) CH₃ G³⁷ A704 R^(B8) CH₃ G³⁷ A705 R^(B10) CH₃ G³⁷ A706R^(B12) CH₃ G³⁷ A707 R^(B14) CH₃ G³⁷ A708 R^(B16) CH₃ G³⁷ A709 R^(B18)CH₃ G³⁷ A710 R^(B20) CH₃ G³⁷ A711 R^(B22) CH₃ G³⁷ A712 R^(B24) CH₃ G³⁷A713 R^(B26) CH₃ G³⁷ A714 R^(B28) CH₃ G³⁷ A715 R^(B30) CH₃ G³⁷ A716R^(B32) CH₃ G³⁷ A717 R^(B34) CH₃ G³⁷ A718 R^(B36) CH₃ G³⁷ A719 R^(B38)CH₃ G³⁷ A720 R^(B40) CH₃ G³⁷ A721 R^(B42) CH₃ G³⁷ A722 R^(B44) CH₃ G³⁷A723 R^(B46) CH₃ G³⁷ A724 R^(B48) CH₃ G³⁷ A725 R^(B50) CH₃ G³⁷ A726R^(B52) CH₃ G³⁷ A727 R^(B54) CH₃ G³⁷ A728 R^(B56) CH₃ G³⁷ A729 R^(B58)CH₃ G³⁷ A730 R^(B60) CH₃ G³⁷ A731 CH₃ R^(B2) G³⁸ A732 CH₃ R^(B4) G³⁸A733 CH₃ R^(B6) G³⁸ A734 CH₃ R^(B8) G³⁸ A735 CH₃ R^(B10) G³⁸ A736 CH₃R^(B12) G³⁸ A737 CH₃ R^(B14) G³⁸ A738 CH₃ R^(B16) G³⁸ A739 CH₃ R^(B18)G³⁸ A740 CH₃ R^(B20) G³⁸ A741 CH₃ R^(B22) G³⁸ A742 CH₃ R^(B24) G³⁸ A743CH₃ R^(B26) G³⁸ A744 CH₃ R^(B28) G³⁸ A745 CH₃ R^(B30) G³⁸ A746 CH₃R^(B32) G³⁸ A747 CH₃ R^(B34) G³⁸ A748 CH₃ R^(B36) G³⁸ A749 CH₃ R^(B38)G³⁸ A750 CH₃ R^(B40) G³⁸ A751 CH₃ R^(B42) G³⁸ A752 CH₃ R^(B44) G³⁸ A753CH₃ R^(B46) G³⁸ A754 CH₃ R^(B48) G³⁸ A755 CH₃ R^(B50) G³⁸ A756 CH₃R^(B52) G³⁸ A757 CH₃ R^(B54) G³⁸ A758 CH₃ R^(B56) G³⁸ A759 CH₃ R^(B58)G³⁸ A760 CH₃ R^(B60) G³⁸ A761 R^(B2) CH₃ G³⁸ A762 R^(B4) CH₃ G³⁸ A763R^(B6) CH₃ G³⁸ A764 R^(B8) CH₃ G³⁸ A765 R^(B10) CH₃ G³⁸ A766 R^(B12) CH₃G³⁸ A767 R^(B14) CH₃ G³⁸ A768 R^(B16) CH₃ G³⁸ A769 R^(B18) CH₃ G³⁸ A770R^(B20) CH₃ G³⁸ A771 R^(B22) CH₃ G³⁸ A772 R^(B24) CH₃ G³⁸ A773 R^(B26)CH₃ G³⁸ A774 R^(B28) CH₃ G³⁸ A775 R^(B30) CH₃ G³⁸ A776 R^(B32) CH₃ G³⁸A777 R^(B34) CH₃ G³⁸ A778 R^(B36) CH₃ G³⁸ A779 R^(B38) CH₃ G³⁸ A780R^(B40) CH₃ G³⁸ A781 R^(B42) CH₃ G³⁸ A782 R^(B44) CH₃ G³⁸ A783 R^(B46)CH₃ G³⁸ A784 R^(B48) CH₃ G³⁸ A785 R^(B50) CH₃ G³⁸ A786 R^(B52) CH₃ G³⁸A787 R^(B54) CH₃ G³⁸ A788 R^(B56) CH₃ G³⁸ A789 R^(B58) CH₃ G³⁸ A790R^(B60) CH₃ G³⁸ A791 CH₃ R^(B2) G³⁹ A792 CH₃ R^(B4) G³⁹ A793 CH₃ R^(B6)G³⁹ A794 CH₃ R^(B8) G³⁹ A795 CH₃ R^(B10) G³⁹ A796 CH₃ R^(B12) G³⁹ A797CH₃ R^(B14) G³⁹ A798 CH₃ R^(B16) G³⁹ A799 CH₃ R^(B18) G³⁹ A800 CH₃R^(B20) G³⁹ A801 CH₃ R^(B22) G³⁹ A802 CH₃ R^(B24) G³⁹ A803 CH₃ R^(B26)G³⁹ A804 CH₃ R^(B28) G³⁹ A805 CH₃ R^(B30) G³⁹ A806 CH₃ R^(B32) G³⁹ A807CH₃ R^(B34) G³⁹ A808 CH₃ R^(B36) G³⁹ A809 CH₃ R^(B38) G³⁹ A810 CH₃R^(B40) G³⁹ A811 CH₃ R^(B42) G³⁹ A812 CH₃ R^(B44) G³⁹ A813 CH₃ R^(B46)G³⁹ A814 CH₃ R^(B48) G³⁹ A815 CH₃ R^(B50) G³⁹ A816 CH₃ R^(B52) G³⁹ A817CH₃ R^(B54) G³⁹ A818 CH₃ R^(B56) G³⁹ A819 CH₃ R^(B58) G³⁹ A820 CH₃R^(B60) G³⁹ A821 R^(B2) CH₃ G³⁹ A822 R^(B4) CH₃ G³⁹ A823 R^(B6) CH₃ G³⁹A824 R^(B8) CH₃ G³⁹ A825 R^(B10) CH₃ G³⁹ A826 R^(B12) CH₃ G³⁹ A827R^(B14) CH₃ G³⁹ A828 R^(B16) CH₃ G³⁹ A829 R^(B18) CH₃ G³⁹ A830 R^(B20)CH₃ G³⁹ A831 R^(B22) CH₃ G³⁹ A832 R^(B24) CH₃ G³⁹ A833 R^(B26) CH₃ G³⁹A834 R^(B28) CH₃ G³⁹ A835 R^(B30) CH₃ G³⁹ A836 R^(B32) CH₃ G³⁹ A837R^(B34) CH₃ G³⁹ A838 R^(B36) CH₃ G³⁹ A839 R^(B38) CH₃ G³⁹ A840 R^(B40)CH₃ G³⁹ A841 R^(B42) CH₃ G³⁹ A842 R^(B44) CH₃ G³⁹ A843 R^(B46) CH₃ G³⁹A844 R^(B48) CH₃ G³⁹ A845 R^(B50) CH₃ G³⁹ A846 R^(B52) CH₃ G³⁹ A847R^(B54) CH₃ G³⁹ A848 R^(B56) CH₃ G³⁹ A849 R^(B58) CH₃ G³⁹ A850 R^(B60)CH₃ G³⁹ A851 CH₃ R^(B2) G⁴⁰ A852 CH₃ R^(B4) G⁴⁰ A853 CH₃ R^(B6) G⁴⁰ A854CH₃ R^(B8) G⁴⁰ A855 CH₃ R^(B10) G⁴⁰ A856 CH₃ R^(B12) G⁴⁰ A857 CH₃R^(B14) G⁴⁰ A858 CH₃ R^(B16) G⁴⁰ A859 CH₃ R^(B18) G⁴⁰ A860 CH₃ R^(B20)G⁴⁰ A861 CH₃ R^(B22) G⁴⁰ A862 CH₃ R^(B24) G⁴⁰ A863 CH₃ R^(B26) G⁴⁰ A864CH₃ R^(B28) G⁴⁰ A865 CH₃ R^(B30) G⁴⁰ A866 CH₃ R^(B32) G⁴⁰ A867 CH₃R^(B34) G⁴⁰ A868 CH₃ R^(B36) G⁴⁰ A869 CH₃ R^(B38) G⁴⁰ A870 CH₃ R^(B40)G⁴⁰ A871 CH₃ R^(B42) G⁴⁰ A872 CH₃ R^(B44) G⁴⁰ A873 CH₃ R^(B46) G⁴⁰ A874CH₃ R^(B48) G⁴⁰ A875 CH₃ R^(B50) G⁴⁰ A876 CH₃ R^(B52) G⁴⁰ A877 CH₃R^(B54) G⁴⁰ A878 CH₃ R^(B56) G⁴⁰ A879 CH₃ R^(B58) G⁴⁰ A880 CH₃ R^(B60)G⁴⁰ A881 R^(B2) CH₃ G⁴⁰ A882 R^(B4) CH₃ G⁴⁰ A883 R^(B6) CH₃ G⁴⁰ A884R^(B8) CH₃ G⁴⁰ A885 R^(B10) CH₃ G⁴⁰ A886 R^(B12) CH₃ G⁴⁰ A887 R^(B14)CH₃ G⁴⁰ A888 R^(B16) CH₃ G⁴⁰ A889 R^(B18) CH₃ G⁴⁰ A890 R^(B20) CH₃ G⁴⁰A891 R^(B22) CH₃ G⁴⁰ A892 R^(B24) CH₃ G⁴⁰ A893 R^(B26) CH₃ G⁴⁰ A894R^(B28) CH₃ G⁴⁰ A895 R^(B30) CH₃ G⁴⁰ A896 R^(B32) CH₃ G⁴⁰ A897 R^(B34)CH₃ G⁴⁰ A898 R^(B36) CH₃ G⁴⁰ A899 R^(B38) CH₃ G⁴⁰ A900 R^(B40) CH₃ G⁴⁰A901 R^(B42) CH₃ G⁴⁰ A902 R^(B44) CH₃ G⁴⁰ A903 R^(B46) CH₃ G⁴⁰ A904R^(B48) CH₃ G⁴⁰ A905 R^(B50) CH₃ G⁴⁰ A906 R^(B52) CH₃ G⁴⁰ A907 R^(B54)CH₃ G⁴⁰ A908 R^(B56) CH₃ G⁴⁰ A909 R^(B57) CH₃ G⁴⁰ A910 R^(B59) CH₃ G⁴⁰A911 CH₃ R^(B1) G⁴¹ A912 CH₃ R^(B3) G⁴¹ A913 CH₃ R^(B5) G⁴¹ A914 CH₃R^(B7) G⁴¹ A915 CH₃ R^(B9) G⁴¹ A916 CH₃ R^(B11) G⁴¹ A917 CH₃ R^(B13) G⁴¹A918 CH₃ R^(B15) G⁴¹ A919 CH₃ R^(B17) G⁴¹ A920 CH₃ R^(B19) G⁴¹ A921 CH₃R^(B21) G⁴¹ A922 CH₃ R^(B23) G⁴¹ A923 CH₃ R^(B25) G⁴¹ A924 CH₃ R^(B27)G⁴¹ A925 CH₃ R^(B29) G⁴¹ A926 CH₃ R^(B31) G⁴¹ A927 CH₃ R^(B33) G⁴¹ A928CH₃ R^(B35) G⁴¹ A929 CH₃ R^(B37) G⁴¹ A930 CH₃ R^(B39) G⁴¹ A931 CH₃R^(B41) G⁴¹ A932 CH₃ R^(B43) G⁴¹ A933 CH₃ R^(B45) G⁴¹ A934 CH₃ R^(B47)G⁴¹ A935 CH₃ R^(B49) G⁴¹ A936 CH₃ R^(B51) G⁴¹ A937 CH₃ R^(B53) G⁴¹ A938CH₃ R^(B55) G⁴¹ A939 CH₃ R^(B57) G⁴¹ A940 CH₃ R^(B59) G⁴¹ A941 R^(B1)CH₃ G⁴¹ A942 R^(B3) CH₃ G⁴¹ A943 R^(B5) CH₃ G⁴¹ A944 R^(B7) CH₃ G⁴¹ A945R^(B9) CH₃ G⁴¹ A946 R^(B11) CH₃ G⁴¹ A947 R^(B13) CH₃ G⁴¹ A948 R^(B15)CH₃ G⁴¹ A949 R^(B17) CH₃ G⁴¹ A950 R^(B19) CH₃ G⁴¹ A951 R^(B21) CH₃ G⁴¹A952 R^(B23) CH₃ G⁴¹ A953 R^(B25) CH₃ G⁴¹ A954 R^(B27) CH₃ G⁴¹ A955R^(B29) CH₃ G⁴¹ A956 R^(B31) CH₃ G⁴¹ A957 R^(B33) CH₃ G⁴¹ A958 R^(B35)CH₃ G⁴¹ A959 R^(B37) CH₃ G⁴¹ A960 R^(B39) CH₃ G⁴¹ A961 R^(B41) CH₃ G⁴¹A962 R^(B43) CH₃ G⁴¹ A963 R^(B45) CH₃ G⁴¹ A964 R^(B47) CH₃ G⁴¹ A965R^(B49) CH₃ G⁴¹ A966 R^(B51) CH₃ G⁴¹ A967 R^(B53) CH₃ G⁴¹ A968 R^(B55)CH₃ G⁴¹ A969 R^(B57) CH₃ G⁴¹ A970 R^(B59) CH₃ G⁴¹ A971 CH₃ R^(B1) G⁴²A972 CH₃ R^(B3) G⁴² A973 CH₃ R^(B5) G⁴² A974 CH₃ R^(B7) G⁴² A975 CH₃R^(B9) G⁴² A976 CH₃ R^(B11) G⁴² A977 CH₃ R^(B13) G⁴² A978 CH₃ R^(B15)G⁴² A979 CH₃ R^(B17) G⁴² A980 CH₃ R^(B19) G⁴² A981 CH₃ R^(B21) G⁴² A982CH₃ R^(B23) G⁴² A983 CH₃ R^(B25) G⁴² A984 CH₃ R^(B27) G⁴² A985 CH₃R^(B29) G⁴² A986 CH₃ R^(B31) G⁴² A987 CH₃ R^(B33) G⁴² A988 CH₃ R^(B35)G⁴² A989 CH₃ R^(B37) G⁴² A990 CH₃ R^(B39) G⁴² A991 CH₃ R^(B41) G⁴² A992CH₃ R^(B43) G⁴² A993 CH₃ R^(B45) G⁴² A994 CH₃ R^(B47) G⁴² A995 CH₃R^(B49) G⁴² A996 CH₃ R^(B51) G⁴² A997 CH₃ R^(B53) G⁴² A998 CH₃ R^(B55)G⁴² A999 CH₃ R^(B57) G⁴² A1000 CH₃ R^(B59) G⁴² A1001 R^(B1) CH₃ G⁴²A1002 R^(B3) CH₃ G⁴² A1003 R^(B5) CH₃ G⁴² A1004 R^(B7) CH₃ G⁴² A1005R^(B9) CH₃ G⁴² A1006 R^(B11) CH₃ G⁴² A1007 R^(B13) CH₃ G⁴² A1008 R^(B15)CH₃ G⁴² A1009 R^(B17) CH₃ G⁴² A1010 R^(B19) CH₃ G⁴² A1011 R^(B21) CH₃G⁴² A1012 R^(B23) CH₃ G⁴² A1013 R^(B25) CH₃ G⁴² A1014 R^(B27) CH₃ G⁴²A1015 R^(B29) CH₃ G⁴² A1016 R^(B31) CH₃ G⁴² A1017 R^(B33) CH₃ G⁴² A1018R^(B35) CH₃ G⁴² A1019 R^(B37) CH₃ G⁴² A1020 R^(B39) CH₃ G⁴² A1021R^(B41) CH₃ G⁴² A1022 R^(B43) CH₃ G⁴² A1023 R^(B45) CH₃ G⁴² A1024R^(B47) CH₃ G⁴² A1025 R^(B49) CH₃ G⁴² A1026 R^(B51) CH₃ G⁴² A1027R^(B53) CH₃ G⁴² A1028 R^(B55) CH₃ G⁴² A1029 R^(B57) CH₃ G⁴² A1030R^(B59) CH₃ G⁴² A1031 R^(B58) CH₃ G⁴⁰ A1032 R^(B60) CH₃ G⁴⁰ A1033 CH₃R^(B2) G⁴¹ A1034 CH₃ R^(B4) G⁴¹ A1035 CH₃ R^(B6) G⁴¹ A1036 CH₃ R^(B8)G⁴¹ A1037 CH₃ R^(B10) G⁴¹ A1038 CH₃ R^(B12) G⁴¹ A1039 CH₃ R^(B14) G⁴¹A1040 CH₃ R^(B16) G⁴¹ A1041 CH₃ R^(B18) G⁴¹ A1042 CH₃ R^(B20) G⁴¹ A1043CH₃ R^(B22) G⁴¹ A1044 CH₃ R^(B24) G⁴¹ A1045 CH₃ R^(B26) G⁴¹ A1046 CH₃R^(B28) G⁴¹ A1047 CH₃ R^(B30) G⁴¹ A1048 CH₃ R^(B32) G⁴¹ A1049 CH₃R^(B34) G⁴¹ A1050 CH₃ R^(B36) G⁴¹ A1051 CH₃ R^(B38) G⁴¹ A1052 CH₃R^(B40) G⁴¹ A1053 CH₃ R^(B42) G⁴¹ A1054 CH₃ R^(B44) G⁴¹ A1055 CH₃R^(B46) G⁴¹ A1056 CH₃ R^(B48) G⁴¹ A1057 CH₃ R^(B50) G⁴¹ A1058 CH₃R^(B52) G⁴¹ A1059 CH₃ R^(B54) G⁴¹ A1060 CH₃ R^(B56) G⁴¹ A1061 CH₃R^(B58) G⁴¹ A1062 CH₃ R^(B60) G⁴¹ A1063 R^(B2) CH₃ G⁴¹ A1064 R^(B4) CH₃G⁴¹ A1065 R^(B6) CH₃ G⁴¹ A1066 R^(B8) CH₃ G⁴¹ A1067 R^(B10) CH₃ G⁴¹A1068 R^(B12) CH₃ G⁴¹ A1069 R^(B14) CH₃ G⁴¹ A1070 R^(B16) CH₃ G⁴¹ A1071R^(B18) CH₃ G⁴¹ A1072 R^(B20) CH₃ G⁴¹ A1073 R^(B22) CH₃ G⁴¹ A1074R^(B24) CH₃ G⁴¹ A1075 R^(B26) CH₃ G⁴¹ A1076 R^(B28) CH₃ G⁴¹ A1077R^(B30) CH₃ G⁴¹ A1078 R^(B32) CH₃ G⁴¹ A1079 R^(B34) CH₃ G⁴¹ A1080R^(B36) CH₃ G⁴¹ A1081 R^(B38) CH₃ G⁴¹ A1082 R^(B40) CH₃ G⁴¹ A1083R^(B42) CH₃ G⁴¹ A1084 R^(B44) CH₃ G⁴¹ A1085 R^(B46) CH₃ G⁴¹ A1086R^(B48) CH₃ G⁴¹ A1087 R^(B50) CH₃ G⁴¹ A1088 R^(B52) CH₃ G⁴¹ A1089R^(B54) CH₃ G⁴¹ A1090 R^(B56) CH₃ G⁴¹ A1091 R^(B58) CH₃ G⁴¹ A1092R^(B60) CH₃ G⁴¹ A1093 CH₃ R^(B2) G⁴² A1094 CH₃ R^(B4) G⁴² A1095 CH₃R^(B6) G⁴² A1096 CH₃ R^(B8) G⁴² A1097 CH₃ R^(B10) G⁴² A1098 CH₃ R^(B12)G⁴² A1099 CH₃ R^(B14) G⁴² A1100 CH₃ R^(B16) G⁴² A1101 CH₃ R^(B18) G⁴²A1102 CH₃ R^(B20) G⁴² A1103 CH₃ R^(B22) G⁴² A1104 CH₃ R^(B24) G⁴² A1105CH₃ R^(B26) G⁴² A1106 CH₃ R^(B28) G⁴² A1107 CH₃ R^(B30) G⁴² A1108 CH₃R^(B32) G⁴² A1109 CH₃ R^(B34) G⁴² A1110 CH₃ R^(B36) G⁴² A1111 CH₃R^(B38) G⁴² A1112 CH₃ R^(B40) G⁴² A1113 CH₃ R^(B42) G⁴² A1114 CH₃R^(B44) G⁴² A1115 CH₃ R^(B46) G⁴² A1116 CH₃ R^(B48) G⁴² A1117 CH₃R^(B50) G⁴² A1118 CH₃ R^(B52) G⁴² A1119 CH₃ R^(B54) G⁴² A1120 CH₃R^(B56) G⁴² A1121 CH₃ R^(B58) G⁴² A1122 CH₃ R^(B60) G⁴² A1123 R^(B2) CH₃G⁴² A1124 R^(B4) CH₃ G⁴² A1125 R^(B6) CH₃ G⁴² A1126 R^(B8) CH₃ G⁴² A1127R^(B10) CH₃ G⁴² A1128 R^(B12) CH₃ G⁴² A1129 R^(B14) CH₃ G⁴² A1130R^(B16) CH₃ G⁴² A1131 R^(B18) CH₃ G⁴² A1132 R^(B20) CH₃ G⁴² A1133R^(B22) CH₃ G⁴² A1134 R^(B24) CH₃ G⁴² A1135 R^(B26) CH₃ G⁴² A1136R^(B28) CH₃ G⁴² A1137 R^(B30) CH₃ G⁴² A1138 R^(B32) CH₃ G⁴² A1139R^(B34) CH₃ G⁴² A1140 R^(B36) CH₃ G⁴² A1141 R^(B38) CH₃ G⁴² A1142R^(B40) CH₃ G⁴² A1143 R^(B42) CH₃ G⁴² A1144 R^(B44) CH₃ G⁴² A1145R^(B46) CH₃ G⁴² A1146 R^(B48) CH₃ G⁴² A1147 R^(B50) CH₃ G⁴² A1148R^(B52) CH₃ G⁴² A1149 R^(B54) CH₃ G⁴² A1150 R^(B56) CH₃ G⁴² A1151R^(B58) CH₃ G⁴² A1152 R^(B60) CH₃ G⁴²,ligands L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S),L_(A1153-C) to L_(A1763-C), and L_(A1764-C) that are based on thestructure

where the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,

where for ligands L_(A1153-O) to L_(A1764-O), A in the structure G is O,

where for ligands L_(A1153-S) to L_(A1764-S), A in the structure G is S,and

where for ligands L_(A1153-C) to L_(A1764-C), A in the structure G isC(CH₃)₂, where R², R³, and G are defined for A1153 to A1764 as shownbelow:

R² R³ G A1153 H H G³⁷ A1154 H H G³⁹ A1155 H H G⁴¹ A1156 H H G⁴³ A1157 HH G⁴⁵ A1158 H H G⁴⁷ A1159 CH₃ R^(B1) G³⁷ A1160 CH₃ R^(B3) G³⁷ A1161 CH₃R^(B5) G³⁷ A1162 CH₃ R^(B7) G³⁷ A1163 CH₃ R^(B9) G³⁷ A1164 CH₃ R^(B11)G³⁷ A1165 CH₃ R^(B13) G³⁷ A1166 CH₃ R^(B15) G³⁷ A1167 CH₃ R^(B17) G³⁷A1168 CH₃ R^(B19) G³⁷ A1169 CH₃ R^(B21) G³⁷ A1170 CH₃ R^(B23) G³⁷ A1171CH₃ R^(B25) G³⁷ A1172 CH₃ R^(B27) G³⁷ A1173 CH₃ R^(B29) G³⁷ A1174 CH₃R^(B31) G³⁷ A1175 CH₃ R^(B33) G³⁷ A1176 CH₃ R^(B35) G³⁷ A1177 CH₃R^(B37) G³⁷ A1178 CH₃ R^(B39) G³⁷ A1179 CH₃ R^(B41) G³⁷ A1180 CH₃R^(B43) G³⁷ A1181 CH₃ R^(B45) G³⁷ A1182 CH₃ R^(B47) G³⁷ A1183 CH₃R^(B49) G³⁷ A1184 CH₃ R^(B51) G³⁷ A1185 CH₃ R^(B53) G³⁷ A1186 CH₃R^(B55) G³⁷ A1187 CH₃ R^(B57) G³⁷ A1188 CH₃ R^(B59) G³⁷ A1189 R^(B1) CH₃G³⁷ A1190 R^(B3) CH₃ G³⁷ A1191 R^(B5) CH₃ G³⁷ A1192 R^(B7) CH₃ G³⁷ A1193R^(B9) CH₃ G³⁷ A1194 R^(B11) CH₃ G³⁷ A1195 R^(B13) CH₃ G³⁷ A1196 R^(B15)CH₃ G³⁷ A1197 R^(B17) CH₃ G³⁷ A1198 R^(B19) CH₃ G³⁷ A1199 R^(B21) CH₃G³⁷ A1200 R^(B23) CH₃ G³⁷ A1201 R^(B25) CH₃ G³⁷ A1202 R^(B27) CH₃ G³⁷A1203 R^(B29) CH₃ G³⁷ A1204 R^(B31) CH₃ G³⁷ A1205 R^(B33) CH₃ G³⁷ A1206R^(B35) CH₃ G³⁷ A1207 R^(B37) CH₃ G³⁷ A1208 R^(B39) CH₃ G³⁷ A1209R^(B41) CH₃ G³⁷ A1210 R^(B43) CH₃ G³⁷ A1211 R^(B45) CH₃ G³⁷ A1212R^(B47) CH₃ G³⁷ A1213 R^(B49) CH₃ G³⁷ A1214 R^(B51) CH₃ G³⁷ A1215R^(B53) CH₃ G³⁷ A1216 R^(B55) CH₃ G³⁷ A1217 R^(B57) CH₃ G³⁷ A1218R^(B59) CH₃ G³⁷ A1219 CH₃ R^(B1) G³⁹ A1220 CH₃ R^(B3) G³⁹ A1221 CH₃R^(B5) G³⁹ A1222 CH₃ R^(B7) G³⁹ A1223 CH₃ R^(B9) G³⁹ A1224 CH₃ R^(B11)G³⁹ A1225 CH₃ R^(B13) G³⁹ A1226 CH₃ R^(B15) G³⁹ A1227 CH₃ R^(B17) G³⁹A1228 CH₃ R^(B19) G³⁹ A1229 CH₃ R^(B21) G³⁹ A1230 CH₃ R^(B23) G³⁹ A1231CH₃ R^(B25) G³⁹ A1232 CH₃ R^(B27) G³⁹ A1233 CH₃ R^(B29) G³⁹ A1234 CH₃R^(B31) G³⁹ A1235 CH₃ R^(B33) G³⁹ A1236 CH₃ R^(B35) G³⁹ A1237 CH₃R^(B37) G³⁹ A1238 CH₃ R^(B39) G³⁹ A1239 CH₃ R^(B41) G³⁹ A1240 CH₃R^(B43) G³⁹ A1241 CH₃ R^(B45) G³⁹ A1242 CH₃ R^(B47) G³⁹ A1243 CH₃R^(B49) G³⁹ A1244 CH₃ R^(B51) G³⁹ A1245 CH₃ R^(B53) G³⁹ A1246 CH₃R^(B55) G³⁹ A1247 CH₃ R^(B57) G³⁹ A1248 CH₃ R^(B59) G³⁹ A1249 R^(B1) CH₃G³⁹ A1250 R^(B3) CH₃ G³⁹ A1251 R^(B5) CH₃ G³⁹ A1252 R^(B7) CH₃ G³⁹ A1253R^(B9) CH₃ G³⁹ A1254 R^(B11) CH₃ G³⁹ A1255 R^(B13) CH₃ G³⁹ A1256 R^(B15)CH₃ G³⁹ A1257 R^(B17) CH₃ G³⁹ A1258 R^(B19) CH₃ G³⁹ A1259 R^(B21) CH₃G³⁹ A1260 R^(B23) CH₃ G³⁹ A1261 R^(B25) CH₃ G³⁹ A1262 R^(B27) CH₃ G³⁹A1263 R^(B29) CH₃ G³⁹ A1264 R^(B31) CH₃ G³⁹ A1265 R^(B33) CH₃ G³⁹ A1266R^(B35) CH₃ G³⁹ A1267 R^(B37) CH₃ G³⁹ A1268 R^(B39) CH₃ G³⁹ A1269R^(B41) CH₃ G³⁹ A1270 R^(B43) CH₃ G³⁹ A1271 R^(B45) CH₃ G³⁹ A1272R^(B47) CH₃ G³⁹ A1273 R^(B49) CH₃ G³⁹ A1274 R^(B51) CH₃ G³⁹ A1275R^(B53) CH₃ G³⁹ A1276 R^(B55) CH₃ G³⁹ A1277 R^(B57) CH₃ G³⁹ A1278R^(B59) CH₃ G³⁹ A1279 CH₃ R^(B1) G⁴⁰ A1280 CH₃ R^(B3) G⁴⁰ A1281 CH₃R^(B5) G⁴⁰ A1282 CH₃ R^(B7) G⁴⁰ A1283 CH₃ R^(B9) G⁴⁰ A1284 CH₃ R^(B11)G⁴⁰ A1285 CH₃ R^(B13) G⁴⁰ A1286 CH₃ R^(B15) G⁴⁰ A1287 CH₃ R^(B17) G⁴⁰A1288 CH₃ R^(B19) G⁴⁰ A1289 CH₃ R^(B21) G⁴⁰ A1290 CH₃ R^(B23) G⁴⁰ A1291CH₃ R^(B25) G⁴⁰ A1292 CH₃ R^(B27) G⁴⁰ A1293 CH₃ R^(B29) G⁴⁰ A1294 CH₃R^(B31) G⁴⁰ A1295 CH₃ R^(B33) G⁴⁰ A1296 CH₃ R^(B35) G⁴⁰ A1297 CH₃R^(B37) G⁴⁰ A1298 CH₃ R^(B39) G⁴⁰ A1299 CH₃ R^(B41) G⁴⁰ A1300 CH₃R^(B43) G⁴⁰ A1301 CH₃ R^(B45) G⁴⁰ A1302 CH₃ R^(B47) G⁴⁰ A1303 CH₃R^(B49) G⁴⁰ A1304 CH₃ R^(B51) G⁴⁰ A1305 CH₃ R^(B53) G⁴⁰ A1306 CH₃R^(B55) G⁴⁰ A1307 CH₃ R^(B57) G⁴⁰ A1308 CH₃ R^(B59) G⁴⁰ A1309 R^(B1) CH₃G⁴⁰ A1310 R^(B3) CH₃ G⁴⁰ A1311 R^(B5) CH₃ G⁴⁰ A1312 R^(B7) CH₃ G⁴⁰ A1313R^(B9) CH₃ G⁴⁰ A1314 R^(B11) CH₃ G⁴⁰ A1315 R^(B13) CH₃ G⁴⁰ A1316 R^(B15)CH₃ G⁴⁰ A1317 R^(B17) CH₃ G⁴⁰ A1318 R^(B19) CH₃ G⁴⁰ A1319 R^(B21) CH₃G⁴⁰ A1320 R^(B23) CH₃ G⁴⁰ A1321 R^(B25) CH₃ G⁴⁰ A1322 R^(B27) CH₃ G⁴⁰A1323 R^(B29) CH₃ G⁴⁰ A1324 R^(B31) CH₃ G⁴⁰ A1325 R^(B33) CH₃ G⁴⁰ A1326R^(B35) CH₃ G⁴⁰ A1327 R^(B37) CH₃ G⁴⁰ A1328 R^(B39) CH₃ G⁴⁰ A1329R^(B41) CH₃ G⁴⁰ A1330 R^(B43) CH₃ G⁴⁰ A1331 R^(B45) CH₃ G⁴⁰ A1332R^(B47) CH₃ G⁴⁰ A1333 R^(B49) CH₃ G⁴⁰ A1334 R^(B51) CH₃ G⁴⁰ A1335R^(B53) CH₃ G⁴⁰ A1336 R^(B55) CH₃ G⁴⁰ A1337 R^(B57) CH₃ G⁴⁰ A1338R^(B59) CH₃ G⁴⁰ A1339 CH₃ R^(B1) G⁴¹ A1340 CH₃ R^(B3) G⁴¹ A1341 CH₃R^(B5) G⁴¹ A1342 CH₃ R^(B7) G⁴¹ A1343 CH₃ R^(B9) G⁴¹ A1344 CH₃ R^(B11)G⁴¹ A1345 CH₃ R^(B13) G⁴¹ A1346 CH₃ R^(B15) G⁴¹ A1347 CH₃ R^(B17) G⁴¹A1348 CH₃ R^(B19) G⁴¹ A1349 CH₃ R^(B21) G⁴¹ A1350 CH₃ R^(B23) G⁴¹ A1351CH₃ R^(B25) G⁴¹ A1352 CH₃ R^(B27) G⁴¹ A1353 CH₃ R^(B29) G⁴¹ A1354 CH₃R^(B31) G⁴¹ A1355 CH₃ R^(B33) G⁴¹ A1356 CH₃ R^(B35) G⁴¹ A1357 H H G³⁸A1358 H H G⁴⁰ A1359 H H G⁴² A1360 H H G⁴⁴ A1361 H H G⁴⁶ A1362 H H G⁴⁸A1363 CH₃ R^(B2) G³⁷ A1364 CH₃ R^(B4) G³⁷ A1365 CH₃ R^(B6) G³⁷ A1366 CH₃R^(B8) G³⁷ A1367 CH₃ R^(B10) G³⁷ A1368 CH₃ R^(B12) G³⁷ A1369 CH₃ R^(B14)G³⁷ A1370 CH₃ R^(B16) G³⁷ A1371 CH₃ R^(B18) G³⁷ A1372 CH₃ R^(B20) G³⁷A1373 CH₃ R^(B22) G³⁷ A1374 CH₃ R^(B24) G³⁷ A1375 CH₃ R^(B26) G³⁷ A1376CH₃ R^(B28) G³⁷ A1377 CH₃ R^(B30) G³⁷ A1378 CH₃ R^(B32) G³⁷ A1379 CH₃R^(B34) G³⁷ A1380 CH₃ R^(B36) G³⁷ A1381 CH₃ R^(B38) G³⁷ A1382 CH₃R^(B40) G³⁷ A1383 CH₃ R^(B42) G³⁷ A1384 CH₃ R^(B44) G³⁷ A1385 CH₃R^(B46) G³⁷ A1386 CH₃ R^(B48) G³⁷ A1387 CH₃ R^(B50) G³⁷ A1388 CH₃R^(B52) G³⁷ A1389 CH₃ R^(B54) G³⁷ A1390 CH₃ R^(B56) G³⁷ A1391 CH₃R^(B58) G³⁷ A1392 CH₃ R^(B60) G³⁷ A1393 R^(B2) CH₃ G³⁷ A1394 R^(B4) CH₃G³⁷ A1395 R^(B6) CH₃ G³⁷ A1396 R^(B8) CH₃ G³⁷ A1397 R^(B10) CH₃ G³⁷A1398 R^(B12) CH₃ G³⁷ A1399 R^(B14) CH₃ G³⁷ A1400 R^(B16) CH₃ G³⁷ A1401R^(B18) CH₃ G³⁷ A1402 R^(B20) CH₃ G³⁷ A1403 R^(B22) CH₃ G³⁷ A1404R^(B24) CH₃ G³⁷ A1405 R^(B26) CH₃ G³⁷ A1406 R^(B28) CH₃ G³⁷ A1407R^(B30) CH₃ G³⁷ A1408 R^(B32) CH₃ G³⁷ A1409 R^(B34) CH₃ G³⁷ A1410R^(B36) CH₃ G³⁷ A1411 R^(B38) CH₃ G³⁷ A1412 R^(B40) CH₃ G³⁷ A1413R^(B42) CH₃ G³⁷ A1414 R^(B44) CH₃ G³⁷ A1415 R^(B46) CH₃ G³⁷ A1416R^(B48) CH₃ G³⁷ A1417 R^(B50) CH₃ G³⁷ A1418 R^(B52) CH₃ G³⁷ A1419R^(B54) CH₃ G³⁷ A1420 R^(B56) CH₃ G³⁷ A1421 R^(B58) CH₃ G³⁷ A1422R^(B60) CH₃ G³⁷ A1423 CH₃ R^(B2) G³⁹ A1424 CH₃ R^(B4) G³⁹ A1425 CH₃R^(B6) G³⁹ A1426 CH₃ R^(B8) G³⁹ A1427 CH₃ R^(B10) G³⁹ A1428 CH₃ R^(B12)G³⁹ A1429 CH₃ R^(B14) G³⁹ A1430 CH₃ R^(B16) G³⁹ A1431 CH₃ R^(B18) G³⁹A1432 CH₃ R^(B20) G³⁹ A1433 CH₃ R^(B22) G³⁹ A1434 CH₃ R^(B24) G³⁹ A1435CH₃ R^(B26) G³⁹ A1436 CH₃ R^(B28) G³⁹ A1437 CH₃ R^(B30) G³⁹ A1438 CH₃R^(B32) G³⁹ A1439 CH₃ R^(B34) G³⁹ A1440 CH₃ R^(B36) G³⁹ A1441 CH₃R^(B38) G³⁹ A1442 CH₃ R^(B40) G³⁹ A1443 CH₃ R^(B42) G³⁹ A1444 CH₃R^(B44) G³⁹ A1445 CH₃ R^(B46) G³⁹ A1446 CH₃ R^(B48) G³⁹ A1447 CH₃R^(B50) G³⁹ A1448 CH₃ R^(B52) G³⁹ A1449 CH₃ R^(B54) G³⁹ A1450 CH₃R^(B56) G³⁹ A1451 CH₃ R^(B58) G³⁹ A1452 CH₃ R^(B60) G³⁹ A1453 R^(B2) CH₃G³⁹ A1454 R^(B4) CH₃ G³⁹ A1455 R^(B6) CH₃ G³⁹ A1456 R^(B8) CH₃ G³⁹ A1457R^(B10) CH₃ G³⁹ A1458 R^(B12) CH₃ G³⁹ A1459 R^(B14) CH₃ G³⁹ A1460R^(B16) CH₃ G³⁹ A1461 R^(B18) CH₃ G³⁹ A1462 R^(B20) CH₃ G³⁹ A1463R^(B22) CH₃ G³⁹ A1464 R^(B24) CH₃ G³⁹ A1465 R^(B26) CH₃ G³⁹ A1466R^(B28) CH₃ G³⁹ A1467 R^(B30) CH₃ G³⁹ A1468 R^(B32) CH₃ G³⁹ A1469R^(B34) CH₃ G³⁹ A1470 R^(B36) CH₃ G³⁹ A1471 R^(B38) CH₃ G³⁹ A1472R^(B40) CH₃ G³⁹ A1473 R^(B42) CH₃ G³⁹ A1474 R^(B44) CH₃ G³⁹ A1475R^(B46) CH₃ G³⁹ A1476 R^(B48) CH₃ G³⁹ A1477 R^(B50) CH₃ G³⁹ A1478R^(B52) CH₃ G³⁹ A1479 R^(B54) CH₃ G³⁹ A1480 R^(B56) CH₃ G³⁹ A1481R^(B58) CH₃ G³⁹ A1482 R^(B60) CH₃ G³⁹ A1483 CH₃ R^(B2) G⁴⁰ A1484 CH₃R^(B4) G⁴⁰ A1485 CH₃ R^(B6) G⁴⁰ A1486 CH₃ R^(B8) G⁴⁰ A1487 CH₃ R^(B10)G⁴⁰ A1488 CH₃ R^(B12) G⁴⁰ A1489 CH₃ R^(B14) G⁴⁰ A1490 CH₃ R^(B16) G⁴⁰A1491 CH₃ R^(B18) G⁴⁰ A1492 CH₃ R^(B20) G⁴⁰ A1493 CH₃ R^(B22) G⁴⁰ A1494CH₃ R^(B24) G⁴⁰ A1495 CH₃ R^(B26) G⁴⁰ A1496 CH₃ R^(B28) G⁴⁰ A1497 CH₃R^(B30) G⁴⁰ A1498 CH₃ R^(B32) G⁴⁰ A1499 CH₃ R^(B34) G⁴⁰ A1500 CH₃R^(B36) G⁴⁰ A1501 CH₃ R^(B38) G⁴⁰ A1502 CH₃ R^(B40) G⁴⁰ A1503 CH₃R^(B42) G⁴⁰ A1504 CH₃ R^(B44) G⁴⁰ A1505 CH₃ R^(B46) G⁴⁰ A1506 CH₃R^(B48) G⁴⁰ A1507 CH₃ R^(B50) G⁴⁰ A1508 CH₃ R^(B52) G⁴⁰ A1509 CH₃R^(B54) G⁴⁰ A1510 CH₃ R^(B56) G⁴⁰ A1511 CH₃ R^(B58) G⁴⁰ A1512 CH₃R^(B60) G⁴⁰ A1513 R^(B2) CH₃ G⁴⁰ A1514 R^(B4) CH₃ G⁴⁰ A1515 R^(B6) CH₃G⁴⁰ A1516 R^(B8) CH₃ G⁴⁰ A1517 R^(B10) CH₃ G⁴⁰ A1518 R^(B12) CH₃ G⁴⁰A1519 R^(B14) CH₃ G⁴⁰ A1520 R^(B16) CH₃ G⁴⁰ A1521 R^(B18) CH₃ G⁴⁰ A1522R^(B20) CH₃ G⁴⁰ A1523 R^(B22) CH₃ G⁴⁰ A1524 R^(B24) CH₃ G⁴⁰ A1525R^(B26) CH₃ G⁴⁰ A1526 R^(B28) CH₃ G⁴⁰ A1527 R^(B30) CH₃ G⁴⁰ A1528R^(B32) CH₃ G⁴⁰ A1529 R^(B34) CH₃ G⁴⁰ A1530 R^(B36) CH₃ G⁴⁰ A1531R^(B38) CH₃ G⁴⁰ A1532 R^(B40) CH₃ G⁴⁰ A1533 R^(B42) CH₃ G⁴⁰ A1534R^(B44) CH₃ G⁴⁰ A1535 R^(B46) CH₃ G⁴⁰ A1536 R^(B48) CH₃ G⁴⁰ A1537R^(B50) CH₃ G⁴⁰ A1538 R^(B52) CH₃ G⁴⁰ A1539 R^(B54) CH₃ G⁴⁰ A1540R^(B56) CH₃ G⁴⁰ A1541 R^(B58) CH₃ G⁴⁰ A1542 R^(B60) CH₃ G⁴⁰ A1543 CH₃R^(B2) G⁴¹ A1544 CH₃ R^(B4) G⁴¹ A1545 CH₃ R^(B6) G⁴¹ A1546 CH₃ R^(B8)G⁴¹ A1547 CH₃ R^(B10) G⁴¹ A1548 CH₃ R^(B12) G⁴¹ A1549 CH₃ R^(B14) G⁴¹A1550 CH₃ R^(B16) G⁴¹ A1551 CH₃ R^(B18) G⁴¹ A1552 CH₃ R^(B20) G⁴¹ A1553CH₃ R^(B22) G⁴¹ A1554 CH₃ R^(B24) G⁴¹ A1555 CH₃ R^(B26) G⁴¹ A1556 CH₃R^(B28) G⁴¹ A1557 CH₃ R^(B30) G⁴¹ A1558 CH₃ R^(B32) G⁴¹ A1559 CH₃R^(B34) G⁴¹ A1560 CH₃ R^(B36) G⁴¹ A1561 CH₃ R^(B37) G⁴¹ A1562 CH₃R^(B39) G⁴¹ A1563 CH₃ R^(B41) G⁴¹ A1564 CH₃ R^(B43) G⁴¹ A1565 CH₃R^(B45) G⁴¹ A1566 CH₃ R^(B47) G⁴¹ A1567 CH₃ R^(B49) G⁴¹ A1568 CH₃R^(B51) G⁴¹ A1569 CH₃ R^(B53) G⁴¹ A1570 CH₃ R^(B55) G⁴¹ A1571 CH₃R^(B57) G⁴¹ A1572 CH₃ R^(B59) G⁴¹ A1573 R^(B1) CH₃ G⁴¹ A1574 R^(B3) CH₃G⁴¹ A1575 R^(B5) CH₃ G⁴¹ A1576 R^(B7) CH₃ G⁴¹ A1577 R^(B9) CH₃ G⁴¹ A1578R^(B11) CH₃ G⁴¹ A1579 R^(B13) CH₃ G⁴¹ A1580 R^(B15) CH₃ G⁴¹ A1581R^(B17) CH₃ G⁴¹ A1582 R^(B19) CH₃ G⁴¹ A1583 R^(B21) CH₃ G⁴¹ A1584R^(B23) CH₃ G⁴¹ A1585 R^(B25) CH₃ G⁴¹ A1586 R^(B27) CH₃ G⁴¹ A1587R^(B29) CH₃ G⁴¹ A1588 R^(B31) CH₃ G⁴¹ A1589 R^(B33) CH₃ G⁴¹ A1590R^(B35) CH₃ G⁴¹ A1591 R^(B37) CH₃ G⁴¹ A1592 R^(B39) CH₃ G⁴¹ A1593R^(B41) CH₃ G⁴¹ A1594 R^(B43) CH₃ G⁴¹ A1595 R^(B45) CH₃ G⁴¹ A1596R^(B47) CH₃ G⁴¹ A1597 R^(B49) CH₃ G⁴¹ A1598 R^(B51) CH₃ G⁴¹ A1599R^(B53) CH₃ G⁴¹ A1600 R^(B55) CH₃ G⁴¹ A1601 R^(B57) CH₃ G⁴¹ A1602R^(B59) CH₃ G⁴¹ A1603 CH₃ R^(B1) G⁴² A1604 CH₃ R^(B3) G⁴² A1605 CH₃R^(B5) G⁴² A1606 CH₃ R^(B7) G⁴² A1607 CH₃ R^(B9) G⁴² A1608 CH₃ R^(B11)G⁴² A1609 CH₃ R^(B13) G⁴² A1610 CH₃ R^(B15) G⁴² A1611 CH₃ R^(B17) G⁴²A1612 CH₃ R^(B19) G⁴² A1613 CH₃ R^(B21) G⁴² A1614 CH₃ R^(B23) G⁴² A1615CH₃ R^(B25) G⁴² A1616 CH₃ R^(B27) G⁴² A1617 CH₃ R^(B29) G⁴² A1618 CH₃R^(B31) G⁴² A1619 CH₃ R^(B33) G⁴² A1620 CH₃ R^(B35) G⁴² A1621 CH₃R^(B37) G⁴² A1622 CH₃ R^(B39) G⁴² A1623 CH₃ R^(B41) G⁴² A1624 CH₃R^(B43) G⁴² A1625 CH₃ R^(B45) G⁴² A1626 CH₃ R^(B47) G⁴² A1627 CH₃R^(B49) G⁴² A1628 CH₃ R^(B51) G⁴² A1629 CH₃ R^(B53) G⁴² A1630 CH₃R^(B55) G⁴² A1631 CH₃ R^(B57) G⁴² A1632 CH₃ R^(B59) G⁴² A1633 R^(B1) CH₃G⁴² A1634 R^(B3) CH₃ G⁴² A1635 R^(B5) CH₃ G⁴² A1636 R^(B7) CH₃ G⁴² A1637R^(B9) CH₃ G⁴² A1638 R^(B11) CH₃ G⁴² A1639 R^(B13) CH₃ G⁴² A1640 R^(B15)CH₃ G⁴² A1641 R^(B17) CH₃ G⁴² A1642 R^(B19) CH₃ G⁴² A1643 R^(B21) CH₃G⁴² A1644 R^(B23) CH₃ G⁴² A1645 R^(B25) CH₃ G⁴² A1646 R^(B27) CH₃ G⁴²A1647 R^(B29) CH₃ G⁴² A1648 R^(B31) CH₃ G⁴² A1649 R^(B33) CH₃ G⁴² A1650R^(B35) CH₃ G⁴² A1651 R^(B37) CH₃ G⁴² A1652 R^(B39) CH₃ G⁴² A1653R^(B41) CH₃ G⁴² A1654 R^(B43) CH₃ G⁴² A1655 R^(B45) CH₃ G⁴² A1656R^(B47) CH₃ G⁴² A1657 R^(B49) CH₃ G⁴² A1658 R^(B51) CH₃ G⁴² A1659R^(B53) CH₃ G⁴² A1660 R^(B55) CH₃ G⁴² A1661 R^(B57) CH₃ G⁴² A1662R^(B59) CH₃ G⁴² A1663 CH₃ R^(B38) G⁴¹ A1664 CH₃ R^(B40) G⁴¹ A1665 CH₃R^(B42) G⁴¹ A1666 CH₃ R^(B44) G⁴¹ A1667 CH₃ R^(B46) G⁴¹ A1668 CH₃R^(B48) G⁴¹ A1669 CH₃ R^(B50) G⁴¹ A1670 CH₃ R^(B52) G⁴¹ A1671 CH₃R^(B54) G⁴¹ A1672 CH₃ R^(B56) G⁴¹ A1673 CH₃ R^(B58) G⁴¹ A1674 CH₃R^(B60) G⁴¹ A1675 R^(B2) CH₃ G⁴¹ A1676 R^(B4) CH₃ G⁴¹ A1677 R^(B6) CH₃G⁴¹ A1678 R^(B8) CH₃ G⁴¹ A1679 R^(B10) CH₃ G⁴¹ A1680 R^(B12) CH₃ G⁴¹A1681 R^(B14) CH₃ G⁴¹ A1682 R^(B16) CH₃ G⁴¹ A1683 R^(B18) CH₃ G⁴¹ A1684R^(B20) CH₃ G⁴¹ A1685 R^(B22) CH₃ G⁴¹ A1686 R^(B24) CH₃ G⁴¹ A1687R^(B26) CH₃ G⁴¹ A1688 R^(B28) CH₃ G⁴¹ A1689 R^(B30) CH₃ G⁴¹ A1690R^(B32) CH₃ G⁴¹ A1691 R^(B34) CH₃ G⁴¹ A1692 R^(B36) CH₃ G⁴¹ A1693R^(B38) CH₃ G⁴¹ A1694 R^(B40) CH₃ G⁴¹ A1695 R^(B42) CH₃ G⁴¹ A1696R^(B44) CH₃ G⁴¹ A1697 R^(B46) CH₃ G⁴¹ A1698 R^(B48) CH₃ G⁴¹ A1699R^(B50) CH₃ G⁴¹ A1700 R^(B52) CH₃ G⁴¹ A1701 R^(B54) CH₃ G⁴¹ A1702R^(B56) CH₃ G⁴¹ A1703 R^(B58) CH₃ G⁴¹ A1704 R^(B60) CH₃ G⁴¹ A1705 CH₃R^(B2) G⁴² A1706 CH₃ R^(B4) G⁴² A1707 CH₃ R^(B6) G⁴² A1708 CH₃ R^(B8)G⁴² A1709 CH₃ R^(B10) G⁴² A1710 CH₃ R^(B12) G⁴² A1711 CH₃ R^(B14) G⁴²A1712 CH₃ R^(B16) G⁴² A1713 CH₃ R^(B18) G⁴² A1714 CH₃ R^(B20) G⁴² A1715CH₃ R^(B22) G⁴² A1716 CH₃ R^(B24) G⁴² A1717 CH₃ R^(B26) G⁴² A1718 CH₃R^(B28) G⁴² A1719 CH₃ R^(B30) G⁴² A1720 CH₃ R^(B32) G⁴² A1721 CH₃R^(B34) G⁴² A1722 CH₃ R^(B36) G⁴² A1723 CH₃ R^(B38) G⁴² A1724 CH₃R^(B40) G⁴² A1725 CH₃ R^(B42) G⁴² A1726 CH₃ R^(B44) G⁴² A1727 CH₃R^(B46) G⁴² A1728 CH₃ R^(B48) G⁴² A1729 CH₃ R^(B50) G⁴² A1730 CH₃R^(B52) G⁴² A1731 CH₃ R^(B54) G⁴² A1732 CH₃ R^(B56) G⁴² A1733 CH₃R^(B58) G⁴² A1734 CH₃ R^(B60) G⁴² A1735 R^(B2) CH₃ G⁴² A1736 R^(B4) CH₃G⁴² A1737 R^(B6) CH₃ G⁴² A1738 R^(B8) CH₃ G⁴² A1739 R^(B10) CH₃ G⁴²A1740 R^(B12) CH₃ G⁴² A1741 R^(B14) CH₃ G⁴² A1742 R^(B16) CH₃ G⁴² A1743R^(B18) CH₃ G⁴² A1744 R^(B20) CH₃ G⁴² A1745 R^(B22) CH₃ G⁴² A1746R^(B24) CH₃ G⁴² A1747 R^(B26) CH₃ G⁴² A1748 R^(B28) CH₃ G⁴² A1749R^(B30) CH₃ G⁴² A1750 R^(B32) CH₃ G⁴² A1751 R^(B34) CH₃ G⁴² A1752R^(B36) CH₃ G⁴² A1753 R^(B38) CH₃ G⁴² A1754 R^(B40) CH₃ G⁴² A1755R^(B42) CH₃ G⁴² A1756 R^(B44) CH₃ G⁴² A1757 R^(B46) CH₃ G⁴² A1758R^(B48) CH₃ G⁴² A1759 R^(B50) CH₃ G⁴² A1760 R^(B52) CH₃ G⁴² A1761R^(B54) CH₃ G⁴² A1762 R^(B56) CH₃ G⁴² A1763 R^(B58) CH₃ G⁴² A1764R^(B60) CH₃ G⁴²,where R^(B1) to R^(B60) have the following structures:

wherein G¹ to G⁴⁸ have the following structures:

and where the Arabic Numerals indicate the points of attachment to thecorresponding points of attachment in ligand L_(A).

In some embodiments, the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), where L_(B) and L_(C) are each abidentate ligand; and x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2;and x+y+z is the oxidation state of the metal M. In some embodimentswhere the compound has a formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z),the compound is selected from the group of formulas consisting ofIr(L_(A))₃, Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))₂(L_(C)), andIr(L_(A))(L_(B))(L_(C)), where L_(A), L_(B), and L_(C) are differentfrom each other. In some embodiments, the compound has a formula ofPt(L_(A))(L_(B)), and L_(A) and L_(B) can be same or different. In someembodiments, L_(A) and L_(B) are connected to form a tetradentateligand. In some embodiments, L_(A) and L_(B) are connected at two placesto form a macrocyclic tetradentate ligand. In some embodiments, L_(B)and L_(C) are each independently selected from the group consisting of:

where each Y¹ to Y¹³ are independently selected from the groupconsisting of carbon and nitrogen; Y′ is selected from the groupconsisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) areoptionally fused or joined to form a ring; each R_(e) and R_(f) isindependently selected from the group consisting of hydrogen, deuterium,halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl,alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl,alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof; each R_(a), R_(b), R_(e), and R_(d) may independently representfrom mono substitution to the maximum possible number of substitutions,or no substitution; each R_(a), R_(b), R_(e), and R_(d) is independentlyhydrogen or a substituent selected from the group consisting of thegeneral substituents defined herein; and any two adjacent substituentsof R_(a), R_(b), R_(e), and R_(d) can be optionally fused or joined toform a ring or form a multidentate ligand.

In some embodiments, the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), where L_(B) and L_(C) are each abidentate ligand; and x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2;and x+y+z is the oxidation state of the metal M, L_(B) and L_(C) areeach independently selected from the group consisting of:

In some embodiments of the compound where the first ligand L_(A) isselected from the group consisting of ligands L_(A1-O) to L_(A384-O),L_(A1-S) to L_(A384-S), L_(A1-C) to L_(A384-C), L_(A385-O) toL_(A420-O), L_(A385-S) to L_(A420-S), and L_(A385-C) to L_(A420-C),L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), L_(A421-C) toL_(A1152-C), L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S),L_(A1153-C) to L_(A1763-C), and L_(A1764-C) as defined above, thecompound is Compound Ai-F having the formula Ir(L_(Ai-F))₃, the CompoundBy-F having the formula Ir(L_(Ai-F))(L_(Bk))₂, or the Compound Cz-Fhaving the formula Ir(L_(Ai-F))₂(L_(Cj));

where i is an integer from 1 to 1764, and k is an integer from 1 to 490,and j is an integer from 1 to 1260, y=490i+k−4908, z=1764i+j−1764, and Fis O, S, or C;

where L_(Bk) is selected from the group consisting of the followingstructures:

where L_(C1) through L_(C1260) are based on a structure of Formula X

in which R¹, R², and R³ are defined as:

Ligand R¹ R² R³ L_(C1) R^(D1) R^(D1) H L_(C2) R^(D2) R^(D2) H L_(C3)R^(D3) R^(D3) H L_(C4) R^(D4) R^(D4) H L_(C5) R^(D5) R^(D5) H L_(C6)R^(D6) R^(D6) H L_(C7) R^(D7) R^(D7) H L_(C8) R^(D8) R^(D8) H L_(C9)R^(D9) R^(D9) H L_(C10) R^(D10) R^(D10) H L_(C11) R^(D11) R^(D11) HL_(C12) R^(D12) R^(D12) H L_(C13) R^(D13) R^(D13) H L_(C14) R^(D14)R^(D14) H L_(C15) R^(D15) R^(D15) H L_(C16) R^(D16) R^(D16) H L_(C17)R^(D17) R^(D17) H L_(C18) R^(D18) R^(D18) H L_(C19) R^(D19) R^(D19) HL_(C20) R^(D20) R^(D20) H L_(C21) R^(D21) R^(D21) H L_(C22) R^(D22)R^(D22) H L_(C23) R^(D23) R^(D23) H L_(C24) R^(D24) R^(D24) H L_(C25)R^(D25) R^(D25) H L_(C26) R^(D26) R^(D26) H L_(C27) R^(D27) R^(D27) HL_(C28) R^(D28) R^(D28) H L_(C29) R^(D29) R^(D29) H L_(C30) R^(D30)R^(D30) H L_(C31) R^(D31) R^(D31) H L_(C32) R^(D32) R^(D32) H L_(C33)R^(D33) R^(D33) H L_(C34) R^(D34) R^(D34) H L_(C35) R^(D35) R^(D35) HL_(C36) R^(D40) R^(D40) H L_(C37) R^(D41) R^(D41) H L_(C38) R^(D42)R^(D42) H L_(C39) R^(D64) R^(D64) H L_(C40) R^(D66) R^(D66) H L_(C41)R^(D68) R^(D68) H L_(C42) R^(D76) R^(D76) H L_(C43) R^(D1) R^(D2) HL_(C44) R^(D1) R^(D3) H L_(C45) R^(D1) R^(D4) H L_(C46) R^(D1) R^(D5) HL_(C47) R^(D1) R^(D6) H L_(C48) R^(D1) R^(D7) H L_(C49) R^(D1) R^(D8) HL_(C50) R^(D1) R^(D9) H L_(C51) R^(D1) R^(D10) H L_(C52) R^(D1) R^(D11)H L_(C53) R^(D1) R^(D12) H L_(C54) R^(D1) R^(D13) H L_(C55) R^(D1)R^(D14) H L_(C56) R^(D1) R^(D15) H L_(C57) R^(D1) R^(D16) H L_(C58)R^(D1) R^(D17) H L_(C59) R^(D1) R^(D18) H L_(C60) R^(D1) R^(D19) HL_(C61) R^(D1) R^(D20) H L_(C62) R^(D1) R^(D21) H L_(C63) R^(D1) R^(D22)H L_(C64) R^(D1) R^(D23) H L_(C65) R^(D1) R^(D24) H L_(C66) R^(D1)R^(D25) H L_(C67) R^(D1) R^(D26) H L_(C68) R^(D1) R^(D27) H L_(C69)R^(D1) R^(D28) H L_(C70) R^(D1) R^(D29) H L_(C71) R^(D1) R^(D30) HL_(C72) R^(D1) R^(D31) H L_(C73) R^(D1) R^(D32) H L_(C74) R^(D1) R^(D33)H L_(C75) R^(D1) R^(D34) H L_(C76) R^(D1) R^(D35) H L_(C77) R^(D1)R^(D40) H L_(C78) R^(D1) R^(D41) H L_(C79) R^(D1) R^(D42) H L_(C80)R^(D1) R^(D64) H L_(C81) R^(D1) R^(D66) H L_(C82) R^(D1) R^(D68) HL_(C83) R^(D1) R^(D76) H L_(C84) R^(D2) R^(D1) H L_(C85) R^(D2) R^(D3) HL_(C86) R^(D2) R^(D4) H L_(C87) R^(D2) R^(D5) H L_(C88) R^(D2) R^(D6) HL_(C89) R^(D2) R^(D7) H L_(C90) R^(D2) R^(D8) H L_(C91) R^(D2) R^(D9) HL_(C92) R^(D2) R^(D10) H L_(C93) R^(D2) R^(D11) H L_(C94) R^(D2) R^(D12)H L_(C95) R^(D2) R^(D13) H L_(C96) R^(D2) R^(D14) H L_(C97) R^(D2)R^(D15) H L_(C98) R^(D2) R^(D16) H L_(C99) R^(D2) R^(D17) H L_(C100)R^(D2) R^(D18) H L_(C101) R^(D2) R^(D19) H L_(C102) R^(D2) R^(D20) HL_(C103) R^(D2) R^(D21) H L_(C104) R^(D2) R^(D22) H L_(C105) R^(D2)R^(D23) H L_(C106) R^(D2) R^(D24) H L_(C107) R^(D2) R^(D25) H L_(C108)R^(D2) R^(D26) H L_(C109) R^(D2) R^(D27) H L_(C110) R^(D2) R^(D28) HL_(C111) R^(D2) R^(D29) H L_(C112) R^(D2) R^(D30) H L_(C113) R^(D2)R^(D31) H L_(C114) R^(D2) R^(D32) H L_(C115) R^(D2) R^(D33) H L_(C116)R^(D2) R^(D34) H L_(C117) R^(D2) R^(D35) H L_(C118) R^(D2) R^(D40) HL_(C119) R^(D2) R^(D41) H L_(C120) R^(D2) R^(D42) H L_(C121) R^(D2)R^(D64) H L_(C122) R^(D2) R^(D66) H L_(C123) R^(D2) R^(D68) H L_(C124)R^(D2) R^(D76) H L_(C125) R^(D3) R^(D4) H L_(C126) R^(D3) R^(D5) HL_(C127) R^(D3) R^(D6) H L_(C128) R^(D3) R^(D7) H L_(C129) R^(D3) R^(D8)H L_(C130) R^(D3) R^(D9) H L_(C131) R^(D3) R^(D10) H L_(C132) R^(D3)R^(D11) H L_(C133) R^(D3) R^(D12) H L_(C134) R^(D3) R^(D13) H L_(C135)R^(D3) R^(D14) H L_(C136) R^(D3) R^(D15) H L_(C137) R^(D3) R^(D16) HL_(C138) R^(D3) R^(D17) H L_(C139) R^(D3) R^(D18) H L_(C140) R^(D3)R^(D19) H L_(C141) R^(D3) R^(D20) H L_(C142) R^(D3) R^(D21) H L_(C143)R^(D3) R^(D22) H L_(C144) R^(D3) R^(D23) H L_(C145) R^(D3) R^(D24) HL_(C146) R^(D3) R^(D25) H L_(C147) R^(D3) R^(D26) H L_(C148) R^(D3)R^(D27) H L_(C149) R^(D3) R^(D28) H L_(C150) R^(D3) R^(D29) H L_(C151)R^(D3) R^(D30) H L_(C152) R^(D3) R^(D31) H L_(C153) R^(D3) R^(D32) HL_(C154) R^(D3) R^(D33) H L_(C155) R^(D3) R^(D34) H L_(C156) R^(D3)R^(D35) H L_(C157) R^(D3) R^(D40) H L_(C158) R^(D3) R^(D41) H L_(C159)R^(D3) R^(D42) H L_(C160) R^(D3) R^(D64) H L_(C161) R^(D3) R^(D66) HL_(C162) R^(D3) R^(D68) H L_(C163) R^(D3) R^(D76) H L_(C164) R^(D4)R^(D5) H L_(C165) R^(D4) R^(D6) H L_(C166) R^(D4) R^(D7) H L_(C167)R^(D4) R^(D8) H L_(C168) R^(D4) R^(D9) H L_(C169) R^(D4) R^(D10) HL_(C170) R^(D4) R^(D11) H L_(C171) R^(D4) R^(D12) H L_(C172) R^(D4)R^(D13) H L_(C173) R^(D4) R^(D14) H L_(C174) R^(D4) R^(D15) H L_(C175)R^(D4) R^(D16) H L_(C176) R^(D4) R^(D17) H L_(C177) R^(D4) R^(D18) HL_(C178) R^(D4) R^(D19) H L_(C179) R^(D4) R^(D20) H L_(C180) R^(D4)R^(D21) H L_(C181) R^(D4) R^(D22) H L_(C182) R^(D4) R^(D23) H L_(C183)R^(D4) R^(D24) H L_(C184) R^(D4) R^(D25) H L_(C185) R^(D4) R^(D26) HL_(C186) R^(D4) R^(D27) H L_(C187) R^(D4) R^(D28) H L_(C188) R^(D4)R^(D29) H L_(C189) R^(D4) R^(D30) H L_(C190) R^(D4) R^(D31) H L_(C191)R^(D4) R^(D32) H L_(C192) R^(D4) R^(D33) H L_(C193) R^(D4) R^(D34) HL_(C194) R^(D4) R^(D35) H L_(C195) R^(D4) R^(D40) H L_(C196) R^(D4)R^(D41) H L_(C197) R^(D4) R^(D42) H L_(C198) R^(D4) R^(D64) H L_(C199)R^(D4) R^(D66) H L_(C200) R^(D4) R^(D68) H L_(C201) R^(D4) R^(D76) HL_(C202) R^(D4) R^(D1) H L_(C203) R^(D7) R^(D5) H L_(C204) R^(D7) R^(D6)H L_(C205) R^(D7) R^(D8) H L_(C206) R^(D7) R^(D9) H L_(C207) R^(D7)R^(D10) H L_(C208) R^(D7) R^(D11) H L_(C209) R^(D7) R^(D12) H L_(C210)R^(D7) R^(D13) H L_(C211) R^(D7) R^(D14) H L_(C212) R^(D7) R^(D15) HL_(C213) R^(D7) R^(D16) H L_(C214) R^(D7) R^(D17) H L_(C215) R^(D7)R^(D18) H L_(C216) R^(D7) R^(D19) H L_(C217) R^(D7) R^(D20) H L_(C218)R^(D7) R^(D21) H L_(C219) R^(D7) R^(D22) H L_(C220) R^(D7) R^(D23) HL_(C221) R^(D7) R^(D24) H L_(C222) R^(D7) R^(D25) H L_(C223) R^(D7)R^(D26) H L_(C224) R^(D7) R^(D27) H L_(C225) R^(D7) R^(D28) H L_(C226)R^(D7) R^(D29) H L_(C227) R^(D7) R^(D30) H L_(C228) R^(D7) R^(D31) HL_(C229) R^(D7) R^(D32) H L_(C230) R^(D7) R^(D33) H L_(C231) R^(D7)R^(D34) H L_(C232) R^(D7) R^(D35) H L_(C233) R^(D7) R^(D40) H L_(C234)R^(D7) R^(D41) H L_(C235) R^(D7) R^(D42) H L_(C236) R^(D7) R^(D64) HL_(C237) R^(D7) R^(D66) H L_(C238) R^(D7) R^(D68) H L_(C239) R^(D7)R^(D76) H L_(C240) R^(D8) R^(D5) H L_(C241) R^(D8) R^(D6) H L_(C242)R^(D8) R^(D9) H L_(C243) R^(D8) R^(D10) H L_(C244) R^(D8) R^(D11) HL_(C245) R^(D8) R^(D12) H L_(C246) R^(D8) R^(D13) H L_(C247) R^(D8)R^(D14) H L_(C248) R^(D8) R^(D15) H L_(C249) R^(D8) R^(D16) H L_(C250)R^(D8) R^(D17) H L_(C251) R^(D8) R^(D18) H L_(C252) R^(D8) R^(D19) HL_(C253) R^(D8) R^(D20) H L_(C254) R^(D8) R^(D21) H L_(C255) R^(D8)R^(D22) H L_(C256) R^(D8) R^(D23) H L_(C257) R^(D8) R^(D24) H L_(C258)R^(D8) R^(D25) H L_(C259) R^(D8) R^(D26) H L_(C260) R^(D8) R^(D27) HL_(C261) R^(D8) R^(D28) H L_(C262) R^(D8) R^(D29) H L_(C263) R^(D8)R^(D30) H L_(C264) R^(D8) R^(D31) H L_(C265) R^(D8) R^(D32) H L_(C266)R^(D8) R^(D33) H L_(C267) R^(D8) R^(D34) H L_(C268) R^(D8) R^(D35) HL_(C269) R^(D8) R^(D40) H L_(C270) R^(D8) R^(D41) H L_(C271) R^(D8)R^(D42) H L_(C272) R^(D8) R^(D64) H L_(C273) R^(D8) R^(D66) H L_(C274)R^(D8) R^(D68) H L_(C275) R^(D8) R^(D76) H L_(C276) R^(D11) R^(D5) HL_(C277) R^(D11) R^(D6) H L_(C278) R^(D11) R^(D9) H L_(C279) R^(D11)R^(D10) H L_(C280) R^(D11) R^(D12) H L_(C281) R^(D11) R^(D13) H L_(C282)R^(D11) R^(D14) H L_(C283) R^(D11) R^(D15) H L_(C284) R^(D11) R^(D16) HL_(C285) R^(D11) R^(D17) H L_(C286) R^(D11) R^(D18) H L_(C287) R^(D11)R^(D19) H L_(C288) R^(D11) R^(D20) H L_(C289) R^(D11) R^(D21) H L_(C290)R^(D11) R^(D22) H L_(C291) R^(D11) R^(D23) H L_(C292) R^(D11) R^(D24) HL_(C293) R^(D11) R^(D25) H L_(C294) R^(D11) R^(D26) H L_(C295) R^(D11)R^(D27) H L_(C296) R^(D11) R^(D28) H L_(C297) R^(D11) R^(D29) H L_(C298)R^(D11) R^(D30) H L_(C299) R^(D11) R^(D31) H L_(C300) R^(D11) R^(D32) HL_(C301) R^(D11) R^(D33) H L_(C302) R^(D11) R^(D34) H L_(C303) R^(D11)R^(D35) H L_(C304) R^(D11) R^(D40) H L_(C305) R^(D11) R^(D41) H L_(C306)R^(D11) R^(D42) H L_(C307) R^(D11) R^(D64) H L_(C308) R^(D11) R^(D66) HL_(C309) R^(D11) R^(D68) H L_(C310) R^(D11) R^(D76) H L_(C311) R^(D13)R^(D5) H L_(C312) R^(D13) R^(D6) H L_(C313) R^(D13) R^(D9) H L_(C314)R^(D13) R^(D10) H L_(C315) R^(D13) R^(D12) H L_(C316) R^(D13) R^(D14) HL_(C317) R^(D13) R^(D15) H L_(C318) R^(D13) R^(D16) H L_(C319) R^(D13)R^(D17) H L_(C320) R^(D13) R^(D18) H L_(C321) R^(D13) R^(D19) H L_(C322)R^(D13) R^(D20) H L_(C323) R^(D13) R^(D21) H L_(C324) R^(D13) R^(D22) HL_(C325) R^(D13) R^(D23) H L_(C326) R^(D13) R^(D24) H L_(C327) R^(D13)R^(D25) H L_(C328) R^(D13) R^(D26) H L_(C329) R^(D13) R^(D27) H L_(C330)R^(D13) R^(D28) H L_(C331) R^(D13) R^(D29) H L_(C332) R^(D13) R^(D30) HL_(C333) R^(D13) R^(D31) H L_(C334) R^(D13) R^(D32) H L_(C335) R^(D13)R^(D33) H L_(C336) R^(D13) R^(D34) H L_(C337) R^(D13) R^(D35) H L_(C338)R^(D13) R^(D40) H L_(C339) R^(D13) R^(D41) H L_(C340) R^(D13) R^(D42) HL_(C341) R^(D13) R^(D64) H L_(C342) R^(D13) R^(D66) H L_(C343) R^(D13)R^(D68) H L_(C344) R^(D13) R^(D76) H L_(C345) R^(D14) R^(D5) H L_(C346)R^(D14) R^(D6) H L_(C347) R^(D14) R^(D9) H L_(C348) R^(D14) R^(D10) HL_(C349) R^(D14) R^(D12) H L_(C350) R^(D14) R^(D15) H L_(C351) R^(D14)R^(D16) H L_(C352) R^(D14) R^(D17) H L_(C353) R^(D14) R^(D18) H L_(C354)R^(D14) R^(D19) H L_(C355) R^(D14) R^(D20) H L_(C356) R^(D14) R^(D21) HL_(C357) R^(D14) R^(D22) H L_(C358) R^(D14) R^(D23) H L_(C359) R^(D14)R^(D24) H L_(C360) R^(D14) R^(D25) H L_(C361) R^(D14) R^(D26) H L_(C362)R^(D14) R^(D27) H L_(C363) R^(D14) R^(D28) H L_(C364) R^(D14) R^(D29) HL_(C365) R^(D14) R^(D30) H L_(C366) R^(D14) R^(D31) H L_(C367) R^(D14)R^(D32) H L_(C368) R^(D14) R^(D33) H L_(C369) R^(D14) R^(D34) H L_(C370)R^(D14) R^(D35) H L_(C371) R^(D14) R^(D40) H L_(C372) R^(D14) R^(D41) HL_(C373) R^(D14) R^(D42) H L_(C374) R^(D14) R^(D64) H L_(C375) R^(D14)R^(D66) H L_(C376) R^(D14) R^(D68) H L_(C377) R^(D14) R^(D76) H L_(C378)R^(D22) R^(D5) H L_(C379) R^(D22) R^(D6) H L_(C380) R^(D22) R^(D9) HL_(C381) R^(D22) R^(D10) H L_(C382) R^(D22) R^(D12) H L_(C383) R^(D22)R^(D15) H L_(C384) R^(D22) R^(D16) H L_(C385) R^(D22) R^(D17) H L_(C386)R^(D22) R^(D18) H L_(C387) R^(D22) R^(D19) H L_(C388) R^(D22) R^(D20) HL_(C389) R^(D22) R^(D21) H L_(C390) R^(D22) R^(D23) H L_(C391) R^(D22)R^(D24) H L_(C392) R^(D22) R^(D25) H L_(C393) R^(D22) R^(D26) H L_(C394)R^(D22) R^(D27) H L_(C395) R^(D22) R^(D28) H L_(C396) R^(D22) R^(D29) HL_(C397) R^(D22) R^(D30) H L_(C398) R^(D22) R^(D31) H L_(C399) R^(D22)R^(D32) H L_(C400) R^(D22) R^(D33) H L_(C401) R^(D22) R^(D34) H L_(C402)R^(D22) R^(D35) H L_(C403) R^(D22) R^(D40) H L_(C404) R^(D22) R^(D41) HL_(C405) R^(D22) R^(D42) H L_(C406) R^(D22) R^(D64) H L_(C407) R^(D22)R^(D66) H L_(C408) R^(D22) R^(D68) H L_(C409) R^(D22) R^(D76) H L_(C410)R^(D26) R^(D5) H L_(C411) R^(D26) R^(D6) H L_(C412) R^(D26) R^(D9) HL_(C413) R^(D26) R^(D10) H L_(C414) R^(D26) R^(D12) H L_(C415) R^(D26)R^(D15) H L_(C416) R^(D26) R^(D16) H L_(C417) R^(D26) R^(D17) H L_(C418)R^(D26) R^(D18) H L_(C419) R^(D26) R^(D19) H L_(C420) R^(D26) R^(D20) HL_(C421) R^(D26) R^(D21) H L_(C422) R^(D26) R^(D23) H L_(C423) R^(D26)R^(D24) H L_(C424) R^(D26) R^(D25) H L_(C425) R^(D26) R^(D27) H L_(C426)R^(D26) R^(D28) H L_(C427) R^(D26) R^(D29) H L_(C428) R^(D26) R^(D30) HL_(C429) R^(D26) R^(D31) H L_(C430) R^(D26) R^(D32) H L_(C431) R^(D26)R^(D33) H L_(C432) R^(D26) R^(D34) H L_(C433) R^(D26) R^(D35) H L_(C434)R^(D26) R^(D40) H L_(C435) R^(D26) R^(D41) H L_(C436) R^(D26) R^(D42) HL_(C437) R^(D26) R^(D64) H L_(C438) R^(D26) R^(D66) H L_(C439) R^(D26)R^(D68) H L_(C440) R^(D26) R^(D76) H L_(C441) R^(D35) R^(D5) H L_(C442)R^(D35) R^(D6) H L_(C443) R^(D35) R^(D9) H L_(C444) R^(D35) R^(D10) HL_(C445) R^(D35) R^(D12) H L_(C446) R^(D35) R^(D15) H L_(C447) R^(D35)R^(D16) H L_(C448) R^(D35) R^(D17) H L_(C449) R^(D35) R^(D18) H L_(C450)R^(D35) R^(D19) H L_(C451) R^(D35) R^(D20) H L_(C452) R^(D35) R^(D21) HL_(C453) R^(D35) R^(D23) H L_(C454) R^(D35) R^(D24) H L_(C455) R^(D35)R^(D25) H L_(C456) R^(D35) R^(D27) H L_(C457) R^(D35) R^(D28) H L_(C458)R^(D35) R^(D29) H L_(C459) R^(D35) R^(D30) H L_(C460) R^(D35) R^(D31) HL_(C461) R^(D35) R^(D32) H L_(C462) R^(D35) R^(D33) H L_(C463) R^(D35)R^(D34) H L_(C464) R^(D35) R^(D40) H L_(C465) R^(D35) R^(D41) H L_(C466)R^(D35) R^(D42) H L_(C467) R^(D35) R^(D64) H L_(C468) R^(D35) R^(D66) HL_(C469) R^(D35) R^(D68) H L_(C470) R^(D35) R^(D76) H L_(C471) R^(D40)R^(D5) H L_(C472) R^(D40) R^(D6) H L_(C473) R^(D40) R^(D9) H L_(C474)R^(D40) R^(D10) H L_(C475) R^(D40) R^(D12) H L_(C476) R^(D40) R^(D15) HL_(C477) R^(D40) R^(D16) H L_(C478) R^(D40) R^(D17) H L_(C479) R^(D40)R^(D18) H L_(C480) R^(D40) R^(D19) H L_(C481) R^(D40) R^(D20) H L_(C482)R^(D40) R^(D21) H L_(C483) R^(D40) R^(D23) H L_(C484) R^(D40) R^(D24) HL_(C485) R^(D40) R^(D25) H L_(C486) R^(D40) R^(D27) H L_(C487) R^(D40)R^(D28) H L_(C488) R^(D40) R^(D29) H L_(C489) R^(D40) R^(D30) H L_(C490)R^(D40) R^(D31) H L_(C491) R^(D40) R^(D32) H L_(C492) R^(D40) R^(D33) HL_(C493) R^(D40) R^(D34) H L_(C494) R^(D40) R^(D41) H L_(C495) R^(D40)R^(D42) H L_(C496) R^(D40) R^(D64) H L_(C497) R^(D40) R^(D66) H L_(C498)R^(D40) R^(D68) H L_(C499) R^(D40) R^(D76) H L_(C500) R^(D41) R^(D5) HL_(C501) R^(D41) R^(D6) H L_(C502) R^(D41) R^(D9) H L_(C503) R^(D41)R^(D10) H L_(C504) R^(D41) R^(D12) H L_(C505) R^(D41) R^(D15) H L_(C506)R^(D41) R^(D16) H L_(C507) R^(D41) R^(D17) H L_(C508) R^(D41) R^(D18) HL_(C509) R^(D41) R^(D19) H L_(C510) R^(D41) R^(D20) H L_(C511) R^(D41)R^(D21) H L_(C512) R^(D41) R^(D23) H L_(C513) R^(D41) R^(D24) H L_(C514)R^(D41) R^(D25) H L_(C515) R^(D41) R^(D27) H L_(C516) R^(D41) R^(D28) HL_(C517) R^(D41) R^(D29) H L_(C518) R^(D41) R^(D30) H L_(C519) R^(D41)R^(D31) H L_(C520) R^(D41) R^(D32) H L_(C521) R^(D41) R^(D33) H L_(C522)R^(D41) R^(D34) H L_(C523) R^(D41) R^(D42) H L_(C524) R^(D41) R^(D64) HL_(C525) R^(D41) R^(D66) H L_(C526) R^(D41) R^(D68) H L_(C527) R^(D41)R^(D76) H L_(C528) R^(D64) R^(D5) H L_(C529) R^(D64) R^(D6) H L_(C530)R^(D64) R^(D9) H L_(C531) R^(D64) R^(D10) H L_(C532) R^(D64) R^(D12) HL_(C533) R^(D64) R^(D15) H L_(C534) R^(D64) R^(D16) H L_(C535) R^(D64)R^(D17) H L_(C536) R^(D64) R^(D18) H L_(C537) R^(D64) R^(D19) H L_(C538)R^(D64) R^(D20) H L_(C539) R^(D64) R^(D21) H L_(C540) R^(D64) R^(D23) HL_(C541) R^(D64) R^(D24) H L_(C542) R^(D64) R^(D25) H L_(C543) R^(D64)R^(D27) H L_(C544) R^(D64) R^(D28) H L_(C545) R^(D64) R^(D29) H L_(C546)R^(D64) R^(D30) H L_(C547) R^(D64) R^(D31) H L_(C548) R^(D64) R^(D32) HL_(C549) R^(D64) R^(D33) H L_(C550) R^(D64) R^(D34) H L_(C551) R^(D64)R^(D42) H L_(C552) R^(D64) R^(D64) H L_(C553) R^(D64) R^(D66) H L_(C554)R^(D64) R^(D68) H L_(C555) R^(D64) R^(D76) H L_(C556) R^(D66) R^(D5) HL_(C557) R^(D66) R^(D6) H L_(C558) R^(D66) R^(D9) H L_(C559) R^(D66)R^(D10) H L_(C560) R^(D66) R^(D12) H L_(C561) R^(D66) R^(D15) H L_(C562)R^(D66) R^(D16) H L_(C563) R^(D66) R^(D17) H L_(C564) R^(D66) R^(D18) HL_(C565) R^(D66) R^(D19) H L_(C566) R^(D66) R^(D20) H L_(C567) R^(D66)R^(D21) H L_(C568) R^(D66) R^(D23) H L_(C569) R^(D66) R^(D24) H L_(C570)R^(D66) R^(D25) H L_(C571) R^(D66) R^(D27) H L_(C572) R^(D66) R^(D28) HL_(C573) R^(D66) R^(D29) H L_(C574) R^(D66) R^(D30) H L_(C575) R^(D66)R^(D31) H L_(C576) R^(D66) R^(D32) H L_(C577) R^(D66) R^(D33) H L_(C578)R^(D66) R^(D34) H L_(C579) R^(D66) R^(D42) H L_(C580) R^(D66) R^(D68) HL_(C581) R^(D66) R^(D76) H L_(C582) R^(D68) R^(D5) H L_(C583) R^(D68)R^(D6) H L_(C584) R^(D68) R^(D9) H L_(C585) R^(D68) R^(D10) H L_(C586)R^(D68) R^(D12) H L_(C587) R^(D68) R^(D15) H L_(C588) R^(D68) R^(D16) HL_(C589) R^(D68) R^(D17) H L_(C590) R^(D68) R^(D18) H L_(C591) R^(D68)R^(D19) H L_(C592) R^(D68) R^(D20) H L_(C593) R^(D68) R^(D21) H L_(C594)R^(D68) R^(D23) H L_(C595) R^(D68) R^(D24) H L_(C596) R^(D68) R^(D25) HL_(C597) R^(D68) R^(D27) H L_(C598) R^(D68) R^(D28) H L_(C599) R^(D68)R^(D29) H L_(C600) R^(D68) R^(D30) H L_(C601) R^(D68) R^(D31) H L_(C602)R^(D68) R^(D32) H L_(C603) R^(D68) R^(D33) H L_(C604) R^(D68) R^(D34) HL_(C605) R^(D68) R^(D42) H L_(C606) R^(D68) R^(D76) H L_(C607) R^(D76)R^(D5) H L_(C608) R^(D76) R^(D6) H L_(C609) R^(D76) R^(D9) H L_(C610)R^(D76) R^(D10) H L_(C611) R^(D76) R^(D12) H L_(C612) R^(D76) R^(D15) HL_(C613) R^(D76) R^(D16) H L_(C614) R^(D76) R^(D17) H L_(C615) R^(D76)R^(D18) H L_(C616) R^(D76) R^(D19) H L_(C617) R^(D76) R^(D20) H L_(C618)R^(D76) R^(D21) H L_(C619) R^(D76) R^(D23) H L_(C620) R^(D76) R^(D24) HL_(C621) R^(D76) R^(D25) H L_(C622) R^(D76) R^(D27) H L_(C623) R^(D76)R^(D28) H L_(C624) R^(D76) R^(D29) H L_(C625) R^(D76) R^(D30) H L_(C626)R^(D76) R^(D31) H L_(C627) R^(D76) R^(D32) H L_(C628) R^(D76) R^(D33) HL_(C629) R^(D76) R^(D34) H L_(C630) R^(D76) R^(D42) H L_(C631) R^(D1)R^(D1) R^(D1) L_(C632) R^(D2) R^(D2) R^(D1) L_(C633) R^(D3) R^(D3)R^(D1) L_(C634) R^(D4) R^(D4) R^(D1) L_(C635) R^(D5) R^(D5) R^(D1)L_(C636) R^(D6) R^(D6) R^(D1) L_(C637) R^(D7) R^(D7) R^(D1) L_(C638)R^(D8) R^(D8) R^(D1) L_(C639) R^(D9) R^(D9) R^(D1) L_(C640) R^(D10)R^(D10) R^(D1) L_(C641) R^(D11) R^(D11) R^(D1) L_(C642) R^(D12) R^(D12)R^(D1) L_(C643) R^(D13) R^(D13) R^(D1) L_(C644) R^(D14) R^(D14) R^(D1)L_(C645) R^(D15) R^(D15) R^(D1) L_(C646) R^(D16) R^(D16) R^(D1) L_(C647)R^(D17) R^(D17) R^(D1) L_(C648) R^(D18) R^(D18) R^(D1) L_(C649) R^(D19)R^(D19) R^(D1) L_(C650) R^(D20) R^(D20) R^(D1) L_(C651) R^(D21) R^(D21)R^(D1) L_(C652) R^(D22) R^(D22) R^(D1) L_(C653) R^(D23) R^(D23) R^(D1)L_(C654) R^(D24) R^(D24) R^(D1) L_(C655) R^(D25) R^(D25) R^(D1) L_(C656)R^(D26) R^(D26) R^(D1) L_(C657) R^(D27) R^(D27) R^(D1) L_(C658) R^(D28)R^(D28) R^(D1) L_(C659) R^(D29) R^(D29) R^(D1) L_(C660) R^(D30) R^(D30)R^(D1) L_(C661) R^(D31) R^(D31) R^(D1) L_(C662) R^(D32) R^(D32) R^(D1)L_(C663) R^(D33) R^(D33) R^(D1) L_(C664) R^(D34) R^(D34) R^(D1) L_(C665)R^(D35) R^(D35) R^(D1) L_(C666) R^(D40) R^(D40) R^(D1) L_(C667) R^(D41)R^(D41) R^(D1) L_(C668) R^(D42) R^(D42) R^(D1) L_(C669) R^(D64) R^(D64)R^(D1) L_(C670) R^(D66) R^(D66) R^(D1) L_(C671) R^(D68) R^(D68) R^(D1)L_(C672) R^(D76) R^(D76) R^(D1) L_(C673) R^(D1) R^(D2) R^(D1) L_(C674)R^(D1) R^(D3) R^(D1) L_(C675) R^(D1) R^(D4) R^(D1) L_(C676) R^(D1)R^(D5) R^(D1) L_(C677) R^(D1) R^(D6) R^(D1) L_(C678) R^(D1) R^(D7)R^(D1) L_(C679) R^(D1) R^(D8) R^(D1) L_(C680) R^(D1) R^(D9) R^(D1)L_(C681) R^(D1) R^(D10) R^(D1) L_(C682) R^(D1) R^(D11) R^(D1) L_(C683)R^(D1) R^(D12) R^(D1) L_(C684) R^(D1) R^(D13) R^(D1) L_(C685) R^(D1)R^(D14) R^(D1) L_(C686) R^(D1) R^(D15) R^(D1) L_(C687) R^(D1) R^(D16)R^(D1) L_(C688) R^(D1) R^(D17) R^(D1) L_(C689) R^(D1) R^(D18) R^(D1)L_(C690) R^(D1) R^(D19) R^(D1) L_(C691) R^(D1) R^(D20) R^(D1) L_(C692)R^(D1) R^(D21) R^(D1) L_(C693) R^(D1) R^(D22) R^(D1) L_(C694) R^(D1)R^(D23) R^(D1) L_(C695) R^(D1) R^(D24) R^(D1) L_(C696) R^(D1) R^(D25)R^(D1) L_(C697) R^(D1) R^(D26) R^(D1) L_(C698) R^(D1) R^(D27) R^(D1)L_(C699) R^(D1) R^(D28) R^(D1) L_(C700) R^(D1) R^(D29) R^(D1) L_(C701)R^(D1) R^(D30) R^(D1) L_(C702) R^(D1) R^(D31) R^(D1) L_(C703) R^(D1)R^(D32) R^(D1) L_(C704) R^(D1) R^(D33) R^(D1) L_(C705) R^(D1) R^(D34)R^(D1) L_(C706) R^(D1) R^(D35) R^(D1) L_(C707) R^(D1) R^(D40) R^(D1)L_(C708) R^(D1) R^(D41) R^(D1) L_(C709) R^(D1) R^(D42) R^(D1) L_(C710)R^(D1) R^(D64) R^(D1) L_(C711) R^(D1) R^(D66) R^(D1) L_(C712) R^(D1)R^(D68) R^(D1) L_(C713) R^(D1) R^(D76) R^(D1) L_(C714) R^(D2) R^(D1)R^(D1) L_(C715) R^(D2) R^(D3) R^(D1) L_(C716) R^(D2) R^(D4) R^(D1)L_(C717) R^(D2) R^(D5) R^(D1) L_(C718) R^(D2) R^(D6) R^(D1) L_(C719)R^(D2) R^(D7) R^(D1) L_(C720) R^(D2) R^(D8) R^(D1) L_(C721) R^(D2)R^(D9) R^(D1) L_(C722) R^(D2) R^(D10) R^(D1) L_(C723) R^(D2) R^(D11)R^(D1) L_(C724) R^(D2) R^(D12) R^(D1) L_(C725) R^(D2) R^(D13) R^(D1)L_(C726) R^(D2) R^(D14) R^(D1) L_(C727) R^(D2) R^(D15) R^(D1) L_(C728)R^(D2) R^(D16) R^(D1) L_(C729) R^(D2) R^(D17) R^(D1) L_(C730) R^(D2)R^(D18) R^(D1) L_(C731) R^(D2) R^(D19) R^(D1) L_(C732) R^(D2) R^(D20)R^(D1) L_(C733) R^(D2) R^(D21) R^(D1) L_(C734) R^(D2) R^(D22) R^(D1)L_(C735) R^(D2) R^(D23) R^(D1) L_(C736) R^(D2) R^(D24) R^(D1) L_(C737)R^(D2) R^(D25) R^(D1) L_(C738) R^(D2) R^(D26) R^(D1) L_(C739) R^(D2)R^(D27) R^(D1) L_(C740) R^(D2) R^(D28) R^(D1) L_(C741) R^(D2) R^(D29)R^(D1) L_(C742) R^(D2) R^(D30) R^(D1) L_(C743) R^(D2) R^(D31) R^(D1)L_(C744) R^(D2) R^(D32) R^(D1) L_(C745) R^(D2) R^(D33) R^(D1) L_(C746)R^(D2) R^(D34) R^(D1) L_(C747) R^(D2) R^(D35) R^(D1) L_(C748) R^(D2)R^(D40) R^(D1) L_(C749) R^(D2) R^(D41) R^(D1) L_(C750) R^(D2) R^(D42)R^(D1) L_(C751) R^(D2) R^(D64) R^(D1) L_(C752) R^(D2) R^(D66) R^(D1)L_(C753) R^(D2) R^(D68) R^(D1) L_(C754) R^(D2) R^(D76) R^(D1) L_(C755)R^(D3) R^(D4) R^(D1) L_(C756) R^(D3) R^(D5) R^(D1) L_(C757) R^(D3)R^(D6) R^(D1) L_(C758) R^(D3) R^(D7) R^(D1) L_(C759) R^(D3) R^(D8)R^(D1) L_(C760) R^(D3) R^(D9) R^(D1) L_(C761) R^(D3) R^(D10) R^(D1)L_(C762) R^(D3) R^(D11) R^(D1) L_(C763) R^(D3) R^(D12) R^(D1) L_(C764)R^(D3) R^(D13) R^(D1) L_(C765) R^(D3) R^(D14) R^(D1) L_(C766) R^(D3)R^(D15) R^(D1) L_(C767) R^(D3) R^(D16) R^(D1) L_(C768) R^(D3) R^(D17)R^(D1) L_(C769) R^(D3) R^(D18) R^(D1) L_(C770) R^(D3) R^(D19) R^(D1)L_(C771) R^(D3) R^(D20) R^(D1) L_(C772) R^(D3) R^(D21) R^(D1) L_(C773)R^(D3) R^(D22) R^(D1) L_(C774) R^(D3) R^(D23) R^(D1) L_(C775) R^(D3)R^(D24) R^(D1) L_(C776) R^(D3) R^(D25) R^(D1) L_(C777) R^(D3) R^(D26)R^(D1) L_(C778) R^(D3) R^(D27) R^(D1) L_(C779) R^(D3) R^(D28) R^(D1)L_(C780) R^(D3) R^(D29) R^(D1) L_(C781) R^(D3) R^(D30) R^(D1) L_(C782)R^(D3) R^(D31) R^(D1) L_(C783) R^(D3) R^(D32) R^(D1) L_(C784) R^(D3)R^(D33) R^(D1) L_(C785) R^(D3) R^(D34) R^(D1) L_(C786) R^(D3) R^(D35)R^(D1) L_(C787) R^(D3) R^(D40) R^(D1) L_(C788) R^(D3) R^(D41) R^(D1)L_(C789) R^(D3) R^(D42) R^(D1) L_(C790) R^(D3) R^(D64) R^(D1) L_(C791)R^(D3) R^(D66) R^(D1) L_(C792) R^(D3) R^(D68) R^(D1) L_(C793) R^(D3)R^(D76) R^(D1) L_(C794) R^(D4) R^(D5) R^(D1) L_(C795) R^(D4) R^(D6)R^(D1) L_(C796) R^(D4) R^(D7) R^(D1) L_(C797) R^(D4) R^(D8) R^(D1)L_(C798) R^(D4) R^(D9) R^(D1) L_(C799) R^(D4) R^(D10) R^(D1) L_(C800)R^(D4) R^(D11) R^(D1) L_(C801) R^(D4) R^(D12) R^(D1) L_(C802) R^(D4)R^(D13) R^(D1) L_(C803) R^(D4) R^(D14) R^(D1) L_(C804) R^(D4) R^(D15)R^(D1) L_(C805) R^(D4) R^(D16) R^(D1) L_(C806) R^(D4) R^(D17) R^(D1)L_(C807) R^(D4) R^(D18) R^(D1) L_(C808) R^(D4) R^(D19) R^(D1) L_(C809)R^(D4) R^(D20) R^(D1) L_(C810) R^(D4) R^(D21) R^(D1) L_(C811) R^(D4)R^(D22) R^(D1) L_(C812) R^(D4) R^(D23) R^(D1) L_(C813) R^(D4) R^(D24)R^(D1) L_(C814) R^(D4) R^(D25) R^(D1) L_(C815) R^(D4) R^(D26) R^(D1)L_(C816) R^(D4) R^(D27) R^(D1) L_(C817) R^(D4) R^(D28) R^(D1) L_(C818)R^(D4) R^(D29) R^(D1) L_(C819) R^(D4) R^(D30) R^(D1) L_(C820) R^(D4)R^(D31) R^(D1) L_(C821) R^(D4) R^(D32) R^(D1) L_(C822) R^(D4) R^(D33)R^(D1) L_(C823) R^(D4) R^(D34) R^(D1) L_(C824) R^(D4) R^(D35) R^(D1)L_(C825) R^(D4) R^(D40) R^(D1) L_(C826) R^(D4) R^(D41) R^(D1) L_(C827)R^(D4) R^(D42) R^(D1) L_(C828) R^(D4) R^(D64) R^(D1) L_(C829) R^(D4)R^(D66) R^(D1) L_(C830) R^(D4) R^(D68) R^(D1) L_(C831) R^(D4) R^(D76)R^(D1) L_(C832) R^(D4) R^(D1) R^(D1) L_(C833) R^(D7) R^(D5) R^(D1)L_(C834) R^(D7) R^(D6) R^(D1) L_(C835) R^(D7) R^(D8) R^(D1) L_(C836)R^(D7) R^(D9) R^(D1) L_(C837) R^(D7) R^(D10) R^(D1) L_(C838) R^(D7)R^(D11) R^(D1) L_(C839) R^(D7) R^(D12) R^(D1) L_(C840) R^(D7) R^(D13)R^(D1) L_(C841) R^(D7) R^(D14) R^(D1) L_(C842) R^(D7) R^(D15) R^(D1)L_(C843) R^(D7) R^(D16) R^(D1) L_(C844) R^(D7) R^(D11) R^(D1) L_(C845)R^(D7) R^(D18) R^(D1) L_(C846) R^(D7) R^(D19) R^(D1) L_(C847) R^(D7)R^(D20) R^(D1) L_(C848) R^(D7) R^(D21) R^(D1) L_(C849) R^(D7) R^(D22)R^(D1) L_(C850) R^(D7) R^(D23) R^(D1) L_(C851) R^(D7) R^(D24) R^(D1)L_(C852) R^(D7) R^(D25) R^(D1) L_(C853) R^(D7) R^(D26) R^(D1) L_(C854)R^(D7) R^(D27) R^(D1) L_(C855) R^(D7) R^(D28) R^(D1) L_(C856) R^(D7)R^(D29) R^(D1) L_(C857) R^(D7) R^(D30) R^(D1) L_(C858) R^(D7) R^(D31)R^(D1) L_(C859) R^(D7) R^(D32) R^(D1) L_(C860) R^(D7) R^(D33) R^(D1)L_(C861) R^(D7) R^(D34) R^(D1) L_(C862) R^(D7) R^(D35) R^(D1) L_(C863)R^(D7) R^(D40) R^(D1) L_(C864) R^(D7) R^(D41) R^(D1) L_(C865) R^(D7)R^(D42) R^(D1) L_(C866) R^(D7) R^(D64) R^(D1) L_(C867) R^(D7) R^(D66)R^(D1) L_(C868) R^(D7) R^(D68) R^(D1) L_(C869) R^(D7) R^(D76) R^(D1)L_(C870) R^(D8) R^(D5) R^(D1) L_(C871) R^(D8) R^(D6) R^(D1) L_(C872)R^(D8) R^(D9) R^(D1) L_(C873) R^(D8) R^(D10) R^(D1) L_(C874) R^(D8)R^(D11) R^(D1) L_(C875) R^(D8) R^(D12) R^(D1) L_(C876) R^(D8) R^(D11)R^(D1) L_(C877) R^(D8) R^(D14) R^(D1) L_(C878) R^(D8) R^(D15) R^(D1)L_(C879) R^(D8) R^(D16) R^(D1) L_(C880) R^(D8) R^(D17) R^(D1) L_(C881)R^(D8) R^(D18) R^(D1) L_(C882) R^(D8) R^(D19) R^(D1) L_(C883) R^(D8)R^(D20) R^(D1) L_(C884) R^(D8) R^(D21) R^(D1) L_(C885) R^(D8) R^(D22)R^(D1) L_(C886) R^(D8) R^(D23) R^(D1) L_(C887) R^(D8) R^(D24) R^(D1)L_(C888) R^(D8) R^(D25) R^(D1) L_(C889) R^(D8) R^(D26) R^(D1) L_(C890)R^(D8) R^(D27) R^(D1) L_(C891) R^(D8) R^(D28) R^(D1) L_(C892) R^(D8)R^(D29) R^(D1) L_(C893) R^(D8) R^(D30) R^(D1) L_(C894) R^(D8) R^(D31)R^(D1) L_(C895) R^(D8) R^(D32) R^(D1) L_(C896) R^(D8) R^(D33) R^(D1)L_(C897) R^(D8) R^(D34) R^(D1) L_(C898) R^(D8) R^(D35) R^(D1) L_(C899)R^(D8) R^(D40) R^(D1) L_(C900) R^(D8) R^(D41) R^(D1) L_(C901) R^(D8)R^(D42) R^(D1) L_(C902) R^(D8) R^(D64) R^(D1) L_(C903) R^(D8) R^(D66)R^(D1) L_(C904) R^(D8) R^(D68) R^(D1) L_(C905) R^(D8) R^(D76) R^(D1)L_(C906) R^(D11) R^(D5) R^(D1) L_(C907) R^(D11) R^(D6) R^(D1) L_(C908)R^(D11) R^(D9) R^(D1) L_(C909) R^(D11) R^(D10) R^(D1) L_(C910) R^(D11)R^(D12) R^(D1) L_(C911) R^(D11) R^(D13) R^(D1) L_(C912) R^(D11) R^(D14)R^(D1) L_(C913) R^(D11) R^(D15) R^(D1) L_(C914) R^(D11) R^(D16) R^(D1)L_(C915) R^(D11) R^(D17) R^(D1) L_(C916) R^(D11) R^(D18) R^(D1) L_(C917)R^(D11) R^(D19) R^(D1) L_(C918) R^(D11) R^(D20) R^(D1) L_(C919) R^(D11)R^(D21) R^(D1) L_(C920) R^(D11) R^(D22) R^(D1) L_(C921) R^(D11) R^(D23)R^(D1) L_(C922) R^(D11) R^(D24) R^(D1) L_(C923) R^(D11) R^(D25) R^(D1)L_(C924) R^(D11) R^(D26) R^(D1) L_(C925) R^(D11) R^(D27) R^(D1) L_(C926)R^(D11) R^(D28) R^(D1) L_(C927) R^(D11) R^(D29) R^(D1) L_(C928) R^(D11)R^(D30) R^(D1) L_(C929) R^(D11) R^(D31) R^(D1) L_(C930) R^(D11) R^(D32)R^(D1) L_(C931) R^(D11) R^(D33) R^(D1) L_(C932) R^(D11) R^(D34) R^(D1)L_(C933) R^(D11) R^(D35) R^(D1) L_(C934) R^(D11) R^(D40) R^(D1) L_(C935)R^(D11) R^(D41) R^(D1) L_(C936) R^(D11) R^(D42) R^(D1) L_(C937) R^(D11)R^(D64) R^(D1) L_(C938) R^(D11) R^(D66) R^(D1) L_(C939) R^(D11) R^(D68)R^(D1) L_(C940) R^(D11) R^(D76) R^(D1) L_(C941) R^(D11) R^(D5) R^(D1)L_(C942) R^(D13) R^(D6) R^(D1) L_(C943) R^(D11) R^(D9) R^(D1) L_(C944)R^(D13) R^(D10) R^(D1) L_(C945) R^(D13) R^(D12) R^(D1) L_(C946) R^(D13)R^(D14) R^(D1) L_(C947) R^(D11) R^(D15) R^(D1) L_(C948) R^(D13) R^(D16)R^(D1) L_(C949) R^(D13) R^(D17) R^(D1) L_(C950) R^(D13) R^(D18) R^(D1)L_(C951) R^(D11) R^(D19) R^(D1) L_(C952) R^(D13) R^(D20) R^(D1) L_(C953)R^(D13) R^(D21) R^(D1) L_(C954) R^(D13) R^(D22) R^(D1) L_(C955) R^(D13)R^(D23) R^(D1) L_(C956) R^(D13) R^(D24) R^(D1) L_(C957) R^(D13) R^(D25)R^(D1) L_(C958) R^(D13) R^(D26) R^(D1) L_(C959) R^(D13) R^(D27) R^(D1)L_(C960) R^(D13) R^(D28) R^(D1) L_(C961) R^(D13) R^(D29) R^(D1) L_(C962)R^(D13) R^(D30) R^(D1) L_(C963) R^(D13) R^(D31) R^(D1) L_(C964) R^(D13)R^(D32) R^(D1) L_(C965) R^(D13) R^(D33) R^(D1) L_(C966) R^(D13) R^(D34)R^(D1) L_(C967) R^(D13) R^(D35) R^(D1) L_(C968) R^(D13) R^(D40) R^(D1)L_(C969) R^(D13) R^(D41) R^(D1) L_(C970) R^(D13) R^(D42) R^(D1) L_(C971)R^(D13) R^(D64) R^(D1) L_(C972) R^(D13) R^(D66) R^(D1) L_(C973) R^(D13)R^(D68) R^(D1) L_(C974) R^(D13) R^(D76) R^(D1) L_(C975) R^(D14) R^(D5)R^(D1) L_(C976) R^(D14) R^(D6) R^(D1) L_(C977) R^(D14) R^(D9) R^(D1)L_(C978) R^(D14) R^(D10) R^(D1) L_(C979) R^(D14) R^(D12) R^(D1) L_(C980)R^(D14) R^(D15) R^(D1) L_(C981) R^(D14) R^(D10) R^(D1) L_(C982) R^(D14)R^(D17) R^(D1) L_(C983) R^(D14) R^(D18) R^(D1) L_(C984) R^(D14) R^(D19)R^(D1) L_(C985) R^(D14) R^(D20) R^(D1) L_(C986) R^(D14) R^(D21) R^(D1)L_(C987) R^(D14) R^(D22) R^(D1) L_(C988) R^(D14) R^(D23) R^(D1) L_(C989)R^(D14) R^(D24) R^(D1) L_(C990) R^(D14) R^(D25) R^(D1) L_(C991) R^(D14)R^(D26) R^(D1) L_(C992) R^(D14) R^(D27) R^(D1) L_(C993) R^(D14) R^(D28)R^(D1) L_(C994) R^(D14) R^(D29) R^(D1) L_(C995) R^(D14) R^(D30) R^(D1)L_(C996) R^(D14) R^(D31) R^(D1) L_(C997) R^(D14) R^(D32) R^(D1) L_(C998)R^(D14) R^(D33) R^(D1) L_(C999) R^(D14) R^(D34) R^(D1) L_(C1000) R^(D14)R^(D35) R^(D1) L_(C1001) R^(D14) R^(D40) R^(D1) L_(C1002) R^(D14)R^(D41) R^(D1) L_(C1003) R^(D14) R^(D42) R^(D1) L_(C1004) R^(D14)R^(D64) R^(D1) L_(C1005) R^(D14) R^(D66) R^(D1) L_(C1006) R^(D14)R^(D68) R^(D1) L_(C1007) R^(D14) R^(D76) R^(D1) L_(C1008) R^(D22) R^(D5)R^(D1) L_(C1009) R^(D22) R^(D6) R^(D1) L_(C1010) R^(D22) R^(D9) R^(D1)L_(C1011) R^(D22) R^(D10) R^(D1) L_(C1012) R^(D22) R^(D12) R^(D1)L_(C1013) R^(D22) R^(D15) R^(D1) L_(C1014) R^(D22) R^(D16) R^(D1)L_(C1015) R^(D22) R^(D17) R^(D1) L_(C1016) R^(D22) R^(D18) R^(D1)L_(C1017) R^(D22) R^(D19) R^(D1) L_(C1018) R^(D22) R^(D20) R^(D1)L_(C1019) R^(D22) R^(D21) R^(D1) L_(C1020) R^(D22) R^(D23) R^(D1)L_(C1021) R^(D22) R^(D24) R^(D1) L_(C1022) R^(D22) R^(D25) R^(D1)L_(C1023) R^(D22) R^(D26) R^(D1) L_(C1024) R^(D22) R^(D27) R^(D1)L_(C1025) R^(D22) R^(D28) R^(D1) L_(C1026) R^(D22) R^(D29) R^(D1)L_(C1027) R^(D22) R^(D30) R^(D1) L_(C1028) R^(D22) R^(D31) R^(D1)L_(C1029) R^(D22) R^(D32) R^(D1) L_(C1030) R^(D22) R^(D33) R^(D1)L_(C1031) R^(D22) R^(D34) R^(D1) L_(C1032) R^(D22) R^(D35) R^(D1)L_(C1033) R^(D22) R^(D40) R^(D1) L_(C1034) R^(D22) R^(D41) R^(D1)L_(C1035) R^(D22) R^(D42) R^(D1) L_(C1036) R^(D22) R^(D64) R^(D1)L_(C1037) R^(D22) R^(D66) R^(D1) L_(C1038) R^(D22) R^(D68) R^(D1)L_(C1039) R^(D22) R^(D76) R^(D1) L_(C1040) R^(D26) R^(D5) R^(D1)L_(C1041) R^(D26) R^(D6) R^(D1) L_(C1042) R^(D26) R^(D9) R^(D1)L_(C1043) R^(D26) R^(D10) R^(D1) L_(C1044) R^(D26) R^(D12) R^(D1)L_(C1045) R^(D26) R^(D15) R^(D1) L_(C1046) R^(D26) R^(D16) R^(D1)L_(C1047) R^(D26) R^(D17) R^(D1) L_(C1048) R^(D26) R^(D18) R^(D1)L_(C1049) R^(D26) R^(D19) R^(D1) L_(C1050) R^(D26) R^(D20) R^(D1)L_(C1051) R^(D26) R^(D21) R^(D1) L_(C1052) R^(D26) R^(D23) R^(D1)L_(C1053) R^(D26) R^(D24) R^(D1) L_(C1054) R^(D26) R^(D25) R^(D1)L_(C1055) R^(D26) R^(D27) R^(D1) L_(C1056) R^(D26) R^(D28) R^(D1)L_(C1057) R^(D26) R^(D29) R^(D1) L_(C1058) R^(D26) R^(D30) R^(D1)L_(C1059) R^(D26) R^(D31) R^(D1) L_(C1060) R^(D26) R^(D32) R^(D1)L_(C1061) R^(D26) R^(D33) R^(D1) L_(C1062) R^(D26) R^(D34) R^(D1)L_(C1063) R^(D26) R^(D35) R^(D1) L_(C1064) R^(D26) R^(D40) R^(D1)L_(C1065) R^(D26) R^(D41) R^(D1) L_(C1066) R^(D26) R^(D42) R^(D1)L_(C1067) R^(D26) R^(D64) R^(D1) L_(C1068) R^(D26) R^(D66) R^(D1)L_(C1069) R^(D26) R^(D68) R^(D1) L_(C1070) R^(D26) R^(D76) R^(D1)L_(C1071) R^(D35) R^(D5) R^(D1) L_(C1072) R^(D35) R^(D6) R^(D1)L_(C1073) R^(D35) R^(D9) R^(D1) L_(C1074) R^(D35) R^(D10) R^(D1)L_(C1075) R^(D35) R^(D12) R^(D1) L_(C1076) R^(D35) R^(D15) R^(D1)L_(C1077) R^(D35) R^(D16) R^(D1) L_(C1078) R^(D35) R^(D17) R^(D1)L_(C1079) R^(D35) R^(D18) R^(D1) L_(C1080) R^(D35) R^(D19) R^(D1)L_(C1081) R^(D35) R^(D20) R^(D1) L_(C1082) R^(D35) R^(D21) R^(D1)L_(C1083) R^(D35) R^(D23) R^(D1) L_(C1084) R^(D35) R^(D24) R^(D1)L_(C1085) R^(D35) R^(D25) R^(D1) L_(C1086) R^(D35) R^(D27) R^(D1)L_(C1087) R^(D35) R^(D28) R^(D1) L_(C1088) R^(D35) R^(D29) R^(D1)L_(C1089) R^(D35) R^(D30) R^(D1) L_(C1090) R^(D35) R^(D31) R^(D1)L_(C1091) R^(D35) R^(D32) R^(D1) L_(C1092) R^(D35) R^(D33) R^(D1)L_(C1093) R^(D35) R^(D34) R^(D1) L_(C1094) R^(D35) R^(D40) R^(D1)L_(C1095) R^(D35) R^(D41) R^(D1) L_(C1096) R^(D35) R^(D42) R^(D1)L_(C1097) R^(D35) R^(D64) R^(D1) L_(C1098) R^(D35) R^(D66) R^(D1)L_(C1099) R^(D35) R^(D68) R^(D1) L_(C1100) R^(D35) R^(D76) R^(D1)L_(C1101) R^(D40) R^(D5) R^(D1) L_(C1102) R^(D40) R^(D6) R^(D1)L_(C1103) R^(D40) R^(D9) R^(D1) L_(C1104) R^(D40) R^(D10) R^(D1)L_(C1105) R^(D40) R^(D12) R^(D1) L_(C1106) R^(D40) R^(D15) R^(D1)L_(C1107) R^(D40) R^(D16) R^(D1) L_(C1108) R^(D40) R^(D17) R^(D1)L_(C1109) R^(D40) R^(D18) R^(D1) L_(C1110) R^(D40) R^(D19) R^(D1)L_(C1111) R^(D40) R^(D20) R^(D1) L_(C1112) R^(D40) R^(D21) R^(D1)L_(C1113) R^(D40) R^(D23) R^(D1) L_(C1114) R^(D40) R^(D24) R^(D1)L_(C1115) R^(D40) R^(D25) R^(D1) L_(C1116) R^(D40) R^(D27) R^(D1)L_(C1117) R^(D40) R^(D28) R^(D1) L_(C1118) R^(D40) R^(D29) R^(D1)L_(C1119) R^(D40) R^(D30) R^(D1) L_(C1120) R^(D40) R^(D31) R^(D1)L_(C1121) R^(D40) R^(D32) R^(D1) L_(C1122) R^(D40) R^(D33) R^(D1)L_(C1123) R^(D40) R^(D34) R^(D1) L_(C1124) R^(D40) R^(D41) R^(D1)L_(C1125) R^(D40) R^(D42) R^(D1) L_(C1126) R^(D40) R^(D64) R^(D1)L_(C1127) R^(D40) R^(D66) R^(D1) L_(C1128) R^(D40) R^(D68) R^(D1)L_(C1129) R^(D40) R^(D76) R^(D1) L_(C1130) R^(D41) R^(D5) R^(D1)L_(C1131) R^(D41) R^(D6) R^(D1) L_(C1132) R^(D41) R^(D9) R^(D1)L_(C1133) R^(D41) R^(D10) R^(D1) L_(C1134) R^(D41) R^(D12) R^(D1)L_(C1135) R^(D41) R^(D15) R^(D1) L_(C1136) R^(D41) R^(D16) R^(D1)L_(C1137) R^(D41) R^(D17) R^(D1) L_(C1138) R^(D41) R^(D18) R^(D1)L_(C1139) R^(D41) R^(D19) R^(D1) L_(C1140) R^(D41) R^(D20) R^(D1)L_(C1141) R^(D41) R^(D21) R^(D1) L_(C1142) R^(D41) R^(D23) R^(D1)L_(C1143) R^(D41) R^(D24) R^(D1) L_(C1144) R^(D41) R^(D25) R^(D1)L_(C1145) R^(D41) R^(D27) R^(D1) L_(C1146) R^(D41) R^(D28) R^(D1)L_(C1147) R^(D41) R^(D29) R^(D1) L_(C1148) R^(D41) R^(D30) R^(D1)L_(C1149) R^(D41) R^(D31) R^(D1) L_(C1150) R^(D41) R^(D32) R^(D1)L_(C1151) R^(D41) R^(D33) R^(D1) L_(C1152) R^(D41) R^(D34) R^(D1)L_(C1153) R^(D41) R^(D42) R^(D1) L_(C1154) R^(D41) R^(D64) R^(D1)L_(C1155) R^(D41) R^(D66) R^(D1) L_(C1156) R^(D41) R^(D68) R^(D1)L_(C1157) R^(D41) R^(D76) R^(D1) L_(C1158) R^(D64) R^(D5) R^(D1)L_(C1159) R^(D64) R^(D6) R^(D1) L_(C1160) R^(D64) R^(D9) R^(D1)L_(C1161) R^(D64) R^(D10) R^(D1) L_(C1162) R^(D64) R^(D12) R^(D1)L_(C1163) R^(D64) R^(D15) R^(D1) L_(C1164) R^(D64) R^(D16) R^(D1)L_(C1165) R^(D64) R^(D17) R^(D1) L_(C1166) R^(D64) R^(D18) R^(D1)L_(C1167) R^(D64) R^(D19) R^(D1) L_(C1168) R^(D64) R^(D20) R^(D1)L_(C1169) R^(D64) R^(D21) R^(D1) L_(C1170) R^(D64) R^(D23) R^(D1)L_(C1171) R^(D64) R^(D24) R^(D1) L_(C1172) R^(D64) R^(D25) R^(D1)L_(C1173) R^(D64) R^(D27) R^(D1) L_(C1174) R^(D64) R^(D28) R^(D1)L_(C1175) R^(D64) R^(D29) R^(D1) L_(C1176) R^(D64) R^(D30) R^(D1)L_(C1177) R^(D64) R^(D31) R^(D1) L_(C1178) R^(D64) R^(D32) R^(D1)L_(C1179) R^(D64) R^(D33) R^(D1) L_(C1180) R^(D64) R^(D34) R^(D1)L_(C1181) R^(D64) R^(D42) R^(D1) L_(C1182) R^(D64) R^(D64) R^(D1)L_(C1183) R^(D64) R^(D66) R^(D1) L_(C1184) R^(D64) R^(D68) R^(D1)L_(C1185) R^(D64) R^(D76) R^(D1) L_(C1186) R^(D66) R^(D5) R^(D1)L_(C1187) R^(D66) R^(D6) R^(D1) L_(C1188) R^(D66) R^(D9) R^(D1)L_(C1189) R^(D66) R^(D10) R^(D1) L_(C1190) R^(D66) R^(D12) R^(D1)L_(C1191) R^(D66) R^(D15) R^(D1) L_(C1192) R^(D66) R^(D16) R^(D1)L_(C1193) R^(D66) R^(D17) R^(D1) L_(C1194) R^(D66) R^(D18) R^(D1)L_(C1195) R^(D66) R^(D19) R^(D1) L_(C1196) R^(D66) R^(D20) R^(D1)L_(C1197) R^(D66) R^(D21) R^(D1) L_(C1198) R^(D66) R^(D23) R^(D1)L_(C1199) R^(D66) R^(D24) R^(D1) L_(C1200) R^(D66) R^(D25) R^(D1)L_(C1201) R^(D66) R^(D27) R^(D1) L_(C1202) R^(D68) R^(D28) R^(D1)L_(C1203) R^(D68) R^(D29) R^(D1) L_(C1204) R^(D68) R^(D30) R^(D1)L_(C1205) R^(D68) R^(D31) R^(D1) L_(C1206) R^(D68) R^(D32) R^(D1)L_(C1207) R^(D68) R^(D33) R^(D1) L_(C1208) R^(D68) R^(D34) R^(D1)L_(C1209) R^(D68) R^(D42) R^(D1) L_(C1210) R^(D68) R^(D68) R^(D1)L_(C1211) R^(D68) R^(D76) R^(D1) L_(C1212) R^(D68) R^(D5) R^(D1)L_(C1213) R^(D68) R^(D6) R^(D1) L_(C1214) R^(D68) R^(D9) R^(D1)L_(C1215) R^(D68) R^(D10) R^(D1) L_(C1216) R^(D68) R^(D12) R^(D1)L_(C1217) R^(D68) R^(D15) R^(D1) L_(C1218) R^(D68) R^(D16) R^(D1)L_(C1219) R^(D68) R^(D17) R^(D1) L_(C1220) R^(D68) R^(D18) R^(D1)L_(C1221) R^(D68) R^(D19) R^(D1) L_(C1222) R^(D68) R^(D20) R^(D1)L_(C1223) R^(D68) R^(D21) R^(D1) L_(C1224) R^(D68) R^(D23) R^(D1)L_(C1225) R^(D68) R^(D24) R^(D1) L_(C1226) R^(D68) R^(D25) R^(D1)L_(C1227) R^(D68) R^(D27) R^(D1) L_(C1228) R^(D68) R^(D28) R^(D1)L_(C1229) R^(D68) R^(D29) R^(D1) L_(C1230) R^(D68) R^(D30) R^(D1)L_(C1231) R^(D68) R^(D31) R^(D1) L_(C1232) R^(D68) R^(D32) R^(D1)L_(C1233) R^(D68) R^(D33) R^(D1) L_(C1234) R^(D68) R^(D34) R^(D1)L_(C1235) R^(D68) R^(D42) R^(D1) L_(C1236) R^(D68) R^(D76) R^(D1)L_(C1237) R^(D76) R^(D5) R^(D1) L_(C1238) R^(D76) R^(D6) R^(D1)L_(C1239) R^(D76) R^(D9) R^(D1) L_(C1240) R^(D76) R^(D10) R^(D1)L_(C1241) R^(D76) R^(D12) R^(D1) L_(C1242) R^(D76) R^(D15) R^(D1)L_(C1243) R^(D76) R^(D16) R^(D1) L_(C1244) R^(D76) R^(D17) R^(D1)L_(C1245) R^(D76) R^(D18) R^(D1) L_(C1246) R^(D76) R^(D19) R^(D1)L_(C1247) R^(D76) R^(D20) R^(D1) L_(C1248) R^(D76) R^(D21) R^(D1)L_(C1249) R^(D76) R^(D23) R^(D1) L_(C1250) R^(D76) R^(D24) R^(D1)L_(C1251) R^(D76) R^(D25) R^(D1) L_(C1252) R^(D76) R^(D27) R^(D1)L_(C1253) R^(D76) R^(D28) R^(D1) L_(C1254) R^(D76) R^(D29) R^(D1)L_(C1255) R^(D76) R^(D30) R^(D1) L_(C1256) R^(D76) R^(D31) R^(D1)L_(C1257) R^(D76) R^(D32) R^(D1) L_(C1258) R^(D76) R^(D33) R^(D1)L_(C1259) R^(D76) R^(D34) R^(D1) L_(C1260) R^(D76) R^(D42) R^(D1),where R^(D1) to R^(D21) have the following structures:

In some embodiments, the compound has the formula:

where rings E and F each independently represents a 5-membered or6-membered carbocyclic or heterocyclic ring; R^(E) and R^(F) eachindependently represents mono to the maximum possible number ofsubstitutions, or no substitution; m₁, m₂, and m₃ are each independentlyan integer of 0 or 1; when m₂ is 0, both m₁ and m₃ are 1; when m₂ is 1,each of m₁ and m₃ independently can be 0 or 1; when m₁ is 0, L¹ is notpresent; when m₂ is 0, L² is not present; when m₃ is 0, L³ is notpresent; where L¹, L², and L³ are each independently selected from thegroup consisting of a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2,CRR′, SiRR′, GeRR′, alkyl, cycloalkyl, and combinations thereof; whereR^(E) and R^(F) are each independently hydrogen or a substituentselected from the group consisting of the general substituents definedabove; where R and R′ are each independently selected from the groupconsisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl,carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, and combinations thereof; and where any adjacentR^(E), R^(F), R, and R′ can be joined to form a ring.

In some embodiments where the compound is homoleptic, the compound hasthe formula:

where R^(G) is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl, partially orfully deuterated variants thereof, partially or fully fluorinatedvariants thereof, and combinations thereof.

In some embodiments, the homoleptic compound has the formula selectedfrom the group consisting of:

According to another aspect of the present disclosure, an OLED isdisclosed. The OLED comprises: an anode; a cathode; and an organiclayer, disposed between the anode and the cathode, where the organiclayer comprises a compound comprising a first ligand L_(A) of Formula I

as defined above.

A consumer product comprising the OLED defined above is also disclosed.

In some embodiments, the OLED has one or more characteristics selectedfrom the group consisting of being flexible, being rollable, beingfoldable, being stretchable, and being curved. In some embodiments, theOLED is transparent or semi-transparent. In some embodiments, the OLEDfurther comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising adelayed fluorescent emitter. In some embodiments, the OLED comprises aRGB pixel arrangement or white plus color filter pixel arrangement. Insome embodiments, the OLED is a mobile device, a hand held device, or awearable device. In some embodiments, the OLED is a display panel havingless than 10 inch diagonal or 50 square inch area. In some embodiments,the OLED is a display panel having at least 10 inch diagonal or 50square inch area. In some embodiments, the OLED is a lighting panel.

An emissive region in an OLED is also disclosed. The emissive regioncomprises a compound comprising a first ligand L_(A) of Formula I

where X¹ to X⁸ are each independently C or N, where no more than two Natoms are bonded to each other. At least one pair of X¹ and X², X² andX³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G ofFormula II

where A is selected from the group consisting of C(CH₃)₂, O, S, Se, andNR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independentlyhydrogen or a substituent selected from the group consisting of thegeneral substituents defined above. Any two substituents may be joinedor fused together to form a ring. The ligand L_(A) is complexed to ametal M. M is optionally coordinated to other ligands. The ligand L_(A)is optionally linked with other ligands to comprise a tridentate,tetradentate, pentadentate, or hexadentate ligand.

In some embodiments of the emissive region, the compound is an emissivedopant or a non-emissive dopant.

In some embodiments, the emissive region further comprises a host,wherein the host contains at least one group selected from the groupconsisting of metal complex, triphenylene, carbazole, dibenzothiophene,dibenzofuran, dibenzoselenophene, aza-triphenylene, azacarbazole,aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments, the emissive region further comprises a host,wherein the host is selected from the group consisting of:

and combinations thereof.

In some embodiments, the compound can be an emissive dopant. In someembodiments, the compound can produce emissions via phosphorescence,fluorescence, thermally activated delayed fluorescence, i.e., TADF (alsoreferred to as E-type delayed fluorescence; see, e.g., U.S. applicationSer. No. 15/700,352, which is hereby incorporated by reference in itsentirety), triplet-triplet annihilation, or combinations of theseprocesses. In some embodiments, the emissive dopant can be a racemicmixture, or can be enriched in one enantiomer. In some embodiments, thecompound can be homoleptic (each ligand is the same). In someembodiments, the compound can be heteroleptic (at least one ligand isdifferent from others).

When there are more than one ligand coordinated to a metal, the ligandscan all be the same in some embodiments. In some other embodiments, atleast one ligand is different from the other ligand(s). In someembodiments, every ligand can be different from each other. This is alsotrue in embodiments where a ligand being coordinated to a metal can belinked with other ligands being coordinated to that metal to form atridentate, tetradentate, pentadentate, or hexadentate ligands. Thus,where the coordinating ligands are being linked together, all of theligands can be the same in some embodiments, and at least one of theligands being linked can be different from the other ligand(s) in someother embodiments.

In some embodiments, the compound can be used as a phosphorescentsensitizer in an OLED where one or multiple layers in the OLED containsan acceptor in the form of one or more fluorescent and/or delayedfluorescence emitters. In some embodiments, the compound can be used asone component of an exciplex to be used as a sensitizer. As aphosphorescent sensitizer, the compound must be capable of energytransfer to the acceptor and the acceptor will emit the energy orfurther transfer energy to a final emitter. The acceptor concentrationscan range from 0.001% to 100%. The acceptor could be in either the samelayer as the phosphorescent sensitizer or in one or more differentlayers. In some embodiments, the acceptor is a TADF emitter. In someembodiments, the acceptor is a fluorescent emitter. In some embodiments,the emission can arise from any or all of the sensitizer, acceptor, andfinal emitter.

According to another aspect, a formulation comprising the compounddescribed herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of aconsumer product, an electronic component module, and a lighting panel.The organic layer can be an emissive layer and the compound can be anemissive dopant in some embodiments, while the compound can be anon-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two ormore hosts are preferred. In some embodiments, the hosts used may be a)bipolar, b) electron transporting, c) hole transporting or d) wide bandgap materials that play little role in charge transport. In someembodiments, the host can include a metal complex. The host can be atriphenylene containing benzo-fused thiophene or benzo-fused furan. Anysubstituent in the host can be an unfused substituent independentlyselected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1),OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1),C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has nosubstitutions. In the preceding substituents n can range from 1 to 10;and Ar₁ and Ar₂ can be independently selected from the group consistingof benzene, biphenyl, naphthalene, triphenylene, carbazole, andheteroaromatic analogs thereof. The host can be an inorganic compound.For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical groupselected from the group consisting of triphenylene, carbazole,dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene,azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, andaza-dibenzoselenophene. The host can include a metal complex. The hostcan be, but is not limited to, a specific compound selected from thegroup consisting of:

and combinations thereof.Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation thatcomprises the novel compound disclosed herein is described. Theformulation can include one or more components selected from the groupconsisting of a solvent, a host, a hole injection material, holetransport material, electron blocking material, hole blocking material,and an electron transport material, disclosed herein.

The present disclosure encompasses any chemical structure comprising thenovel compound of the present disclosure, or a monovalent or polyvalentvariant thereof. In other words, the inventive compound, or a monovalentor polyvalent variant thereof, can be a part of a larger chemicalstructure. Such chemical structure can be selected from the groupconsisting of a monomer, a polymer, a macromolecule, and a supramolecule(also known as supermolecule). As used herein, a “monovalent variant ofa compound” refers to a moiety that is identical to the compound exceptthat one hydrogen has been removed and replaced with a bond to the restof the chemical structure. As used herein, a “polyvalent variant of acompound” refers to a moiety that is identical to the compound exceptthat more than one hydrogen has been removed and replaced with a bond orbonds to the rest of the chemical structure. In the instance of asupramolecule, the inventive compound can also be incorporated into thesupramolecule complex without covalent bonds.

Combination with Other Materials

The materials described herein as useful for a particular layer in anorganic light emitting device may be used in combination with a widevariety of other materials present in the device. For example, emissivedopants disclosed herein may be used in conjunction with a wide varietyof hosts, transport layers, blocking layers, injection layers,electrodes and other layers that may be present. The materials describedor referred to below are non-limiting examples of materials that may beuseful in combination with the compounds disclosed herein, and one ofskill in the art can readily consult the literature to identify othermaterials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants tosubstantially alter its density of charge carriers, which will in turnalter its conductivity. The conductivity is increased by generatingcharge carriers in the matrix material, and depending on the type ofdopant, a change in the Fermi level of the semiconductor may also beachieved. Hole-transporting layer can be doped by p-type conductivitydopants and n-type conductivity dopants are used in theelectron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:EP01617493, EP01968131, EP2020694, EP2684932, US20050139810,US20070160905, US20090167167, US2010288362, WO006081780, WO2009003455,WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804,US20150123047, and US2012146012.

HIL/HTL:

A hole injecting/transporting material to be used in the presentinvention is not particularly limited, and any compound may be used aslong as the compound is typically used as a hole injecting/transportingmaterial. Examples of the material include, but are not limited to: aphthalocyanine or porphyrin derivative; an aromatic amine derivative; anindolocarbazole derivative; a polymer containing fluorohydrocarbon; apolymer with conductivity dopants; a conducting polymer, such asPEDOT/PSS; a self-assembly monomer derived from compounds such asphosphonic acid and silane derivatives; a metal oxide derivative, suchas MoO_(x); a p-type semiconducting organic compound, such as1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and across-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, butnot limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatichydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl,triphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each Ar may beunsubstituted or may be substituted by a substituent selected from thegroup consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the groupconsisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH)or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are notlimited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40;(Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independentlyselected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is aninteger value from 1 to the maximum number of ligands that may beattached to the metal; and k′+k″ is the maximum number of ligands thatmay be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In anotheraspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met isselected from Ir, Pt, Os, and Zn. In a further aspect, the metal complexhas a smallest oxidation potential in solution vs. Fc⁺/Fc couple lessthan about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used inan OLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334,EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701,EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765,JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473,TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053,US20050123751, US20060182993, US20060240279, US20070145888,US20070181874, US20070278938, US20080014464, US20080091025,US20080106190, US20080124572, US20080145707, US20080220265,US20080233434, US20080303417, US2008107919, US20090115320,US20090167161, US2009066235, US2011007385, US20110163302, US2011240968,US2011278551, US2012205642, US2013241401, US20140117329, US2014183517,U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550,WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006,WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577,WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937,WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

An electron blocking layer (EBL) may be used to reduce the number ofelectrons and/or excitons that leave the emissive layer. The presence ofsuch a blocking layer in a device may result in substantially higherefficiencies, and/or longer lifetime, as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the EBLmaterial has a higher LUMO (closer to the vacuum level) and/or highertriplet energy than the emitter closest to the EBL interface. In someembodiments, the EBL material has a higher LUMO (closer to the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the EBL interface. In one aspect, the compound used in EBLcontains the same molecule or the same functional groups used as one ofthe hosts described below.

Host:

The light emitting layer of the organic EL device of the presentinvention preferably contains at least a metal complex as light emittingmaterial, and may contain a host material using the metal complex as adopant material. Examples of the host material are not particularlylimited, and any metal complexes or organic compounds may be used aslong as the triplet energy of the host is larger than that of thedopant. Any host material may be used with any dopant so long as thetriplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have thefollowing general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹ is an anotherligand; k′ is an integer value from 1 to the maximum number of ligandsthat may be attached to the metal; and k′+k″ is the maximum number ofligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms Oand N.

In another aspect, Met is selected from Ir and Pt. In a further aspect,(Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

In one aspect, the host compound contains at least one of the followinggroups selected from the group consisting of aromatic hydrocarbon cycliccompounds such as benzene, biphenyl, triphenyl, triphenylene,tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each option withineach group may be unsubstituted or may be substituted by a substituentselected from the group consisting of deuterium, halogen, alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile,sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the followinggroups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, and when it is aryl or heteroaryl, it has thesimilar definition as Ar's mentioned above. k is an integer from 0 to 20or 1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (includingCH) or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: EP2034538,EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644,KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919,US20060280965, US20090017330, US20090030202, US20090167162,US20090302743, US20090309488, US20100012931, US20100084966,US20100187984, US2010187984, US2012075273, US2012126221, US2013009543,US2013105787, US2013175519, US2014001446, US20140183503, US20140225088,US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207,WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754,WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778,WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423,WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649,WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,US20170263869, US20160163995, U.S. Pat. No. 9,466,803,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction withthe compound of the present disclosure. Examples of the additionalemitter dopants are not particularly limited, and any compounds may beused as long as the compounds are typically used as emitter materials.Examples of suitable emitter materials include, but are not limited to,compounds which can produce emissions via phosphorescence, fluorescence,thermally activated delayed fluorescence, i.e., TADF (also referred toas E-type delayed fluorescence), triplet-triplet annihilation, orcombinations of these processes.

Non-limiting examples of the emitter materials that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526,EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907,EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652,KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599,U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526,US20030072964, US20030138657, US20050123788, US20050244673,US2005123791, US2005260449, US20060008670, US20060065890, US20060127696,US20060134459, US20060134462, US20060202194, US20060251923,US20070034863, US20070087321, US20070103060, US20070111026,US20070190359, US20070231600, US2007034863, US2007104979, US2007104980,US2007138437, US2007224450, US2007278936, US20080020237, US20080233410,US20080261076, US20080297033, US200805851, US2008161567, US2008210930,US20090039776, US20090108737, US20090115322, US20090179555,US2009085476, US2009104472, US20100090591, US20100148663, US20100244004,US20100295032, US2010102716, US2010105902, US2010244004, US2010270916,US20110057559, US20110108822, US20110204333, US2011215710, US2011227049,US2011285275, US2012292601, US20130146848, US2013033172, US2013165653,US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos.6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469,6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228,7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586,8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970,WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373,WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842,WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731,WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491,WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471,WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977,WO2014038456, WO2014112450.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holesand/or excitons that leave the emissive layer. The presence of such ablocking layer in a device may result in substantially higherefficiencies and/or longer lifetime as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the HBLmaterial has a lower HOMO (further from the vacuum level) and/or highertriplet energy than the emitter closest to the HBL interface. In someembodiments, the HBL material has a lower HOMO (further from the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or thesame functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of thefollowing groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ isan integer from 1 to 3.ETL:

Electron transport layer (ETL) may include a material capable oftransporting electrons. Electron transport layer may be intrinsic(undoped), or doped. Doping may be used to enhance conductivity.Examples of the ETL material are not particularly limited, and any metalcomplexes or organic compounds may be used as long as they are typicallyused to transport electrons.

In one aspect, compound used in ETL contains at least one of thefollowing groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, when it is aryl or heteroaryl, it has the similardefinition as Ar's mentioned above. Ar¹ to Ar³ has the similardefinition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but notlimit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinatedto atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer valuefrom 1 to the maximum number of ligands that may be attached to themetal.

Non-limiting examples of the ETL materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: CN103508940,EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918,JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977,US2007018155, US20090101870, US20090115316, US20090140637,US20090179554, US2009218940, US2010108990, US2011156017, US2011210320,US2012193612, US2012214993, US2014014925, US2014014927, US20140284580,U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263,WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373,WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in theperformance, which is composed of an n-doped layer and a p-doped layerfor injection of electrons and holes, respectively. Electrons and holesare supplied from the CGL and electrodes. The consumed electrons andholes in the CGL are refilled by the electrons and holes injected fromthe cathode and anode, respectively; then, the bipolar currents reach asteady state gradually. Typical CGL materials include n and pconductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device,the hydrogen atoms can be partially or fully deuterated. Thus, anyspecifically listed substituent, such as, without limitation, methyl,phenyl, pyridyl, etc. may be undeuterated, partially deuterated, andfully deuterated versions thereof. Similarly, classes of substituentssuch as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc.also may be undeuterated, partially deuterated, and fully deuteratedversions thereof.

EXPERIMENTAL

2,3-dibromopyridine (24.00 g, 101 mmol), dibenzo[b,d]furan-3-ylboronicacid (22.55 g, 106 mmol), sodium hydroxide (12.16 g, 304 mmol),tetrakis(triphenylphosphine)palladium(0) (5.85 g, 5.07 mmol), THF (1673ml) and water (239 ml) were added to a 5 L flask. The resulting mixturewas degassed and stirred at 60° C. for 5 hrs. The reaction mixture wasthen cooled to room temperature and diluted with brine. The organiclayer was separated, and the aqueous layer was extracted with DCM. Thecombined organic layers were dried over Na₂SO₄, filtered, andconcentrated. The resulting residue was purified by columnchromatography (DCM/heptane) to obtain 23.36 g (66% yield) of3-bromo-2-(dibenzo[b,d]furan-3-yl)pyridine as a white solid.

A 500 mL flask was charged withdicyclohexyl(2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)phosphane (1.374g, 2.88 mmol), PdOAc₂ (0.324 g, 1.441 mmol), copper(I) iodide (0.274 g,1.441 mmol), 3-bromo-2-(dibenzo[b,d]furan-3-yl)pyridine (23.36 g, 72.1mmol), and triethylamine (144 mL). The reaction mixture was stirred andheated to 55° C. Ethynyltrimethylsilane (14.97 mL, 108 mmol) was thenadded into reaction mixture and stirred at 55° C. for about 16 hrs. Thereaction mixture was cooled to room temperature, diluted with water andextracted with EtOAc. The combined organic layer was dried over Na₂SO₄,concentrated and the resulting residue was subjected to silica gelcolumn chromatography (DCM/heptane) to afford2-(dibenzo[b,d]furan-3-yl)-3-((trimethylsilyl)ethynyl)pyridine (24.38 g,99% yield).

Potassium carbonate (29.60 g, 214 mmol) was added to a 2 L flaskcontaining2-(dibenzo[b,d]furan-3-yl)-3-((trimethylsilyl)ethynyl)pyridine (24.38 g,71.4 mmol) in methanol (714 mL). After 3 hrs of stirring at roomtemperature, the reaction mixture was concentrated on the rotaryevaporator. Purification of crude material via silica gel columnchromatography (EtOAc/heptane) gave2-(dibenzo[b,d]furan-3-yl)-3-ethynylpyridine (18 g, 94% yield) as anoff-white solid.

1 L flask equipped with a magnetic stir bar was charged with2-(dibenzo[b,d]furan-3-yl)-3-ethynylpyridine (16.00 g, 59.4 mmol),platinum(II) chloride (3.95 g, 14.85 mmol), and toluene (300 mL). Themixture was stirred and heated to reflux for about 16 hrs under nitrogenatmosphere. Upon completion, as evidenced by TLC analysis, the reactionmixture was cooled to room temperature and purified via silica gelcolumn chromatography (EtOAc/heptane) which produced 6.7 g (42% yield)of desired benzo[2,3]benzofuro[5,6-h]quinoline with 99.99% purity.

A 250 mL, 4-neck round bottom flask, equipped with a condenser, stir barand thermocouple was charged with[Ir(5-(methyl-d₃)-2-phenylpyridine(1H))₂(MeOH)₂](trifluoromethane-sulfonate)(4.1 g, 5.48 mmol, 1.0 equiv), benzo[2,3]benzofuro[5,6-h]quinoline (3.1g, 11.31 mmol, 2.1 equiv) and ethanol (122 mL). The reaction mixture wascooled to room temperature, filtered through paper, washing the residuewith methanol (100 mL). The filtrate was concentrated under reducedpressure. The crude solid was chromatographed on silica gel (150 g),eluting with a gradient of 50-100% dichloromethane in heptanes to givethe inventive example Compound A as a yellow solid.

The photoluminescence spectrum of the inventive example Compound A inPMMA film was measured and the plot of the spectrum is shown in FIG. 3.The inventive compound exhibited a broad emission profile withλ_(max)=540 nm and unprecedentedly high PLQY (˜100%). The broad emissionprofile from 490 nm to almost 700 nm covering a significant portion ofthe visible region makes the inventive compound as useful emittermaterial in white OLEDs for lighting and display applications.

It is understood that the various embodiments described herein are byway of example only, and are not intended to limit the scope of theinvention. For example, many of the materials and structures describedherein may be substituted with other materials and structures withoutdeviating from the spirit of the invention. The present invention asclaimed may therefore include variations from the particular examplesand preferred embodiments described herein, as will be apparent to oneof skill in the art. It is understood that various theories as to whythe invention works are not intended to be limiting.

We claim:
 1. A compound comprising a first ligand L_(A) of Formula I

wherein X¹ to X⁸ are each independently C or N; wherein no more than twoN atoms are bonded to each other; wherein at least one pair of X¹ andX², X² and X³, X⁶ and X⁷, or X⁷ and X⁸ is C—C, and is joined to astructure G of Formula II

wherein A is selected from the group consisting of C(CH₃)₂, O, S, Se,and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution; wherein each R^(A), R^(B), R^(C), R^(D), and R′ isindependently hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof; wherein any two substituents may bejoined or fused together to form an aromatic ring; wherein L_(A) iscomplexed to a metal M; wherein M is optionally coordinated to otherligands; wherein the ligand L_(A) is optionally linked with otherligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand.
 2. The compound of claim 1, wherein each R^(A),R^(B), R^(C), and R^(D) is independently selected from the groupconsisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, andcombinations thereof.
 3. The compound of claim 1, wherein X¹ to X⁸ areeach C.
 4. The compound of claim 1, wherein at least one of X¹ to X⁸ isN.
 5. The compound of claim 1, wherein M is selected from the groupconsisting of Ru, Os, Pd, Pt, Ir, Cu, and Au.
 6. The compound of claim1, wherein Formula II is substituted or unsubstituted


7. The compound of claim 1, wherein only one pair of X¹ and X², X² andX³, X⁶ and X⁷, or X⁷ and X⁸ is C—C, and is joined to the structure G. 8.The compound of claim 1, wherein the first ligand L_(A) is selected fromthe group consisting of

wherein X⁹ to X¹² are each independently C or N; and wherein no morethan two N atoms are bonded to each other.
 9. The compound of claim 1,wherein the first ligand L_(A) is selected from the group consisting ofligands L_(A1-O) to L_(A384-O), L_(A1-S) to L_(A384-S), and L_(A1-C) toL_(A384-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,wherein for ligands L_(A1-O) to L_(A384-O), A in the structure G is O,wherein for ligands L_(A1-S) to L_(A384-S), A in the structure G is S,wherein for ligands L_(A1-C) to L_(A384-C), A in the structure G isC(CH₃)₂, wherein X³, R⁶, R⁸, and G are defined for A1 to A384 as shownbelow: X³ R⁶ R⁸ G A1 CH H H G¹ A2 CH H H G³ A3 CH H H G⁵ A4 CH H H G⁷ A5CH H H G⁹ A6 CH H H G¹¹ A7 N H H G¹ A8 N H H G³ A9 N H H G⁵ A10 N H H G⁷A11 N H H G⁹ A12 N H H G¹¹ A13 CR^(B1) H H G¹ A14 CR^(B3) H H G¹ A15CR^(B5) H H G¹ A16 CR^(B7) H H G¹ A17 CR^(B9) H H G¹ A18 CR^(B11) H H G¹A19 CR^(B13) H H G¹ A20 CR^(B15) H H G¹ A21 CR^(B17) H H G¹ A22 CR^(B19)H H G¹ A23 CR^(B21) H H G¹ A24 CR^(B23) H H G¹ A25 CR^(B25) H H G¹ A26CR^(B27) H H G¹ A27 CR^(B29) H H G¹ A28 CR^(B31) H H G¹ A29 CR^(B33) H HG¹ A30 CR^(B35) H H G¹ A31 CR^(B37) H H G¹ A32 CR^(B39) H H G¹ A33CR^(B41) H H G¹ A34 CR^(B43) H H G¹ A35 CR^(B45) H H G¹ A36 CR^(B47) H HG¹ A37 CR^(B49) H H G¹ A38 CR^(B51) H H G¹ A39 CR^(B53) H H G¹ A40CR^(B55) H H G¹ A41 CR^(B57) H H G¹ A42 CR^(B59) H H G¹ A43 CR^(B1) H HG² A44 CR^(B3) H H G² A45 CR^(B5) H H G² A46 CR^(B7) H H G² A47 CR^(B9)H H G² A48 CR^(B11) H H G² A49 CR^(B13) H H G² A50 CR^(B15) H H G² A51CR^(B17) H H G² A52 CR^(B19) H H G² A53 CR^(B21) H H G² A54 CR^(B23) H HG² A55 CR^(B25) H H G² A56 CR^(B27) H H G² A57 CR^(B29) H H G² A58CR^(B31) H H G² A59 CR^(B33) H H G² A60 CR^(B35) H H G² A61 CR^(B37) H HG² A62 CR^(B39) H H G² A63 CR^(B41) H H G² A64 CR^(B43) H H G² A65CR^(B45) H H G² A66 CR^(B47) H H G² A67 CR^(B49) H H G² A68 CR^(B51) H HG² A69 CR^(B53) H H G² A70 CR^(B55) H H G² A71 CR^(B57) H H G² A72CR^(B59) H H G² A73 CR^(B1) H H G³ A74 CR^(B3) H H G³ A75 CR^(B5) H H G³A76 CR^(B7) H H G³ A77 CR^(B9) H H G³ A78 CR^(B11) H H G³ A79 CR^(B13) HH G³ A80 CR^(B15) H H G³ A81 CR^(B17) H H G³ A82 CR^(B19) H H G³ A83CR^(B21) H H G³ A84 CR^(B23) H H G³ A85 CR^(B25) H H G³ A86 CR^(B27) H HG³ A87 CR^(B29) H H G³ A88 CR^(B31) H H G³ A89 CR^(B33) H H G³ A90CR^(B35) H H G³ A91 CR^(B37) H H G³ A92 CR^(B39) H H G³ A93 CR^(B41) H HG³ A94 CR^(B43) H H G³ A95 CR^(B45) H H G³ A96 CR^(B47) H H G³ A97CR^(B49) H H G³ A98 CR^(B51) H H G³ A99 CR^(B53) H H G³ A100 CR^(B55) HH G³ A101 CR^(B57) H H G³ A102 CR^(B59) H H G³ A103 CR^(B1) H H G⁴ A104CR^(B3) H H G⁴ A105 CR^(B5) H H G⁴ A106 CR^(B7) H H G⁴ A107 CR^(B9) H HG⁴ A108 CR^(B11) H H G⁴ A109 CR^(B13) H H G⁴ A110 CR^(B15) H H G⁴ A111CR^(B17) H H G⁴ A112 CR^(B19) H H G⁴ A113 CR^(B21) H H G⁴ A114 CR^(B23)H H G⁴ A115 CR^(B25) H H G⁴ A116 CR^(B27) H H G⁴ A117 CR^(B29) H H G⁴A118 CR^(B31) H H G⁴ A119 CR^(B33) H H G⁴ A120 CR^(B35) H H G⁴ A121CR^(B37) H H G⁴ A122 CR^(B39) H H G⁴ A123 CR^(B41) H H G⁴ A124 CR^(B43)H H G⁴ A125 CR^(B45) H H G⁴ A126 CR^(B47) H H G⁴ A127 CR^(B49) H H G⁴A128 CR^(B51) H H G⁴ A129 CH H H G² A130 CH H H G⁴ A131 CH H H G⁶ A132CH H H G⁸ A133 CH H H G¹⁰ A134 CH H H G¹² A135 N H H G² A136 N H H G⁴A137 N H H G⁶ A138 N H H G⁸ A139 N H H G¹⁰ A140 N H H G¹² A141 CR^(B2) HH G¹ A142 CR^(B4) H H G¹ A143 CR^(B6) H H G¹ A144 CR^(B8) H H G¹ A145CR^(B10) H H G¹ A146 CR^(B12) H H G¹ A147 CR^(B14) H H G¹ A148 CR^(B16)H H G¹ A149 CR^(B18) H H G¹ A150 CR^(B20) H H G¹ A151 CR^(B22) H H G¹A152 CR^(B24) H H G¹ A153 CR^(B26) H H G¹ A154 CR^(B27) H H G¹ A155CR^(B30) H H G¹ A156 CR^(B32) H H G¹ A157 CR^(B34) H H G¹ A158 CR^(B36)H H G¹ A159 CR^(B38) H H G¹ A160 CR^(B40) H H G¹ A161 CR^(B42) H H G¹A162 CR^(B44) H H G¹ A163 CR^(B46) H H G¹ A164 CR^(B47) H H G¹ A165CR^(B50) H H G¹ A166 CR^(B51) H H G¹ A167 CR^(B54) H H G¹ A168 CR^(B56)H H G¹ A169 CR^(B58) H H G¹ A170 CR^(B60) H H G¹ A171 CR^(B2) H H G²A172 CR^(B4) H H G² A173 CR^(B6) H H G² A174 CR^(B8) H H G² A175CR^(B10) H H G² A176 CR^(B12) H H G² A177 CR^(B14) H H G² A178 CR^(B16)H H G² A179 CR^(B18) H H G² A180 CR^(B20) H H G² A181 CR^(B22) H H G²A182 CR^(B24) H H G² A183 CR^(B26) H H G² A184 CR^(B27) H H G² A185CR^(B30) H H G² A186 CR^(B32) H H G² A187 CR^(B34) H H G² A188 CR^(B36)H H G² A189 CR^(B38) H H G² A190 CR^(B40) H H G² A191 CR^(B42) H H G²A192 CR^(B44) H H G² A193 CR^(B46) H H G² A194 CR^(B47) H H G² A195CR^(B50) H H G² A196 CR^(B52) H H G² A197 CR^(B54) H H G² A198 CR^(B56)H H G² A199 CR^(B58) H H G² A200 CR^(B60) H H G² A201 CR^(B2) H H G³A202 CR^(B4) H H G³ A203 CR^(B6) H H G³ A204 CR^(B8) H H G³ A205CR^(B10) H H G³ A206 CR^(B12) H H G³ A207 CR^(B14) H H G³ A208 CR^(B16)H H G³ A209 CR^(B18) H H G³ A210 CR^(B20) H H G³ A211 CR^(B22) H H G³A212 CR^(B24) H H G³ A213 CR^(B26) H H G³ A214 CR^(B27) H H G³ A215CR^(B30) H H G³ A216 CR^(B32) H H G³ A217 CR^(B34) H H G³ A218 CR^(B36)H H G³ A219 CR^(B38) H H G³ A220 CR^(B40) H H G³ A221 CR^(B42) H H G³A222 CR^(B44) H H G³ A223 CR^(B46) H H G³ A224 CR^(B48) H H G³ A225CR^(B50) H H G³ A226 CR^(B51) H H G³ A227 CR^(B54) H H G³ A228 CR^(B56)H H G³ A229 CR^(B57) H H G³ A230 CR^(B60) H H G³ A231 CR^(B2) H H G⁴A232 CR^(B4) H H G⁴ A233 CR^(B6) H H G⁴ A234 CR^(B8) H H G⁴ A235CR^(B10) H H G⁴ A236 CR^(B12) H H G⁴ A237 CR^(B14) H H G⁴ A238 CR^(B16)H H G⁴ A239 CR^(B18) H H G⁴ A240 CR^(B20) H H G⁴ A241 CR^(B22) H H G⁴A242 CR^(B24) H H G⁴ A243 CR^(B26) H H G⁴ A244 CR^(B28) H H G⁴ A245CR^(B30) H H G⁴ A246 CR^(B32) H H G⁴ A247 CR^(B34) H H G⁴ A248 CR^(B36)H H G⁴ A249 CR^(B38) H H G⁴ A250 CR^(B40) H H G⁴ A251 CR^(B42) H H G⁴A252 CR^(B44) H H G⁴ A253 CR^(B46) H H G⁴ A254 CR^(B47) H H G⁴ A255CR^(B50) H H G⁴ A256 CR^(B52) H H G⁴ A257 CR^(B55) H H G⁴ A258 CR^(B57)H H G⁴ A259 CR^(B59) H H G⁴ A260 CR^(B1) H H G⁵ A261 CR^(B3) H H G⁵ A262CR^(B5) H H G⁵ A263 CR^(B7) H H G⁵ A264 CR^(B9) H H G⁵ A265 CR^(B11) H HG⁵ A266 CR^(B13) H H G⁵ A267 CR^(B15) H H G⁵ A268 CR^(B17) H H G⁵ A269CR^(B19) H H G⁵ A270 CR^(B21) H H G⁵ A271 CR^(B23) H H G⁵ A272 CR^(B25)H H G⁵ A273 CR^(B27) H H G⁵ A274 CR^(B29) H H G⁵ A275 CR^(B31) H H G⁵A276 CR^(B33) H H G⁵ A277 CR^(B35) H H G⁵ A278 CR^(B37) H H G⁵ A279CR^(B39) H H G⁵ A280 CR^(B41) H H G⁵ A281 CR^(B43) H H G⁵ A282 CR^(B45)H H G⁵ A283 CR^(B47) H H G⁵ A284 CR^(B49) H H G⁵ A285 CR^(B51) H H G⁵A286 CR^(B53) H H G⁵ A287 CR^(B55) H H G⁵ A288 CR^(B57) H H G⁵ A289CR^(B59) H H G⁵ A290 CR^(B1) H H G⁶ A291 CR^(B3) H H G⁶ A292 CR^(B5) H HG⁶ A293 CR^(B7) H H G⁶ A294 CR^(B9) H H G⁶ A295 CR^(B11) H H G⁶ A296CR^(B13) H H G⁶ A297 CR^(B15) H H G⁶ A298 CR^(B17) H H G⁶ A299 CR^(B19)H H G⁶ A200 CR^(B21) H H G⁶ A301 CR^(B23) H H G⁶ A302 CR^(B25) H H G⁶A303 CR^(B27) H H G⁶ A304 CR^(B29) H H G⁶ A305 CR^(B31) H H G⁶ A306CR^(B33) H H G⁶ A307 CR^(B35) H H G⁶ A308 CR^(B37) H H G⁶ A309 CR^(B39)H H G⁶ A310 CR^(B41) H H G⁶ A311 CR^(B43) H H G⁶ A312 CR^(B45) H H G⁶A313 CR^(B47) H H G⁶ A314 CR^(B49) H H G⁶ A315 CR^(B51) H H G⁶ A316CR^(B53) H H G⁶ A317 CR^(B55) H H G⁶ A318 CR^(B57) H H G⁶ A319 CR^(B59)H H G⁶ A320 CR^(B56) H H G⁴ A321 CR^(B58) H H G⁴ A322 CR^(B60) H H G⁴A323 CR^(B2) H H G⁵ A324 CR^(B4) H H G⁵ A325 CR^(B6) H H G⁵ A326 CR^(B8)H H G⁵ A327 CR^(B10) H H G⁵ A328 CR^(B12) H H G⁵ A329 CR^(B14) H H G⁵A330 CR^(B16) H H G⁵ A331 CR^(B18) H H G⁵ A332 CR^(B20) H H G⁵ A333CR^(B22) H H G⁵ A334 CR^(B24) H H G⁵ A335 CR^(B26) H H G⁵ A336 CR^(B28)H H G⁵ A337 CR^(B30) H H G⁵ A338 CR^(B32) H H G⁵ A339 CR^(B34) H H G⁵A340 CR^(B36) H H G⁵ A341 CR^(B38) H H G⁵ A342 CR^(B40) H H G⁵ A343CR^(B42) H H G⁵ A344 CR^(B44) H H G⁵ A345 CR^(B46) H H G⁵ A346 CR^(B48)H H G⁵ A347 CR^(B50) H H G⁵ A348 CR^(B52) H H G⁵ A349 CR^(B54) H H G⁵A350 CR^(B56) H H G⁵ A351 CR^(B58) H H G⁵ A352 CR^(B60) H H G⁵ A353CR^(B1) H H G⁶ A354 CR^(B4) H H G⁶ A355 CR^(B7) H H G⁶ A356 CR^(B10) H HG⁶ A357 CR^(B13) H H G⁶ A358 CR^(B16) H H G⁶ A359 CR^(B19) H H G⁶ A360CR^(B22) H H G⁶ A361 CR^(B25) H H G⁶ A362 CR^(B28) H H G⁶ A363 CR^(B31)H H G⁶ A364 CR^(B34) H H G⁶ A365 CR^(B37) H H G⁶ A366 CR^(B40) H H G⁶A367 CR^(B43) H H G⁶ A368 CR^(B46) H H G⁶ A369 CR^(B49) H H G⁶ A370CR^(B52) H H G⁶ A371 CR^(B55) H H G⁶ A372 CR^(B58) H H G⁶ A373 CR^(B61)H H G⁶ A374 CR^(B64) H H G⁶ A375 CR^(B67) H H G⁶ A376 CR^(B70) H H G⁶A377 CR^(B73) H H G⁶ A378 CR^(B76) H H G⁶ A379 CR^(B79) H H G⁶ A380CR^(B82) H H G⁶ A381 CR^(B85) H H G⁶ A382 CR^(B88) H H G⁶ A383 CR^(B53)H H G⁴ A384 CR^(B54) H H G⁴

ligands L_(A385-O) to L_(A420-O), L_(A385-S) to L_(A420-S), andL_(A385-C) to L_(A420-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,wherein for ligands L_(A385-O) to L_(A420-O), A in the structure G is O,wherein for ligands L_(A385-S) to L_(A420-S), A in the structure G is S,wherein for ligands L_(A385-C) to L_(A420-C), A in the structure G isC(CH₃)₂, wherein R⁶, R⁸, and G are defined for A385 to A420 as shownbelow: R⁶ R⁸ G A385 H H G¹³ A386 H H G¹⁵ A387 H H G¹⁷ A388 H H G¹⁹ A389H H G²¹ A390 H H G²³ A391 CH₃ CH₃ G¹³ A392 CH₃ CH₃ G¹⁵ A393 CH₃ CH₃ G¹⁷A394 CH₃ CH₃ G¹⁹ A395 CH₃ CH₃ G²¹ A396 CH₃ CH₃ G²³ A397 CH₃ CH₃ G¹³ A398CH₃ CH₃ G¹⁵ A399 CH₃ CH₃ G¹⁷ A400 CH₃ CH₃ G¹⁹ A401 CH₃ CH₃ G²¹ A402 CH₃CH₃ G²³ A403 H H G¹⁴ A404 H H G¹⁶ A405 H H G¹⁸ A406 H H G²⁰ A407 H H G²²A408 H H G²⁴ A409 CH₃ CH₃ G¹⁴ A410 CH₃ CH₃ G¹⁶ A411 CH₃ CH₃ G¹⁸ A412 CH₃CH₃ G²⁰ A413 CH₃ CH₃ G²² A414 CH₃ CH₃ G²⁴ A415 CH₃ CH₃ G¹⁴ A416 CH₃ CH₃G¹⁶ A417 CH₃ CH₃ G¹⁸ A418 CH₃ CH₃ G²⁰ A419 CH₃ CH₃ G²² A420 CH₃ CH₃ G²⁴

ligands L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), andL_(A421-C) to L_(A1152-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,wherein for ligands L_(A421-O) to L_(A1152-O), A in the structure G isO, wherein for ligands L_(A421-S) to L_(A1152-S), A in the structure Gis S, and wherein for ligands L_(A421-C) to L_(A1152-C), A in thestructure G is C(CH₃)₂, wherein R², R³, and G are defined for A421 toA1152 as shown below: R² R³ G A421 H H G³⁷ A422 H H G³⁹ A423 H H G⁴¹A424 H H G⁴³ A425 H H G⁴⁵ A426 H H G⁴⁷ A427 CH₃ R^(B1) G³⁷ A428 CH₃R^(B3) G³⁷ A429 CH₃ R^(B5) G³⁷ A430 CH₃ R^(B7) G³⁷ A431 CH₃ R^(B9) G³⁷A432 CH₃ R^(B11) G³⁷ A433 CH₃ R^(B13) G³⁷ A434 CH₃ R^(B15) G³⁷ A435 CH₃R^(B17) G³⁷ A436 CH₃ R^(B19) G³⁷ A437 CH₃ R^(B21) G³⁷ A438 CH₃ R^(B23)G³⁷ A439 CH₃ R^(B25) G³⁷ A440 CH₃ R^(B27) G³⁷ A441 CH₃ R^(B29) G³⁷ A442CH₃ R^(B31) G³⁷ A443 CH₃ R^(B33) G³⁷ A444 CH₃ R^(B35) G³⁷ A445 CH₃R^(B37) G³⁷ A446 CH₃ R^(B39) G³⁷ A447 CH₃ R^(B41) G³⁷ A448 CH₃ R^(B43)G³⁷ A449 CH₃ R^(B45) G³⁷ A450 CH₃ R^(B47) G³⁷ A451 CH₃ R^(B49) G³⁷ A452CH₃ R^(B51) G³⁷ A453 CH₃ R^(B53) G³⁷ A454 CH₃ R^(B55) G³⁷ A455 CH₃R^(B57) G³⁷ A456 CH₃ R^(B59) G³⁷ A457 R^(B1) CH₃ G³⁷ A458 R^(B3) CH₃ G³⁷A459 R^(B5) CH₃ G³⁷ A460 R^(B7) CH₃ G³⁷ A461 R^(B9) CH₃ G³⁷ A462 R^(B11)CH₃ G³⁷ A463 R^(B13) CH₃ G³⁷ A464 R^(B15) CH₃ G³⁷ A465 R^(B17) CH₃ G³⁷A466 R^(B19) CH₃ G³⁷ A467 R^(B21) CH₃ G³⁷ A468 R^(B23) CH₃ G³⁷ A469R^(B25) CH₃ G³⁷ A470 R^(B27) CH₃ G³⁷ A471 R^(B29) CH₃ G³⁷ A472 R^(B31)CH₃ G³⁷ A473 R^(B33) CH₃ G³⁷ A474 R^(B35) CH₃ G³⁷ A475 R^(B37) CH₃ G³⁷A476 R^(B39) CH₃ G³⁷ A477 R^(B41) CH₃ G³⁷ A478 R^(B43) CH₃ G³⁷ A479R^(B45) CH₃ G³⁷ A480 R^(B47) CH₃ G³⁷ A481 R^(B49) CH₃ G³⁷ A482 R^(B51)CH₃ G³⁷ A483 R^(B53) CH₃ G³⁷ A484 R^(B55) CH₃ G³⁷ A485 R^(B57) CH₃ G³⁷A486 R^(B59) CH₃ G³⁷ A487 CH₃ R^(B1) G³⁸ A488 CH₃ R^(B3) G³⁸ A489 CH₃R^(B5) G³⁸ A490 CH₃ R^(B7) G³⁸ A491 CH₃ R^(B9) G³⁸ A492 CH₃ R^(B11) G³⁸A493 CH₃ R^(B13) G³⁸ A494 CH₃ R^(B15) G³⁸ A495 CH₃ R^(B17) G³⁸ A496 CH₃R^(B19) G³⁸ A497 CH₃ R^(B21) G³⁸ A498 CH₃ R^(B23) G³⁸ A499 CH₃ R^(B25)G³⁸ A500 CH₃ R^(B27) G³⁸ A501 CH₃ R^(B29) G³⁸ A502 CH₃ R^(B31) G³⁸ A503CH₃ R^(B33) G³⁸ A504 CH₃ R^(B35) G³⁸ A505 CH₃ R^(B37) G³⁸ A506 CH₃R^(B39) G³⁸ A507 CH₃ R^(B41) G³⁸ A508 CH₃ R^(B43) G³⁸ A509 CH₃ R^(B45)G³⁸ A510 CH₃ R^(B47) G³⁸ A511 CH₃ R^(B49) G³⁸ A512 CH₃ R^(B51) G³⁸ A513CH₃ R^(B53) G³⁸ A514 CH₃ R^(B55) G³⁸ A515 CH₃ R^(B57) G³⁸ A516 CH₃R^(B59) G³⁸ A517 R^(B1) CH₃ G³⁸ A518 R^(B3) CH₃ G³⁸ A519 R^(B5) CH₃ G³⁸A520 R^(B7) CH₃ G³⁸ A521 R^(B9) CH₃ G³⁸ A522 R^(B11) CH₃ G³⁸ A523R^(B13) CH₃ G³⁸ A524 R^(B15) CH₃ G³⁸ A525 R^(B17) CH₃ G³⁸ A526 R^(B19)CH₃ G³⁸ A527 R^(B21) CH₃ G³⁸ A528 R^(B23) CH₃ G³⁸ A529 R^(B25) CH₃ G³⁸A530 R^(B27) CH₃ G³⁸ A531 R^(B29) CH₃ G³⁸ A532 R^(B31) CH₃ G³⁸ A533R^(B33) CH₃ G³⁸ A534 R^(B35) CH₃ G³⁸ A535 R^(B37) CH₃ G³⁸ A536 R^(B39)CH₃ G³⁸ A537 R^(B41) CH₃ G³⁸ A538 R^(B43) CH₃ G³⁸ A539 R^(B45) CH₃ G³⁸A540 R^(B47) CH₃ G³⁸ A541 R^(B49) CH₃ G³⁸ A542 R^(B51) CH₃ G³⁸ A543R^(B53) CH₃ G³⁸ A544 R^(B55) CH₃ G³⁸ A545 R^(B57) CH₃ G³⁸ A546 R^(B59)CH₃ G³⁸ A547 CH₃ R^(B1) G³⁹ A548 CH₃ R^(B3) G³⁹ A549 CH₃ R^(B5) G³⁹ A550CH₃ R^(B7) G³⁹ A551 CH₃ R^(B9) G³⁹ A552 CH₃ R^(B11) G³⁹ A553 CH₃ R^(B13)G³⁹ A554 CH₃ R^(B15) G³⁹ A555 CH₃ R^(B17) G³⁹ A556 CH₃ R^(B19) G³⁹ A557CH₃ R^(B21) G³⁹ A558 CH₃ R^(B23) G³⁹ A559 CH₃ R^(B25) G³⁹ A560 CH₃R^(B27) G³⁹ A561 CH₃ R^(B29) G³⁹ A562 CH₃ R^(B31) G³⁹ A563 CH₃ R^(B33)G³⁹ A564 CH₃ R^(B35) G³⁹ A565 CH₃ R^(B37) G³⁹ A566 CH₃ R^(B39) G³⁹ A567CH₃ R^(B41) G³⁹ A568 CH₃ R^(B43) G³⁹ A569 CH₃ R^(B45) G³⁹ A570 CH₃R^(B47) G³⁹ A571 CH₃ R^(B49) G³⁹ A572 CH₃ R^(B51) G³⁹ A573 CH₃ R^(B53)G³⁹ A574 CH₃ R^(B55) G³⁹ A575 CH₃ R^(B57) G³⁹ A576 CH₃ R^(B59) G³⁹ A577R^(B1) CH₃ G³⁹ A578 R^(B3) CH₃ G³⁹ A579 R^(B5) CH₃ G³⁹ A580 R^(B7) CH₃G³⁹ A581 R^(B9) CH₃ G³⁹ A582 R^(B11) CH₃ G³⁹ A583 R^(B13) CH₃ G³⁹ A584R^(B15) CH₃ G³⁹ A585 R^(B17) CH₃ G³⁹ A586 R^(B19) CH₃ G³⁹ A587 R^(B21)CH₃ G³⁹ A588 R^(B23) CH₃ G³⁹ A589 R^(B25) CH₃ G³⁹ A590 R^(B27) CH₃ G³⁹A591 R^(B29) CH₃ G³⁹ A592 R^(B31) CH₃ G³⁹ A593 R^(B33) CH₃ G³⁹ A594R^(B35) CH₃ G³⁹ A595 R^(B37) CH₃ G³⁹ A596 R^(B39) CH₃ G³⁹ A597 R^(B41)CH₃ G³⁹ A598 R^(B43) CH₃ G³⁹ A599 R^(B45) CH₃ G³⁹ A600 R^(B47) CH₃ G³⁹A601 R^(B49) CH₃ G³⁹ A602 R^(B51) CH₃ G³⁹ A603 R^(B53) CH₃ G³⁹ A604R^(B55) CH₃ G³⁹ A605 R^(B57) CH₃ G³⁹ A606 R^(B59) CH₃ G³⁹ A607 CH₃R^(B1) G⁴⁰ A608 CH₃ R^(B3) G⁴⁰ A609 CH₃ R^(B5) G⁴⁰ A610 CH₃ R^(B7) G⁴⁰A611 CH₃ R^(B9) G⁴⁰ A612 CH₃ R^(B11) G⁴⁰ A613 CH₃ R^(B13) G⁴⁰ A614 CH₃R^(B15) G⁴⁰ A615 CH₃ R^(B17) G⁴⁰ A616 CH₃ R^(B19) G⁴⁰ A617 CH₃ R^(B21)G⁴⁰ A618 CH₃ R^(B23) G⁴⁰ A619 CH₃ R^(B25) G⁴⁰ A620 CH₃ R^(B27) G⁴⁰ A621CH₃ R^(B29) G⁴⁰ A622 CH₃ R^(B31) G⁴⁰ A623 CH₃ R^(B33) G⁴⁰ A624 CH₃R^(B35) G⁴⁰ A625 CH₃ R^(B37) G⁴⁰ A626 CH₃ R^(B39) G⁴⁰ A627 CH₃ R^(B41)G⁴⁰ A628 CH₃ R^(B43) G⁴⁰ A629 CH₃ R^(B45) G⁴⁰ A630 CH₃ R^(B47) G⁴⁰ A631CH₃ R^(B49) G⁴⁰ A632 CH₃ R^(B51) G⁴⁰ A633 CH₃ R^(B53) G⁴⁰ A634 CH₃R^(B55) G⁴⁰ A635 CH₃ R^(B57) G⁴⁰ A636 CH₃ R^(B59) G⁴⁰ A637 R^(B1) CH₃G⁴⁰ A638 R^(B3) CH₃ G⁴⁰ A639 R^(B5) CH₃ G⁴⁰ A640 R^(B7) CH₃ G⁴⁰ A641R^(B9) CH₃ G⁴⁰ A642 R^(B11) CH₃ G⁴⁰ A643 R^(B13) CH₃ G⁴⁰ A644 R^(B15)CH₃ G⁴⁰ A645 R^(B17) CH₃ G⁴⁰ A646 R^(B19) CH₃ G⁴⁰ A647 R^(B21) CH₃ G⁴⁰A648 R^(B23) CH₃ G⁴⁰ A649 R^(B25) CH₃ G⁴⁰ A650 R^(B27) CH₃ G⁴⁰ A651R^(B29) CH₃ G⁴⁰ A652 R^(B31) CH₃ G⁴⁰ A653 R^(B33) CH₃ G⁴⁰ A654 R^(B35)CH₃ G⁴⁰ A655 R^(B37) CH₃ G⁴⁰ A656 R^(B39) CH₃ G⁴⁰ A657 R^(B41) CH₃ G⁴⁰A658 R^(B43) CH₃ G⁴⁰ A659 R^(B45) CH₃ G⁴⁰ A660 R^(B47) CH₃ G⁴⁰ A661R^(B49) CH₃ G⁴⁰ A662 R^(B51) CH₃ G⁴⁰ A663 R^(B53) CH₃ G⁴⁰ A664 R^(B55)CH₃ G⁴⁰ A665 H H G³⁸ A666 H H G⁴⁰ A667 H H G⁴² A668 H H G⁴⁴ A669 H H G⁴⁶A670 H H G⁴⁸ A671 CH₃ R^(B2) G³⁷ A672 CH₃ R^(B4) G³⁷ A673 CH₃ R^(B6) G³⁷A674 CH₃ R^(B8) G³⁷ A675 CH₃ R^(B10) G³⁷ A676 CH₃ R^(B12) G³⁷ A677 CH₃R^(B14) G³⁷ A678 CH₃ R^(B16) G³⁷ A679 CH₃ R^(B18) G³⁷ A680 CH₃ R^(B20)G³⁷ A681 CH₃ R^(B22) G³⁷ A682 CH₃ R^(B24) G³⁷ A683 CH₃ R^(B26) G³⁷ A684CH₃ R^(B28) G³⁷ A685 CH₃ R^(B30) G³⁷ A686 CH₃ R^(B32) G³⁷ A687 CH₃R^(B34) G³⁷ A688 CH₃ R^(B36) G³⁷ A689 CH₃ R^(B38) G³⁷ A690 CH₃ R^(B40)G³⁷ A691 CH₃ R^(B42) G³⁷ A692 CH₃ R^(B44) G³⁷ A693 CH₃ R^(B46) G³⁷ A694CH₃ R^(B48) G³⁷ A695 CH₃ R^(B50) G³⁷ A696 CH₃ R^(B52) G³⁷ A697 CH₃R^(B54) G³⁷ A698 CH₃ R^(B56) G³⁷ A699 CH₃ R^(B58) G³⁷ A700 CH₃ R^(B60)G³⁷ A701 R^(B2) CH₃ G³⁷ A702 R^(B4) CH₃ G³⁷ A703 R^(B6) CH₃ G³⁷ A704R^(B8) CH₃ G³⁷ A705 R^(B10) CH₃ G³⁷ A706 R^(B12) CH₃ G³⁷ A707 R^(B14)CH₃ G³⁷ A708 R^(B16) CH₃ G³⁷ A709 R^(B18) CH₃ G³⁷ A710 R^(B20) CH₃ G³⁷A711 R^(B22) CH₃ G³⁷ A712 R^(B24) CH₃ G³⁷ A713 R^(B26) CH₃ G³⁷ A714R^(B28) CH₃ G³⁷ A715 R^(B30) CH₃ G³⁷ A716 R^(B32) CH₃ G³⁷ A717 R^(B34)CH₃ G³⁷ A718 R^(B36) CH₃ G³⁷ A719 R^(B38) CH₃ G³⁷ A720 R^(B40) CH₃ G³⁷A721 R^(B42) CH₃ G³⁷ A722 R^(B44) CH₃ G³⁷ A723 R^(B46) CH₃ G³⁷ A724R^(B48) CH₃ G³⁷ A725 R^(B50) CH₃ G³⁷ A726 R^(B52) CH₃ G³⁷ A727 R^(B54)CH₃ G³⁷ A728 R^(B56) CH₃ G³⁷ A729 R^(B58) CH₃ G³⁷ A730 R^(B60) CH₃ G³⁷A731 CH₃ R^(B2) G³⁸ A732 CH₃ R^(B4) G³⁸ A733 CH₃ R^(B6) G³⁸ A734 CH₃R^(B8) G³⁸ A735 CH₃ R^(B10) G³⁸ A736 CH₃ R^(B12) G³⁸ A737 CH₃ R^(B14)G³⁸ A738 CH₃ R^(B16) G³⁸ A739 CH₃ R^(B18) G³⁸ A740 CH₃ R^(B20) G³⁸ A741CH₃ R^(B22) G³⁸ A742 CH₃ R^(B24) G³⁸ A743 CH₃ R^(B26) G³⁸ A744 CH₃R^(B28) G³⁸ A745 CH₃ R^(B30) G³⁸ A746 CH₃ R^(B32) G³⁸ A747 CH₃ R^(B34)G³⁸ A748 CH₃ R^(B36) G³⁸ A749 CH₃ R^(B38) G³⁸ A750 CH₃ R^(B40) G³⁸ A751CH₃ R^(B42) G³⁸ A752 CH₃ R^(B44) G³⁸ A753 CH₃ R^(B46) G³⁸ A754 CH₃R^(B48) G³⁸ A755 CH₃ R^(B50) G³⁸ A756 CH₃ R^(B52) G³⁸ A757 CH₃ R^(B54)G³⁸ A758 CH₃ R^(B56) G³⁸ A759 CH₃ R^(B58) G³⁸ A760 CH₃ R^(B60) G³⁸ A761R^(B2) CH₃ G³⁸ A762 R^(B4) CH₃ G³⁸ A763 R^(B6) CH₃ G³⁸ A764 R^(B8) CH₃G³⁸ A765 R^(B10) CH₃ G³⁸ A766 R^(B12) CH₃ G³⁸ A767 R^(B14) CH₃ G³⁸ A768R^(B16) CH₃ G³⁸ A769 R^(B18) CH₃ G³⁸ A770 R^(B20) CH₃ G³⁸ A771 R^(B22)CH₃ G³⁸ A772 R^(B24) CH₃ G³⁸ A773 R^(B26) CH₃ G³⁸ A774 R^(B28) CH₃ G³⁸A775 R^(B30) CH₃ G³⁸ A776 R^(B32) CH₃ G³⁸ A777 R^(B34) CH₃ G³⁸ A778R^(B36) CH₃ G³⁸ A779 R^(B38) CH₃ G³⁸ A780 R^(B40) CH₃ G³⁸ A781 R^(B42)CH₃ G³⁸ A782 R^(B44) CH₃ G³⁸ A783 R^(B46) CH₃ G³⁸ A784 R^(B48) CH₃ G³⁸A785 R^(B50) CH₃ G³⁸ A786 R^(B52) CH₃ G³⁸ A787 R^(B54) CH₃ G³⁸ A788R^(B56) CH₃ G³⁸ A789 R^(B58) CH₃ G³⁸ A790 R^(B60) CH₃ G³⁸ A791 CH₃R^(B2) G³⁹ A792 CH₃ R^(B4) G³⁹ A793 CH₃ R^(B6) G³⁹ A794 CH₃ R^(B8) G³⁹A795 CH₃ R^(B10) G³⁹ A796 CH₃ R^(B12) G³⁹ A797 CH₃ R^(B14) G³⁹ A798 CH₃R^(B16) G³⁹ A799 CH₃ R^(B18) G³⁹ A800 CH₃ R^(B20) G³⁹ A801 CH₃ R^(B22)G³⁹ A802 CH₃ R^(B24) G³⁹ A803 CH₃ R^(B26) G³⁹ A804 CH₃ R^(B28) G³⁹ A805CH₃ R^(B30) G³⁹ A806 CH₃ R^(B32) G³⁹ A807 CH₃ R^(B34) G³⁹ A808 CH₃R^(B36) G³⁹ A809 CH₃ R^(B38) G³⁹ A810 CH₃ R^(B40) G³⁹ A811 CH₃ R^(B42)G³⁹ A812 CH₃ R^(B44) G³⁹ A813 CH₃ R^(B46) G³⁹ A814 CH₃ R^(B48) G³⁹ A815CH₃ R^(B50) G³⁹ A816 CH₃ R^(B52) G³⁹ A817 CH₃ R^(B54) G³⁹ A818 CH₃R^(B56) G³⁹ A819 CH₃ R^(B58) G³⁹ A820 CH₃ R^(B60) G³⁹ A821 R^(B2) CH₃G³⁹ A822 R^(B4) CH₃ G³⁹ A823 R^(B6) CH₃ G³⁹ A824 R^(B8) CH₃ G³⁹ A825R^(B10) CH₃ G³⁹ A826 R^(B12) CH₃ G³⁹ A827 R^(B14) CH₃ G³⁹ A828 R^(B16)CH₃ G³⁹ A829 R^(B18) CH₃ G³⁹ A830 R^(B20) CH₃ G³⁹ A831 R^(B22) CH₃ G³⁹A832 R^(B24) CH₃ G³⁹ A833 R^(B26) CH₃ G³⁹ A834 R^(B28) CH₃ G³⁹ A835R^(B30) CH₃ G³⁹ A836 R^(B32) CH₃ G³⁹ A837 R^(B34) CH₃ G³⁹ A838 R^(B36)CH₃ G³⁹ A839 R^(B38) CH₃ G³⁹ A840 R^(B40) CH₃ G³⁹ A841 R^(B42) CH₃ G³⁹A842 R^(B44) CH₃ G³⁹ A843 R^(B46) CH₃ G³⁹ A844 R^(B48) CH₃ G³⁹ A845R^(B50) CH₃ G³⁹ A846 R^(B52) CH₃ G³⁹ A847 R^(B54) CH₃ G³⁹ A848 R^(B56)CH₃ G³⁹ A849 R^(B58) CH₃ G³⁹ A850 R^(B60) CH₃ G³⁹ A851 CH₃ R^(B2) G⁴⁰A852 CH₃ R^(B4) G⁴⁰ A853 CH₃ R^(B6) G⁴⁰ A854 CH₃ R^(B8) G⁴⁰ A855 CH₃R^(B10) G⁴⁰ A856 CH₃ R^(B12) G⁴⁰ A857 CH₃ R^(B14) G⁴⁰ A858 CH₃ R^(B16)G⁴⁰ A859 CH₃ R^(B18) G⁴⁰ A860 CH₃ R^(B20) G⁴⁰ A861 CH₃ R^(B22) G⁴⁰ A862CH₃ R^(B24) G⁴⁰ A863 CH₃ R^(B26) G⁴⁰ A864 CH₃ R^(B28) G⁴⁰ A865 CH₃R^(B30) G⁴⁰ A866 CH₃ R^(B32) G⁴⁰ A867 CH₃ R^(B34) G⁴⁰ A868 CH₃ R^(B36)G⁴⁰ A869 CH₃ R^(B38) G⁴⁰ A870 CH₃ R^(B40) G⁴⁰ A871 CH₃ R^(B42) G⁴⁰ A872CH₃ R^(B44) G⁴⁰ A873 CH₃ R^(B46) G⁴⁰ A874 CH₃ R^(B48) G⁴⁰ A875 CH₃R^(B50) G⁴⁰ A876 CH₃ R^(B52) G⁴⁰ A877 CH₃ R^(B54) G⁴⁰ A878 CH₃ R^(B56)G⁴⁰ A879 CH₃ R^(B58) G⁴⁰ A880 CH₃ R^(B60) G⁴⁰ A881 R^(B2) CH₃ G⁴⁰ A882R^(B4) CH₃ G⁴⁰ A883 R^(B6) CH₃ G⁴⁰ A884 R^(B8) CH₃ G⁴⁰ A885 R^(B10) CH₃G⁴⁰ A886 R^(B12) CH₃ G⁴⁰ A887 R^(B14) CH₃ G⁴⁰ A888 R^(B16) CH₃ G⁴⁰ A889R^(B18) CH₃ G⁴⁰ A890 R^(B20) CH₃ G⁴⁰ A891 R^(B22) CH₃ G⁴⁰ A892 R^(B24)CH₃ G⁴⁰ A893 R^(B26) CH₃ G⁴⁰ A894 R^(B28) CH₃ G⁴⁰ A895 R^(B30) CH₃ G⁴⁰A896 R^(B32) CH₃ G⁴⁰ A897 R^(B34) CH₃ G⁴⁰ A898 R^(B36) CH₃ G⁴⁰ A899R^(B38) CH₃ G⁴⁰ A900 R^(B40) CH₃ G⁴⁰ A901 R^(B42) CH₃ G⁴⁰ A902 R^(B44)CH₃ G⁴⁰ A903 R^(B46) CH₃ G⁴⁰ A904 R^(B48) CH₃ G⁴⁰ A905 R^(B50) CH₃ G⁴⁰A906 R^(B52) CH₃ G⁴⁰ A907 R^(B54) CH₃ G⁴⁰ A908 R^(B56) CH₃ G⁴⁰ A909R^(B57) CH₃ G⁴⁰ A910 R^(B59) CH₃ G⁴⁰ A911 CH₃ R^(B1) G⁴¹ A912 CH₃ R^(B3)G⁴¹ A913 CH₃ R^(B5) G⁴¹ A914 CH₃ R^(B7) G⁴¹ A915 CH₃ R^(B9) G⁴¹ A916 CH₃R^(B11) G⁴¹ A917 CH₃ R^(B13) G⁴¹ A918 CH₃ R^(B15) G⁴¹ A919 CH₃ R^(B17)G⁴¹ A920 CH₃ R^(B19) G⁴¹ A921 CH₃ R^(B21) G⁴¹ A922 CH₃ R^(B23) G⁴¹ A923CH₃ R^(B25) G⁴¹ A924 CH₃ R^(B27) G⁴¹ A925 CH₃ R^(B29) G⁴¹ A926 CH₃R^(B31) G⁴¹ A927 CH₃ R^(B33) G⁴¹ A928 CH₃ R^(B35) G⁴¹ A929 CH₃ R^(B37)G⁴¹ A930 CH₃ R^(B39) G⁴¹ A931 CH₃ R^(B41) G⁴¹ A932 CH₃ R^(B43) G⁴¹ A933CH₃ R^(B45) G⁴¹ A934 CH₃ R^(B47) G⁴¹ A935 CH₃ R^(B49) G⁴¹ A936 CH₃R^(B51) G⁴¹ A937 CH₃ R^(B53) G⁴¹ A938 CH₃ R^(B55) G⁴¹ A939 CH₃ R^(B57)G⁴¹ A940 CH₃ R^(B59) G⁴¹ A941 R^(B1) CH₃ G⁴¹ A942 R^(B3) CH₃ G⁴¹ A943R^(B5) CH₃ G⁴¹ A944 R^(B7) CH₃ G⁴¹ A945 R^(B9) CH₃ G⁴¹ A946 R^(B11) CH₃G⁴¹ A947 R^(B13) CH₃ G⁴¹ A948 R^(B15) CH₃ G⁴¹ A949 R^(B17) CH₃ G⁴¹ A950R^(B19) CH₃ G⁴¹ A951 R^(B21) CH₃ G⁴¹ A952 R^(B23) CH₃ G⁴¹ A953 R^(B25)CH₃ G⁴¹ A954 R^(B27) CH₃ G⁴¹ A955 R^(B29) CH₃ G⁴¹ A956 R^(B31) CH₃ G⁴¹A957 R^(B33) CH₃ G⁴¹ A958 R^(B35) CH₃ G⁴¹ A959 R^(B37) CH₃ G⁴¹ A960R^(B39) CH₃ G⁴¹ A961 R^(B41) CH₃ G⁴¹ A962 R^(B43) CH₃ G⁴¹ A963 R^(B45)CH₃ G⁴¹ A964 R^(B47) CH₃ G⁴¹ A965 R^(B49) CH₃ G⁴¹ A966 R^(B51) CH₃ G⁴¹A967 R^(B53) CH₃ G⁴¹ A968 R^(B55) CH₃ G⁴¹ A969 R^(B57) CH₃ G⁴¹ A970R^(B59) CH₃ G⁴¹ A971 CH₃ R^(B1) G⁴² A972 CH₃ R^(B3) G⁴² A973 CH₃ R^(B5)G⁴² A974 CH₃ R^(B7) G⁴² A975 CH₃ R^(B9) G⁴² A976 CH₃ R^(B11) G⁴² A977CH₃ R^(B13) G⁴² A978 CH₃ R^(B15) G⁴² A979 CH₃ R^(B17) G⁴² A980 CH₃R^(B19) G⁴² A981 CH₃ R^(B21) G⁴² A982 CH₃ R^(B23) G⁴² A983 CH₃ R^(B25)G⁴² A984 CH₃ R^(B27) G⁴² A985 CH₃ R^(B29) G⁴² A986 CH₃ R^(B31) G⁴² A987CH₃ R^(B33) G⁴² A988 CH₃ R^(B35) G⁴² A989 CH₃ R^(B37) G⁴² A990 CH₃R^(B39) G⁴² A991 CH₃ R^(B41) G⁴² A992 CH₃ R^(B43) G⁴² A993 CH₃ R^(B45)G⁴² A994 CH₃ R^(B47) G⁴² A995 CH₃ R^(B49) G⁴² A996 CH₃ R^(B51) G⁴² A997CH₃ R^(B53) G⁴² A998 CH₃ R^(B55) G⁴² A999 CH₃ R^(B57) G⁴² A1000 CH₃R^(B59) G⁴² A1001 R^(B1) CH₃ G⁴² A1002 R^(B3) CH₃ G⁴² A1003 R^(B5) CH₃G⁴² A1004 R^(B7) CH₃ G⁴² A1005 R^(B9) CH₃ G⁴² A1006 R^(B11) CH₃ G⁴²A1007 R^(B13) CH₃ G⁴² A1008 R^(B15) CH₃ G⁴² A1009 R^(B17) CH₃ G⁴² A1010R^(B19) CH₃ G⁴² A1011 R^(B21) CH₃ G⁴² A1012 R^(B23) CH₃ G⁴² A1013R^(B25) CH₃ G⁴² A1014 R^(B27) CH₃ G⁴² A1015 R^(B29) CH₃ G⁴² A1016R^(B31) CH₃ G⁴² A1017 R^(B33) CH₃ G⁴² A1018 R^(B35) CH₃ G⁴² A1019R^(B37) CH₃ G⁴² A1020 R^(B39) CH₃ G⁴² A1021 R^(B41) CH₃ G⁴² A1022R^(B43) CH₃ G⁴² A1023 R^(B45) CH₃ G⁴² A1024 R^(B47) CH₃ G⁴² A1025R^(B49) CH₃ G⁴² A1026 R^(B51) CH₃ G⁴² A1027 R^(B53) CH₃ G⁴² A1028R^(B55) CH₃ G⁴² A1029 R^(B57) CH₃ G⁴² A1030 R^(B59) CH₃ G⁴² A1031R^(B58) CH₃ G⁴⁰ A1032 R^(B60) CH₃ G⁴⁰ A1033 CH₃ R^(B2) G⁴¹ A1034 CH₃R^(B4) G⁴¹ A1035 CH₃ R^(B6) G⁴¹ A1036 CH₃ R^(B8) G⁴¹ A1037 CH₃ R^(B10)G⁴¹ A1038 CH₃ R^(B12) G⁴¹ A1039 CH₃ R^(B14) G⁴¹ A1040 CH₃ R^(B16) G⁴¹A1041 CH₃ R^(B18) G⁴¹ A1042 CH₃ R^(B20) G⁴¹ A1043 CH₃ R^(B22) G⁴¹ A1044CH₃ R^(B24) G⁴¹ A1045 CH₃ R^(B26) G⁴¹ A1046 CH₃ R^(B28) G⁴¹ A1047 CH₃R^(B30) G⁴¹ A1048 CH₃ R^(B32) G⁴¹ A1049 CH₃ R^(B34) G⁴¹ A1050 CH₃R^(B36) G⁴¹ A1051 CH₃ R^(B38) G⁴¹ A1052 CH₃ R^(B40) G⁴¹ A1053 CH₃R^(B42) G⁴¹ A1054 CH₃ R^(B44) G⁴¹ A1055 CH₃ R^(B46) G⁴¹ A1056 CH₃R^(B48) G⁴¹ A1057 CH₃ R^(B50) G⁴¹ A1058 CH₃ R^(B52) G⁴¹ A1059 CH₃R^(B54) G⁴¹ A1060 CH₃ R^(B56) G⁴¹ A1061 CH₃ R^(B58) G⁴¹ A1062 CH₃R^(B60) G⁴¹ A1063 R^(B2) CH₃ G⁴¹ A1064 R^(B4) CH₃ G⁴¹ A1065 R^(B6) CH₃G⁴¹ A1066 R^(B8) CH₃ G⁴¹ A1067 R^(B10) CH₃ G⁴¹ A1068 R^(B12) CH₃ G⁴¹A1069 R^(B14) CH₃ G⁴¹ A1070 R^(B16) CH₃ G⁴¹ A1071 R^(B18) CH₃ G⁴¹ A1072R^(B20) CH₃ G⁴¹ A1073 R^(B22) CH₃ G⁴¹ A1074 R^(B24) CH₃ G⁴¹ A1075R^(B26) CH₃ G⁴¹ A1076 R^(B28) CH₃ G⁴¹ A1077 R^(B30) CH₃ G⁴¹ A1078R^(B32) CH₃ G⁴¹ A1079 R^(B34) CH₃ G⁴¹ A1080 R^(B36) CH₃ G⁴¹ A1081R^(B38) CH₃ G⁴¹ A1082 R^(B40) CH₃ G⁴¹ A1083 R^(B42) CH₃ G⁴¹ A1084R^(B44) CH₃ G⁴¹ A1085 R^(B46) CH₃ G⁴¹ A1086 R^(B48) CH₃ G⁴¹ A1087R^(B50) CH₃ G⁴¹ A1088 R^(B52) CH₃ G⁴¹ A1089 R^(B54) CH₃ G⁴¹ A1090R^(B56) CH₃ G⁴¹ A1091 R^(B58) CH₃ G⁴¹ A1092 R^(B60) CH₃ G⁴¹ A1093 CH₃R^(B2) G⁴² A1094 CH₃ R^(B4) G⁴² A1095 CH₃ R^(B6) G⁴² A1096 CH₃ R^(B8)G⁴² A1097 CH₃ R^(B10) G⁴² A1098 CH₃ R^(B12) G⁴² A1099 CH₃ R^(B14) G⁴²A1100 CH₃ R^(B16) G⁴² A1101 CH₃ R^(B18) G⁴² A1102 CH₃ R^(B20) G⁴² A1103CH₃ R^(B22) G⁴² A1104 CH₃ R^(B24) G⁴² A1105 CH₃ R^(B26) G⁴² A1106 CH₃R^(B28) G⁴² A1107 CH₃ R^(B30) G⁴² A1108 CH₃ R^(B32) G⁴² A1109 CH₃R^(B34) G⁴² A1110 CH₃ R^(B36) G⁴² A1111 CH₃ R^(B38) G⁴² A1112 CH₃R^(B40) G⁴² A1113 CH₃ R^(B42) G⁴² A1114 CH₃ R^(B44) G⁴² A1115 CH₃R^(B46) G⁴² A1116 CH₃ R^(B48) G⁴² A1117 CH₃ R^(B50) G⁴² A1118 CH₃R^(B52) G⁴² A1119 CH₃ R^(B54) G⁴² A1120 CH₃ R^(B56) G⁴² A1121 CH₃R^(B58) G⁴² A1122 CH₃ R^(B60) G⁴² A1123 R^(B2) CH₃ G⁴² A1124 R^(B4) CH₃G⁴² A1125 R^(B6) CH₃ G⁴² A1126 R^(B8) CH₃ G⁴² A1127 R^(B10) CH₃ G⁴²A1128 R^(B12) CH₃ G⁴² A1129 R^(B14) CH₃ G⁴² A1130 R^(B16) CH₃ G⁴² A1131R^(B18) CH₃ G⁴² A1132 R^(B20) CH₃ G⁴² A1133 R^(B22) CH₃ G⁴² A1134R^(B24) CH₃ G⁴² A1135 R^(B26) CH₃ G⁴² A1136 R^(B28) CH₃ G⁴² A1137R^(B30) CH₃ G⁴² A1138 R^(B32) CH₃ G⁴² A1139 R^(B34) CH₃ G⁴² A1140R^(B36) CH₃ G⁴² A1141 R^(B38) CH₃ G⁴² A1142 R^(B40) CH₃ G⁴² A1143R^(B42) CH₃ G⁴² A1144 R^(B44) CH₃ G⁴² A1145 R^(B46) CH₃ G⁴² A1146R^(B48) CH₃ G⁴² A1147 R^(B50) CH₃ G⁴² A1148 R^(B52) CH₃ G⁴² A1149R^(B54) CH₃ G⁴² A1150 R^(B56) CH₃ G⁴² A1151 R^(B58) CH₃ G⁴² A1152R^(B60) CH₃ G⁴²

ligands L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S),L_(A1153-C) to L_(A1764-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points ofattachment to the corresponding points of attachment in the structure G,wherein for ligands L_(A1153-O) to L_(A1764-O), A in the structure G isO, wherein for ligands L_(A1153-S) to L_(A1764-S), A in the structure Gis S, and wherein for ligands L_(A1153-C) to L_(A1764-C), A in thestructure G is C(CH₃)₂, wherein R², R³, and G are defined for A1153 toA1764 as shown below: R² R³ G A1153 H H G³⁷ A1154 H H G³⁹ A1155 H H G⁴¹A1156 H H G⁴³ A1157 H H G⁴⁵ A1158 H H G⁴⁷ A1159 CH₃ R^(B1) G³⁷ A1160 CH₃R^(B3) G³⁷ A1161 CH₃ R^(B5) G³⁷ A1162 CH₃ R^(B7) G³⁷ A1163 CH₃ R^(B9)G³⁷ A1164 CH₃ R^(B11) G³⁷ A1165 CH₃ R^(B13) G³⁷ A1166 CH₃ R^(B15) G³⁷A1167 CH₃ R^(B17) G³⁷ A1168 CH₃ R^(B19) G³⁷ A1169 CH₃ R^(B21) G³⁷ A1170CH₃ R^(B23) G³⁷ A1171 CH₃ R^(B25) G³⁷ A1172 CH₃ R^(B27) G³⁷ A1173 CH₃R^(B29) G³⁷ A1174 CH₃ R^(B31) G³⁷ A1175 CH₃ R^(B33) G³⁷ A1176 CH₃R^(B35) G³⁷ A1177 CH₃ R^(B37) G³⁷ A1178 CH₃ R^(B39) G³⁷ A1179 CH₃R^(B41) G³⁷ A1180 CH₃ R^(B43) G³⁷ A1181 CH₃ R^(B45) G³⁷ A1182 CH₃R^(B47) G³⁷ A1183 CH₃ R^(B49) G³⁷ A1184 CH₃ R^(B51) G³⁷ A1185 CH₃R^(B53) G³⁷ A1186 CH₃ R^(B55) G³⁷ A1187 CH₃ R^(B57) G³⁷ A1188 CH₃R^(B59) G³⁷ A1189 R^(B1) CH₃ G³⁷ A1190 R^(B3) CH₃ G³⁷ A1191 R^(B5) CH₃G³⁷ A1192 R^(B7) CH₃ G³⁷ A1193 R^(B9) CH₃ G³⁷ A1194 R^(B11) CH₃ G³⁷A1195 R^(B13) CH₃ G³⁷ A1196 R^(B15) CH₃ G³⁷ A1197 R^(B17) CH₃ G³⁷ A1198R^(B19) CH₃ G³⁷ A1199 R^(B21) CH₃ G³⁷ A1200 R^(B23) CH₃ G³⁷ A1201R^(B25) CH₃ G³⁷ A1202 R^(B27) CH₃ G³⁷ A1203 R^(B29) CH₃ G³⁷ A1204R^(B31) CH₃ G³⁷ A1205 R^(B33) CH₃ G³⁷ A1206 R^(B35) CH₃ G³⁷ A1207R^(B37) CH₃ G³⁷ A1208 R^(B39) CH₃ G³⁷ A1209 R^(B41) CH₃ G³⁷ A1210R^(B43) CH₃ G³⁷ A1211 R^(B45) CH₃ G³⁷ A1212 R^(B47) CH₃ G³⁷ A1213R^(B49) CH₃ G³⁷ A1214 R^(B51) CH₃ G³⁷ A1215 R^(B53) CH₃ G³⁷ A1216R^(B55) CH₃ G³⁷ A1217 R^(B57) CH₃ G³⁷ A1218 R^(B59) CH₃ G³⁷ A1219 CH₃R^(B1) G³⁹ A1220 CH₃ R^(B3) G³⁹ A1221 CH₃ R^(B5) G³⁹ A1222 CH₃ R^(B7)G³⁹ A1223 CH₃ R^(B9) G³⁹ A1224 CH₃ R^(B11) G³⁹ A1225 CH₃ R^(B13) G³⁹A1226 CH₃ R^(B15) G³⁹ A1227 CH₃ R^(B17) G³⁹ A1228 CH₃ R^(B19) G³⁹ A1229CH₃ R^(B21) G³⁹ A1230 CH₃ R^(B23) G³⁹ A1231 CH₃ R^(B25) G³⁹ A1232 CH₃R^(B27) G³⁹ A1233 CH₃ R^(B29) G³⁹ A1234 CH₃ R^(B31) G³⁹ A1235 CH₃R^(B33) G³⁹ A1236 CH₃ R^(B35) G³⁹ A1237 CH₃ R^(B37) G³⁹ A1238 CH₃R^(B39) G³⁹ A1239 CH₃ R^(B41) G³⁹ A1240 CH₃ R^(B43) G³⁹ A1241 CH₃R^(B45) G³⁹ A1242 CH₃ R^(B47) G³⁹ A1243 CH₃ R^(B49) G³⁹ A1244 CH₃R^(B51) G³⁹ A1245 CH₃ R^(B53) G³⁹ A1246 CH₃ R^(B55) G³⁹ A1247 CH₃R^(B57) G³⁹ A1248 CH₃ R^(B59) G³⁹ A1249 R^(B1) CH₃ G³⁹ A1250 R^(B3) CH₃G³⁹ A1251 R^(B5) CH₃ G³⁹ A1252 R^(B7) CH₃ G³⁹ A1253 R^(B9) CH₃ G³⁹ A1254R^(B11) CH₃ G³⁹ A1255 R^(B13) CH₃ G³⁹ A1256 R^(B15) CH₃ G³⁹ A1257R^(B17) CH₃ G³⁹ A1258 R^(B19) CH₃ G³⁹ A1259 R^(B21) CH₃ G³⁹ A1260R^(B23) CH₃ G³⁹ A1261 R^(B25) CH₃ G³⁹ A1262 R^(B27) CH₃ G³⁹ A1263R^(B29) CH₃ G³⁹ A1264 R^(B31) CH₃ G³⁹ A1265 R^(B33) CH₃ G³⁹ A1266R^(B35) CH₃ G³⁹ A1267 R^(B37) CH₃ G³⁹ A1268 R^(B39) CH₃ G³⁹ A1269R^(B41) CH₃ G³⁹ A1270 R^(B43) CH₃ G³⁹ A1271 R^(B45) CH₃ G³⁹ A1272R^(B47) CH₃ G³⁹ A1273 R^(B49) CH₃ G³⁹ A1274 R^(B51) CH₃ G³⁹ A1275R^(B53) CH₃ G³⁹ A1276 R^(B55) CH₃ G³⁹ A1277 R^(B57) CH₃ G³⁹ A1278R^(B59) CH₃ G³⁹ A1279 CH₃ R^(B1) G⁴⁰ A1280 CH₃ R^(B3) G⁴⁰ A1281 CH₃R^(B5) G⁴⁰ A1282 CH₃ R^(B7) G⁴⁰ A1283 CH₃ R^(B9) G⁴⁰ A1284 CH₃ R^(B11)G⁴⁰ A1285 CH₃ R^(B13) G⁴⁰ A1286 CH₃ R^(B15) G⁴⁰ A1287 CH₃ R^(B17) G⁴⁰A1288 CH₃ R^(B19) G⁴⁰ A1289 CH₃ R^(B21) G⁴⁰ A1290 CH₃ R^(B23) G⁴⁰ A1291CH₃ R^(B25) G⁴⁰ A1292 CH₃ R^(B27) G⁴⁰ A1293 CH₃ R^(B29) G⁴⁰ A1294 CH₃R^(B31) G⁴⁰ A1295 CH₃ R^(B33) G⁴⁰ A1296 CH₃ R^(B35) G⁴⁰ A1297 CH₃R^(B37) G⁴⁰ A1298 CH₃ R^(B39) G⁴⁰ A1299 CH₃ R^(B41) G⁴⁰ A1300 CH₃R^(B43) G⁴⁰ A1301 CH₃ R^(B45) G⁴⁰ A1302 CH₃ R^(B47) G⁴⁰ A1303 CH₃R^(B49) G⁴⁰ A1304 CH₃ R^(B51) G⁴⁰ A1305 CH₃ R^(B53) G⁴⁰ A1306 CH₃R^(B55) G⁴⁰ A1307 CH₃ R^(B57) G⁴⁰ A1308 CH₃ R^(B59) G⁴⁰ A1309 R^(B1) CH₃G⁴⁰ A1310 R^(B3) CH₃ G⁴⁰ A1311 R^(B5) CH₃ G⁴⁰ A1312 R^(B7) CH₃ G⁴⁰ A1313R^(B9) CH₃ G⁴⁰ A1314 R^(B11) CH₃ G⁴⁰ A1315 R^(B13) CH₃ G⁴⁰ A1316 R^(B15)CH₃ G⁴⁰ A1317 R^(B17) CH₃ G⁴⁰ A1318 R^(B19) CH₃ G⁴⁰ A1319 R^(B21) CH₃G⁴⁰ A1320 R^(B23) CH₃ G⁴⁰ A1321 R^(B25) CH₃ G⁴⁰ A1322 R^(B27) CH₃ G⁴⁰A1323 R^(B29) CH₃ G⁴⁰ A1324 R^(B31) CH₃ G⁴⁰ A1325 R^(B33) CH₃ G⁴⁰ A1326R^(B35) CH₃ G⁴⁰ A1327 R^(B37) CH₃ G⁴⁰ A1328 R^(B39) CH₃ G⁴⁰ A1329R^(B41) CH₃ G⁴⁰ A1330 R^(B43) CH₃ G⁴⁰ A1331 R^(B45) CH₃ G⁴⁰ A1332R^(B47) CH₃ G⁴⁰ A1333 R^(B49) CH₃ G⁴⁰ A1334 R^(B51) CH₃ G⁴⁰ A1335R^(B53) CH₃ G⁴⁰ A1336 R^(B55) CH₃ G⁴⁰ A1337 R^(B57) CH₃ G⁴⁰ A1338R^(B59) CH₃ G⁴⁰ A1339 CH₃ R^(B1) G⁴¹ A1340 CH₃ R^(B3) G⁴¹ A1341 CH₃R^(B5) G⁴¹ A1342 CH₃ R^(B7) G⁴¹ A1343 CH₃ R^(B9) G⁴¹ A1344 CH₃ R^(B11)G⁴¹ A1345 CH₃ R^(B13) G⁴¹ A1346 CH₃ R^(B15) G⁴¹ A1347 CH₃ R^(B17) G⁴¹A1348 CH₃ R^(B19) G⁴¹ A1349 CH₃ R^(B21) G⁴¹ A1350 CH₃ R^(B23) G⁴¹ A1351CH₃ R^(B25) G⁴¹ A1352 CH₃ R^(B27) G⁴¹ A1353 CH₃ R^(B29) G⁴¹ A1354 CH₃R^(B31) G⁴¹ A1355 CH₃ R^(B33) G⁴¹ A1356 CH₃ R^(B35) G⁴¹ A1357 H H G³⁸A1358 H H G⁴⁰ A1359 H H G⁴² A1360 H H G⁴⁴ A1361 H H G⁴⁶ A1362 H H G⁴⁸A1363 CH₃ R^(B2) G³⁷ A1364 CH₃ R^(B4) G³⁷ A1365 CH₃ R^(B6) G³⁷ A1366 CH₃R^(B8) G³⁷ A1367 CH₃ R^(B10) G³⁷ A1368 CH₃ R^(B12) G³⁷ A1369 CH₃ R^(B14)G³⁷ A1370 CH₃ R^(B16) G³⁷ A1371 CH₃ R^(B18) G³⁷ A1372 CH₃ R^(B20) G³⁷A1373 CH₃ R^(B22) G³⁷ A1374 CH₃ R^(B24) G³⁷ A1375 CH₃ R^(B26) G³⁷ A1376CH₃ R^(B28) G³⁷ A1377 CH₃ R^(B30) G³⁷ A1378 CH₃ R^(B32) G³⁷ A1379 CH₃R^(B34) G³⁷ A1380 CH₃ R^(B36) G³⁷ A1381 CH₃ R^(B38) G³⁷ A1382 CH₃R^(B40) G³⁷ A1383 CH₃ R^(B42) G³⁷ A1384 CH₃ R^(B44) G³⁷ A1385 CH₃R^(B46) G³⁷ A1386 CH₃ R^(B48) G³⁷ A1387 CH₃ R^(B50) G³⁷ A1388 CH₃R^(B52) G³⁷ A1389 CH₃ R^(B54) G³⁷ A1390 CH₃ R^(B56) G³⁷ A1391 CH₃R^(B58) G³⁷ A1392 CH₃ R^(B60) G³⁷ A1393 R^(B2) CH₃ G³⁷ A1394 R^(B4) CH₃G³⁷ A1395 R^(B6) CH₃ G³⁷ A1396 R^(B8) CH₃ G³⁷ A1397 R^(B10) CH₃ G³⁷A1398 R^(B12) CH₃ G³⁷ A1399 R^(B14) CH₃ G³⁷ A1400 R^(B16) CH₃ G³⁷ A1401R^(B18) CH₃ G³⁷ A1402 R^(B20) CH₃ G³⁷ A1403 R^(B22) CH₃ G³⁷ A1404R^(B24) CH₃ G³⁷ A1405 R^(B26) CH₃ G³⁷ A1406 R^(B28) CH₃ G³⁷ A1407R^(B30) CH₃ G³⁷ A1408 R^(B32) CH₃ G³⁷ A1409 R^(B34) CH₃ G³⁷ A1410R^(B36) CH₃ G³⁷ A1411 R^(B38) CH₃ G³⁷ A1412 R^(B40) CH₃ G³⁷ A1413R^(B42) CH₃ G³⁷ A1414 R^(B44) CH₃ G³⁷ A1415 R^(B46) CH₃ G³⁷ A1416R^(B48) CH₃ G³⁷ A1417 R^(B50) CH₃ G³⁷ A1418 R^(B52) CH₃ G³⁷ A1419R^(B54) CH₃ G³⁷ A1420 R^(B56) CH₃ G³⁷ A1421 R^(B58) CH₃ G³⁷ A1422R^(B60) CH₃ G³⁷ A1423 CH₃ R^(B2) G³⁹ A1424 CH₃ R^(B4) G³⁹ A1425 CH₃R^(B6) G³⁹ A1426 CH₃ R^(B8) G³⁹ A1427 CH₃ R^(B10) G³⁹ A1428 CH₃ R^(B12)G³⁹ A1429 CH₃ R^(B14) G³⁹ A1430 CH₃ R^(B16) G³⁹ A1431 CH₃ R^(B18) G³⁹A1432 CH₃ R^(B20) G³⁹ A1433 CH₃ R^(B22) G³⁹ A1434 CH₃ R^(B24) G³⁹ A1435CH₃ R^(B26) G³⁹ A1436 CH₃ R^(B28) G³⁹ A1437 CH₃ R^(B30) G³⁹ A1438 CH₃R^(B32) G³⁹ A1439 CH₃ R^(B34) G³⁹ A1440 CH₃ R^(B36) G³⁹ A1441 CH₃R^(B38) G³⁹ A1442 CH₃ R^(B40) G³⁹ A1443 CH₃ R^(B42) G³⁹ A1444 CH₃R^(B44) G³⁹ A1445 CH₃ R^(B46) G³⁹ A1446 CH₃ R^(B48) G³⁹ A1447 CH₃R^(B50) G³⁹ A1448 CH₃ R^(B52) G³⁹ A1449 CH₃ R^(B54) G³⁹ A1450 CH₃R^(B56) G³⁹ A1451 CH₃ R^(B58) G³⁹ A1452 CH₃ R^(B60) G³⁹ A1453 R^(B2) CH₃G³⁹ A1454 R^(B4) CH₃ G³⁹ A1455 R^(B6) CH₃ G³⁹ A1456 R^(B8) CH₃ G³⁹ A1457R^(B10) CH₃ G³⁹ A1458 R^(B12) CH₃ G³⁹ A1459 R^(B14) CH₃ G³⁹ A1460R^(B16) CH₃ G³⁹ A1461 R^(B18) CH₃ G³⁹ A1462 R^(B20) CH₃ G³⁹ A1463R^(B22) CH₃ G³⁹ A1464 R^(B24) CH₃ G³⁹ A1465 R^(B26) CH₃ G³⁹ A1466R^(B28) CH₃ G³⁹ A1467 R^(B30) CH₃ G³⁹ A1468 R^(B32) CH₃ G³⁹ A1469R^(B34) CH₃ G³⁹ A1470 R^(B36) CH₃ G³⁹ A1471 R^(B38) CH₃ G³⁹ A1472R^(B40) CH₃ G³⁹ A1473 R^(B42) CH₃ G³⁹ A1474 R^(B44) CH₃ G³⁹ A1475R^(B46) CH₃ G³⁹ A1476 R^(B48) CH₃ G³⁹ A1477 R^(B50) CH₃ G³⁹ A1478R^(B52) CH₃ G³⁹ A1479 R^(B54) CH₃ G³⁹ A1480 R^(B56) CH₃ G³⁹ A1481R^(B58) CH₃ G³⁹ A1482 R^(B60) CH₃ G³⁹ A1483 CH₃ R^(B2) G⁴⁰ A1484 CH₃R^(B4) G⁴⁰ A1485 CH₃ R^(B6) G⁴⁰ A1486 CH₃ R^(B8) G⁴⁰ A1487 CH₃ R^(B10)G⁴⁰ A1488 CH₃ R^(B12) G⁴⁰ A1489 CH₃ R^(B14) G⁴⁰ A1490 CH₃ R^(B16) G⁴⁰A1491 CH₃ R^(B18) G⁴⁰ A1492 CH₃ R^(B20) G⁴⁰ A1493 CH₃ R^(B22) G⁴⁰ A1494CH₃ R^(B24) G⁴⁰ A1495 CH₃ R^(B26) G⁴⁰ A1496 CH₃ R^(B28) G⁴⁰ A1497 CH₃R^(B30) G⁴⁰ A1498 CH₃ R^(B32) G⁴⁰ A1499 CH₃ R^(B34) G⁴⁰ A1500 CH₃R^(B36) G⁴⁰ A1501 CH₃ R^(B38) G⁴⁰ A1502 CH₃ R^(B40) G⁴⁰ A1503 CH₃R^(B42) G⁴⁰ A1504 CH₃ R^(B44) G⁴⁰ A1505 CH₃ R^(B46) G⁴⁰ A1506 CH₃R^(B48) G⁴⁰ A1507 CH₃ R^(B50) G⁴⁰ A1508 CH₃ R^(B52) G⁴⁰ A1509 CH₃R^(B54) G⁴⁰ A1510 CH₃ R^(B56) G⁴⁰ A1511 CH₃ R^(B58) G⁴⁰ A1512 CH₃R^(B60) G⁴⁰ A1513 R^(B2) CH₃ G⁴⁰ A1514 R^(B4) CH₃ G⁴⁰ A1515 R^(B6) CH₃G⁴⁰ A1516 R^(B8) CH₃ G⁴⁰ A1517 R^(B10) CH₃ G⁴⁰ A1518 R^(B12) CH₃ G⁴⁰A1519 R^(B14) CH₃ G⁴⁰ A1520 R^(B16) CH₃ G⁴⁰ A1521 R^(B18) CH₃ G⁴⁰ A1522R^(B20) CH₃ G⁴⁰ A1523 R^(B22) CH₃ G⁴⁰ A1524 R^(B24) CH₃ G⁴⁰ A1525R^(B26) CH₃ G⁴⁰ A1526 R^(B28) CH₃ G⁴⁰ A1527 R^(B30) CH₃ G⁴⁰ A1528R^(B32) CH₃ G⁴⁰ A1529 R^(B34) CH₃ G⁴⁰ A1530 R^(B36) CH₃ G⁴⁰ A1531R^(B38) CH₃ G⁴⁰ A1532 R^(B40) CH₃ G⁴⁰ A1533 R^(B42) CH₃ G⁴⁰ A1534R^(B44) CH₃ G⁴⁰ A1535 R^(B46) CH₃ G⁴⁰ A1536 R^(B48) CH₃ G⁴⁰ A1537R^(B50) CH₃ G⁴⁰ A1538 R^(B52) CH₃ G⁴⁰ A1539 R^(B54) CH₃ G⁴⁰ A1540R^(B56) CH₃ G⁴⁰ A1541 R^(B58) CH₃ G⁴⁰ A1542 R^(B60) CH₃ G⁴⁰ A1543 CH₃R^(B2) G⁴¹ A1544 CH₃ R^(B4) G⁴¹ A1545 CH₃ R^(B6) G⁴¹ A1546 CH₃ R^(B8)G⁴¹ A1547 CH₃ R^(B10) G⁴¹ A1548 CH₃ R^(B12) G⁴¹ A1549 CH₃ R^(B14) G⁴¹A1550 CH₃ R^(B16) G⁴¹ A1551 CH₃ R^(B18) G⁴¹ A1552 CH₃ R^(B20) G⁴¹ A1553CH₃ R^(B22) G⁴¹ A1554 CH₃ R^(B24) G⁴¹ A1555 CH₃ R^(B26) G⁴¹ A1556 CH₃R^(B28) G⁴¹ A1557 CH₃ R^(B30) G⁴¹ A1558 CH₃ R^(B32) G⁴¹ A1559 CH₃R^(B34) G⁴¹ A1560 CH₃ R^(B36) G⁴¹ A1561 CH₃ R^(B37) G⁴¹ A1562 CH₃R^(B39) G⁴¹ A1563 CH₃ R^(B41) G⁴¹ A1564 CH₃ R^(B43) G⁴¹ A1565 CH₃R^(B45) G⁴¹ A1566 CH₃ R^(B47) G⁴¹ A1567 CH₃ R^(B49) G⁴¹ A1568 CH₃R^(B51) G⁴¹ A1569 CH₃ R^(B53) G⁴¹ A1570 CH₃ R^(B55) G⁴¹ A1571 CH₃R^(B57) G⁴¹ A1572 CH₃ R^(B59) G⁴¹ A1573 R^(B1) CH₃ G⁴¹ A1574 R^(B3) CH₃G⁴¹ A1575 R^(B5) CH₃ G⁴¹ A1576 R^(B7) CH₃ G⁴¹ A1577 R^(B9) CH₃ G⁴¹ A1578R^(B11) CH₃ G⁴¹ A1579 R^(B13) CH₃ G⁴¹ A1580 R^(B15) CH₃ G⁴¹ A1581R^(B17) CH₃ G⁴¹ A1582 R^(B19) CH₃ G⁴¹ A1583 R^(B21) CH₃ G⁴¹ A1584R^(B23) CH₃ G⁴¹ A1585 R^(B25) CH₃ G⁴¹ A1586 R^(B27) CH₃ G⁴¹ A1587R^(B29) CH₃ G⁴¹ A1588 R^(B31) CH₃ G⁴¹ A1589 R^(B33) CH₃ G⁴¹ A1590R^(B35) CH₃ G⁴¹ A1591 R^(B37) CH₃ G⁴¹ A1592 R^(B39) CH₃ G⁴¹ A1593R^(B41) CH₃ G⁴¹ A1594 R^(B43) CH₃ G⁴¹ A1595 R^(B45) CH₃ G⁴¹ A1596R^(B47) CH₃ G⁴¹ A1597 R^(B49) CH₃ G⁴¹ A1598 R^(B51) CH₃ G⁴¹ A1599R^(B53) CH₃ G⁴¹ A1600 R^(B55) CH₃ G⁴¹ A1601 R^(B57) CH₃ G⁴¹ A1602R^(B59) CH₃ G⁴¹ A1603 CH₃ R^(B1) G⁴² A1604 CH₃ R^(B3) G⁴² A1605 CH₃R^(B5) G⁴² A1606 CH₃ R^(B7) G⁴² A1607 CH₃ R^(B9) G⁴² A1608 CH₃ R^(B11)G⁴² A1609 CH₃ R^(B13) G⁴² A1610 CH₃ R^(B15) G⁴² A1611 CH₃ R^(B17) G⁴²A1612 CH₃ R^(B19) G⁴² A1613 CH₃ R^(B21) G⁴² A1614 CH₃ R^(B23) G⁴² A1615CH₃ R^(B25) G⁴² A1616 CH₃ R^(B27) G⁴² A1617 CH₃ R^(B29) G⁴² A1618 CH₃R^(B31) G⁴² A1619 CH₃ R^(B33) G⁴² A1620 CH₃ R^(B35) G⁴² A1621 CH₃R^(B37) G⁴² A1622 CH₃ R^(B39) G⁴² A1623 CH₃ R^(B41) G⁴² A1624 CH₃R^(B43) G⁴² A1625 CH₃ R^(B45) G⁴² A1626 CH₃ R^(B47) G⁴² A1627 CH₃R^(B49) G⁴² A1628 CH₃ R^(B51) G⁴² A1629 CH₃ R^(B53) G⁴² A1630 CH₃R^(B55) G⁴² A1631 CH₃ R^(B57) G⁴² A1632 CH₃ R^(B59) G⁴² A1633 R^(B1) CH₃G⁴² A1634 R^(B3) CH₃ G⁴² A1635 R^(B5) CH₃ G⁴² A1636 R^(B7) CH₃ G⁴² A1637R^(B9) CH₃ G⁴² A1638 R^(B11) CH₃ G⁴² A1639 R^(B13) CH₃ G⁴² A1640 R^(B15)CH₃ G⁴² A1641 R^(B17) CH₃ G⁴² A1642 R^(B19) CH₃ G⁴² A1643 R^(B21) CH₃G⁴² A1644 R^(B23) CH₃ G⁴² A1645 R^(B25) CH₃ G⁴² A1646 R^(B27) CH₃ G⁴²A1647 R^(B29) CH₃ G⁴² A1648 R^(B31) CH₃ G⁴² A1649 R^(B33) CH₃ G⁴² A1650R^(B35) CH₃ G⁴² A1651 R^(B37) CH₃ G⁴² A1652 R^(B39) CH₃ G⁴² A1653R^(B41) CH₃ G⁴² A1654 R^(B43) CH₃ G⁴² A1655 R^(B45) CH₃ G⁴² A1656R^(B47) CH₃ G⁴² A1657 R^(B49) CH₃ G⁴² A1658 R^(B51) CH₃ G⁴² A1659R^(B53) CH₃ G⁴² A1660 R^(B55) CH₃ G⁴² A1661 R^(B57) CH₃ G⁴² A1662R^(B59) CH₃ G⁴² A1663 CH₃ R^(B38) G⁴¹ A1664 CH₃ R^(B40) G⁴¹ A1665 CH₃R^(B42) G⁴¹ A1666 CH₃ R^(B44) G⁴¹ A1667 CH₃ R^(B46) G⁴¹ A1668 CH₃R^(B48) G⁴¹ A1669 CH₃ R^(B50) G⁴¹ A1670 CH₃ R^(B52) G⁴¹ A1671 CH₃R^(B54) G⁴¹ A1672 CH₃ R^(B56) G⁴¹ A1673 CH₃ R^(B58) G⁴¹ A1674 CH₃R^(B60) G⁴¹ A1675 R^(B2) CH₃ G⁴¹ A1676 R^(B4) CH₃ G⁴¹ A1677 R^(B6) CH₃G⁴¹ A1678 R^(B8) CH₃ G⁴¹ A1679 R^(B10) CH₃ G⁴¹ A1680 R^(B12) CH₃ G⁴¹A1681 R^(B14) CH₃ G⁴¹ A1682 R^(B16) CH₃ G⁴¹ A1683 R^(B18) CH₃ G⁴¹ A1684R^(B20) CH₃ G⁴¹ A1685 R^(B22) CH₃ G⁴¹ A1686 R^(B24) CH₃ G⁴¹ A1687R^(B26) CH₃ G⁴¹ A1688 R^(B28) CH₃ G⁴¹ A1689 R^(B30) CH₃ G⁴¹ A1690R^(B32) CH₃ G⁴¹ A1691 R^(B34) CH₃ G⁴¹ A1692 R^(B36) CH₃ G⁴¹ A1693R^(B38) CH₃ G⁴¹ A1694 R^(B40) CH₃ G⁴¹ A1695 R^(B42) CH₃ G⁴¹ A1696R^(B44) CH₃ G⁴¹ A1697 R^(B46) CH₃ G⁴¹ A1698 R^(B48) CH₃ G⁴¹ A1699R^(B50) CH₃ G⁴¹ A1700 R^(B52) CH₃ G⁴¹ A1701 R^(B54) CH₃ G⁴¹ A1702R^(B56) CH₃ G⁴¹ A1703 R^(B58) CH₃ G⁴¹ A1704 R^(B60) CH₃ G⁴¹ A1705 CH₃R^(B2) G⁴² A1706 CH₃ R^(B4) G⁴² A1707 CH₃ R^(B6) G⁴² A1708 CH₃ R^(B8)G⁴² A1709 CH₃ R^(B10) G⁴² A1710 CH₃ R^(B12) G⁴² A1711 CH₃ R^(B14) G⁴²A1712 CH₃ R^(B16) G⁴² A1713 CH₃ R^(B18) G⁴² A1714 CH₃ R^(B20) G⁴² A1715CH₃ R^(B22) G⁴² A1716 CH₃ R^(B24) G⁴² A1717 CH₃ R^(B26) G⁴² A1718 CH₃R^(B28) G⁴² A1719 CH₃ R^(B30) G⁴² A1720 CH₃ R^(B32) G⁴² A1721 CH₃R^(B34) G⁴² A1722 CH₃ R^(B36) G⁴² A1723 CH₃ R^(B38) G⁴² A1724 CH₃R^(B40) G⁴² A1725 CH₃ R^(B42) G⁴² A1726 CH₃ R^(B44) G⁴² A1727 CH₃R^(B46) G⁴² A1728 CH₃ R^(B48) G⁴² A1729 CH₃ R^(B50) G⁴² A1730 CH₃R^(B52) G⁴² A1731 CH₃ R^(B54) G⁴² A1732 CH₃ R^(B56) G⁴² A1733 CH₃R^(B58) G⁴² A1734 CH₃ R^(B60) G⁴² A1735 R^(B2) CH₃ G⁴² A1736 R^(B4) CH₃G⁴² A1737 R^(B6) CH₃ G⁴² A1738 R^(B8) CH₃ G⁴² A1739 R^(B10) CH₃ G⁴²A1740 R^(B12) CH₃ G⁴² A1741 R^(B14) CH₃ G⁴² A1742 R^(B16) CH₃ G⁴² A1743R^(B18) CH₃ G⁴² A1744 R^(B20) CH₃ G⁴² A1745 R^(B22) CH₃ G⁴² A1746R^(B24) CH₃ G⁴² A1747 R^(B26) CH₃ G⁴² A1748 R^(B28) CH₃ G⁴² A1749R^(B30) CH₃ G⁴² A1750 R^(B32) CH₃ G⁴² A1751 R^(B34) CH₃ G⁴² A1752R^(B36) CH₃ G⁴² A1753 R^(B38) CH₃ G⁴² A1754 R^(B40) CH₃ G⁴² A1755R^(B42) CH₃ G⁴² A1756 R^(B44) CH₃ G⁴² A1757 R^(B46) CH₃ G⁴² A1758R^(B48) CH₃ G⁴² A1759 R^(B50) CH₃ G⁴² A1760 R^(B52) CH₃ G⁴² A1761R^(B54) CH₃ G⁴² A1762 R^(B56) CH₃ G⁴² A1763 R^(B58) CH₃ G⁴² A1764R^(B60) CH₃ G⁴²

wherein R^(B1) to R^(B60) have the following structures:

wherein G¹ to G⁴⁸ have the following structures:

and wherein the Arabic Numerals indicate the points of attachment to thecorresponding points of attachment in ligand L_(A).
 10. The compound ofclaim 9, wherein the compound is Compound Ai-F having the formulaIr(L_(Ai-F))₃, Compound By-F having the formula Ir(L_(Ai-F))(L_(Bk))₂,or Compound Cz-F having the formula Ir(L_(Ai-F))₂(L_(Cj)); wherein i isan integer from 1 to 1764, and k is an integer from 1 to 490, j is aninteger from 1 to 1260, y=490i+k-4908, and z=1764i+j-1764; and wherein Fis O, S, or C; wherein L_(Bk) is selected from the group consisting ofthe following structures:

wherein L_(C1) through L_(C1260) are based on a structure of Formula X

in which R¹, R², and R³ are defined as: Ligand R¹ R² R³ L_(C1) R^(D1)R^(D1) H L_(C2) R^(D2) R^(D2) H L_(C3) R^(D3) R^(D3) H L_(C4) R^(D4)R^(D4) H L_(C5) R^(D5) R^(D5) H L_(C6) R^(D6) R^(D6) H L_(C7) R^(D7)R^(D7) H L_(C8) R^(D8) R^(D8) H L_(C9) R^(D9) R^(D9) H L_(C10) R^(D10)R^(D10) H L_(C11) R^(D11) R^(D11) H L_(C12) R^(D12) R^(D12) H L_(C13)R^(D13) R^(D13) H L_(C14) R^(D14) R^(D14) H L_(C15) R^(D15) R^(D15) HL_(C16) R^(D16) R^(D16) H L_(C17) R^(D17) R^(D17) H L_(C18) R^(D18)R^(D18) H L_(C19) R^(D19) R^(D19) H L_(C20) R^(D20) R^(D20) H L_(C21)R^(D21) R^(D21) H L_(C22) R^(D22) R^(D22) H L_(C23) R^(D23) R^(D23) HL_(C24) R^(D24) R^(D24) H L_(C25) R^(D25) R^(D25) H L_(C26) R^(D26)R^(D26) H L_(C27) R^(D27) R^(D27) H L_(C28) R^(D28) R^(D28) H L_(C29)R^(D29) R^(D29) H L_(C30) R^(D30) R^(D30) H L_(C31) R^(D31) R^(D31) HL_(C32) R^(D32) R^(D32) H L_(C33) R^(D33) R^(D33) H L_(C34) R^(D34)R^(D34) H L_(C35) R^(D35) R^(D35) H L_(C36) R^(D40) R^(D40) H L_(C37)R^(D41) R^(D41) H L_(C38) R^(D42) R^(D42) H L_(C39) R^(D64) R^(D64) HL_(C40) R^(D66) R^(D66) H L_(C41) R^(D68) R^(D68) H L_(C42) R^(D76)R^(D76) H L_(C43) R^(D1) R^(D2) H L_(C44) R^(D1) R^(D3) H L_(C45) R^(D1)R^(D4) H L_(C46) R^(D1) R^(D5) H L_(C47) R^(D1) R^(D6) H L_(C48) R^(D1)R^(D7) H L_(C49) R^(D1) R^(D8) H L_(C50) R^(D1) R^(D9) H L_(C51) R^(D1)R^(D10) H L_(C52) R^(D1) R^(D11) H L_(C53) R^(D1) R^(D12) H L_(C54)R^(D1) R^(D13) H L_(C55) R^(D1) R^(D14) H L_(C56) R^(D1) R^(D15) HL_(C57) R^(D1) R^(D16) H L_(C58) R^(D1) R^(D17) H L_(C59) R^(D1) R^(D18)H L_(C60) R^(D1) R^(D19) H L_(C61) R^(D1) R^(D20) H L_(C62) R^(D1)R^(D21) H L_(C63) R^(D1) R^(D22) H L_(C64) R^(D1) R^(D23) H L_(C65)R^(D1) R^(D24) H L_(C66) R^(D1) R^(D25) H L_(C67) R^(D1) R^(D26) HL_(C68) R^(D1) R^(D27) H L_(C69) R^(D1) R^(D28) H L_(C70) R^(D1) R^(D29)H L_(C71) R^(D1) R^(D30) H L_(C72) R^(D1) R^(D31) H L_(C73) R^(D1)R^(D32) H L_(C74) R^(D1) R^(D33) H L_(C75) R^(D1) R^(D34) H L_(C76)R^(D1) R^(D35) H L_(C77) R^(D1) R^(D40) H L_(C78) R^(D1) R^(D41) HL_(C79) R^(D1) R^(D42) H L_(C80) R^(D1) R^(D64) H L_(C81) R^(D1) R^(D66)H L_(C82) R^(D1) R^(D68) H L_(C83) R^(D1) R^(D76) H L_(C84) R^(D2)R^(D1) H L_(C85) R^(D2) R^(D3) H L_(C86) R^(D2) R^(D4) H L_(C87) R^(D2)R^(D5) H L_(C88) R^(D2) R^(D6) H L_(C89) R^(D2) R^(D7) H L_(C90) R^(D2)R^(D8) H L_(C91) R^(D2) R^(D9) H L_(C92) R^(D2) R^(D10) H L_(C93) R^(D2)R^(D11) H L_(C94) R^(D2) R^(D12) H L_(C95) R^(D2) R^(D13) H L_(C96)R^(D2) R^(D14) H L_(C97) R^(D2) R^(D15) H L_(C98) R^(D2) R^(D16) HL_(C99) R^(D2) R^(D17) H L_(C100) R^(D2) R^(D18) H L_(C101) R^(D2)R^(D19) H L_(C102) R^(D2) R^(D20) H L_(C103) R^(D2) R^(D21) H L_(C104)R^(D2) R^(D22) H L_(C105) R^(D2) R^(D23) H L_(C106) R^(D2) R^(D24) HL_(C107) R^(D2) R^(D25) H L_(C108) R^(D2) R^(D26) H L_(C109) R^(D2)R^(D27) H L_(C110) R^(D2) R^(D28) H L_(C111) R^(D2) R^(D29) H L_(C112)R^(D2) R^(D30) H L_(C113) R^(D2) R^(D31) H L_(C114) R^(D2) R^(D32) HL_(C115) R^(D2) R^(D33) H L_(C116) R^(D2) R^(D34) H L_(C117) R^(D2)R^(D35) H L_(C118) R^(D2) R^(D40) H L_(C119) R^(D2) R^(D41) H L_(C120)R^(D2) R^(D42) H L_(C121) R^(D2) R^(D64) H L_(C122) R^(D2) R^(D66) HL_(C123) R^(D2) R^(D68) H L_(C124) R^(D2) R^(D76) H L_(C125) R^(D3)R^(D4) H L_(C126) R^(D3) R^(D5) H L_(C127) R^(D3) R^(D6) H L_(C128)R^(D3) R^(D7) H L_(C129) R^(D3) R^(D8) H L_(C130) R^(D3) R^(D9) HL_(C131) R^(D3) R^(D10) H L_(C132) R^(D3) R^(D11) H L_(C133) R^(D3)R^(D12) H L_(C134) R^(D3) R^(D13) H L_(C135) R^(D3) R^(D14) H L_(C136)R^(D3) R^(D15) H L_(C137) R^(D3) R^(D16) H L_(C138) R^(D3) R^(D17) HL_(C139) R^(D3) R^(D18) H L_(C140) R^(D3) R^(D19) H L_(C141) R^(D3)R^(D20) H L_(C142) R^(D3) R^(D21) H L_(C143) R^(D3) R^(D22) H L_(C144)R^(D3) R^(D23) H L_(C145) R^(D3) R^(D24) H L_(C146) R^(D3) R^(D25) HL_(C147) R^(D3) R^(D26) H L_(C148) R^(D3) R^(D27) H L_(C149) R^(D3)R^(D28) H L_(C150) R^(D3) R^(D29) H L_(C151) R^(D3) R^(D30) H L_(C152)R^(D3) R^(D31) H L_(C153) R^(D3) R^(D32) H L_(C154) R^(D3) R^(D33) HL_(C155) R^(D3) R^(D34) H L_(C156) R^(D3) R^(D35) H L_(C157) R^(D3)R^(D40) H L_(C158) R^(D3) R^(D41) H L_(C159) R^(D3) R^(D42) H L_(C160)R^(D3) R^(D64) H L_(C161) R^(D3) R^(D66) H L_(C162) R^(D3) R^(D68) HL_(C163) R^(D3) R^(D76) H L_(C164) R^(D4) R^(D5) H L_(C165) R^(D4)R^(D6) H L_(C166) R^(D4) R^(D7) H L_(C167) R^(D4) R^(D8) H L_(C168)R^(D4) R^(D9) H L_(C169) R^(D4) R^(D10) H L_(C170) R^(D4) R^(D11) HL_(C171) R^(D4) R^(D12) H L_(C172) R^(D4) R^(D13) H L_(C173) R^(D4)R^(D14) H L_(C174) R^(D4) R^(D15) H L_(C175) R^(D4) R^(D16) H L_(C176)R^(D4) R^(D17) H L_(C177) R^(D4) R^(D18) H L_(C178) R^(D4) R^(D19) HL_(C179) R^(D4) R^(D20) H L_(C180) R^(D4) R^(D21) H L_(C181) R^(D4)R^(D22) H L_(C182) R^(D4) R^(D23) H L_(C183) R^(D4) R^(D24) H L_(C184)R^(D4) R^(D25) H L_(C185) R^(D4) R^(D26) H L_(C186) R^(D4) R^(D27) HL_(C187) R^(D4) R^(D28) H L_(C188) R^(D4) R^(D29) H L_(C189) R^(D4)R^(D30) H L_(C190) R^(D4) R^(D31) H L_(C191) R^(D4) R^(D32) H L_(C192)R^(D4) R^(D33) H L_(C193) R^(D4) R^(D34) H L_(C194) R^(D4) R^(D35) HL_(C195) R^(D4) R^(D40) H L_(C196) R^(D4) R^(D41) H L_(C197) R^(D4)R^(D42) H L_(C198) R^(D4) R^(D64) H L_(C199) R^(D4) R^(D66) H L_(C200)R^(D4) R^(D68) H L_(C201) R^(D4) R^(D76) H L_(C202) R^(D4) R^(D1) HL_(C203) R^(D7) R^(D5) H L_(C204) R^(D7) R^(D6) H L_(C205) R^(D7) R^(D8)H L_(C206) R^(D7) R^(D9) H L_(C207) R^(D7) R^(D10) H L_(C208) R^(D7)R^(D11) H L_(C209) R^(D7) R^(D12) H L_(C210) R^(D7) R^(D13) H L_(C211)R^(D7) R^(D14) H L_(C212) R^(D7) R^(D15) H L_(C213) R^(D7) R^(D16) HL_(C214) R^(D7) R^(D17) H L_(C215) R^(D7) R^(D18) H L_(C216) R^(D7)R^(D19) H L_(C217) R^(D7) R^(D20) H L_(C218) R^(D7) R^(D21) H L_(C219)R^(D7) R^(D22) H L_(C220) R^(D7) R^(D23) H L_(C221) R^(D7) R^(D24) HL_(C222) R^(D7) R^(D25) H L_(C223) R^(D7) R^(D26) H L_(C224) R^(D7)R^(D27) H L_(C225) R^(D7) R^(D28) H L_(C226) R^(D7) R^(D29) H L_(C227)R^(D7) R^(D30) H L_(C228) R^(D7) R^(D31) H L_(C229) R^(D7) R^(D32) HL_(C230) R^(D7) R^(D33) H L_(C231) R^(D7) R^(D34) H L_(C232) R^(D7)R^(D35) H L_(C233) R^(D7) R^(D40) H L_(C234) R^(D7) R^(D41) H L_(C235)R^(D7) R^(D42) H L_(C236) R^(D7) R^(D64) H L_(C237) R^(D7) R^(D66) HL_(C238) R^(D7) R^(D68) H L_(C239) R^(D7) R^(D76) H L_(C240) R^(D8)R^(D5) H L_(C241) R^(D8) R^(D6) H L_(C242) R^(D8) R^(D9) H L_(C243)R^(D8) R^(D10) H L_(C244) R^(D8) R^(D11) H L_(C245) R^(D8) R^(D12) HL_(C246) R^(D8) R^(D13) H L_(C247) R^(D8) R^(D14) H L_(C248) R^(D8)R^(D15) H L_(C249) R^(D8) R^(D16) H L_(C250) R^(D8) R^(D17) H L_(C251)R^(D8) R^(D18) H L_(C252) R^(D8) R^(D19) H L_(C253) R^(D8) R^(D20) HL_(C254) R^(D8) R^(D21) H L_(C255) R^(D8) R^(D22) H L_(C256) R^(D8)R^(D23) H L_(C257) R^(D8) R^(D24) H L_(C258) R^(D8) R^(D25) H L_(C259)R^(D8) R^(D26) H L_(C260) R^(D8) R^(D27) H L_(C261) R^(D8) R^(D28) HL_(C262) R^(D8) R^(D29) H L_(C263) R^(D8) R^(D30) H L_(C264) R^(D8)R^(D31) H L_(C265) R^(D8) R^(D32) H L_(C266) R^(D8) R^(D33) H L_(C267)R^(D8) R^(D34) H L_(C268) R^(D8) R^(D35) H L_(C269) R^(D8) R^(D40) HL_(C270) R^(D8) R^(D41) H L_(C271) R^(D8) R^(D42) H L_(C272) R^(D8)R^(D64) H L_(C273) R^(D8) R^(D66) H L_(C274) R^(D8) R^(D68) H L_(C275)R^(D8) R^(D76) H L_(C276) R^(D11) R^(D5) H L_(C277) R^(D11) R^(D6) HL_(C278) R^(D11) R^(D9) H L_(C279) R^(D11) R^(D10) H L_(C280) R^(D11)R^(D12) H L_(C281) R^(D11) R^(D13) H L_(C282) R^(D11) R^(D14) H L_(C283)R^(D11) R^(D15) H L_(C284) R^(D11) R^(D16) H L_(C285) R^(D11) R^(D17) HL_(C286) R^(D11) R^(D18) H L_(C287) R^(D11) R^(D19) H L_(C288) R^(D11)R^(D20) H L_(C289) R^(D11) R^(D21) H L_(C290) R^(D11) R^(D22) H L_(C291)R^(D11) R^(D23) H L_(C292) R^(D11) R^(D24) H L_(C293) R^(D11) R^(D25) HL_(C294) R^(D11) R^(D26) H L_(C295) R^(D11) R^(D27) H L_(C296) R^(D11)R^(D28) H L_(C297) R^(D11) R^(D29) H L_(C298) R^(D11) R^(D30) H L_(C299)R^(D11) R^(D31) H L_(C300) R^(D11) R^(D32) H L_(C301) R^(D11) R^(D33) HL_(C302) R^(D11) R^(D34) H L_(C303) R^(D11) R^(D35) H L_(C304) R^(D11)R^(D40) H L_(C305) R^(D11) R^(D41) H L_(C306) R^(D11) R^(D42) H L_(C307)R^(D11) R^(D64) H L_(C308) R^(D11) R^(D66) H L_(C309) R^(D11) R^(D68) HL_(C310) R^(D11) R^(D76) H L_(C311) R^(D13) R^(D5) H L_(C312) R^(D13)R^(D6) H L_(C313) R^(D13) R^(D9) H L_(C314) R^(D13) R^(D10) H L_(C315)R^(D13) R^(D12) H L_(C316) R^(D13) R^(D14) H L_(C317) R^(D13) R^(D15) HL_(C318) R^(D13) R^(D16) H L_(C319) R^(D13) R^(D17) H L_(C320) R^(D13)R^(D18) H L_(C321) R^(D13) R^(D19) H L_(C322) R^(D13) R^(D20) H L_(C323)R^(D13) R^(D21) H L_(C324) R^(D13) R^(D22) H L_(C325) R^(D13) R^(D23) HL_(C326) R^(D13) R^(D24) H L_(C327) R^(D13) R^(D25) H L_(C328) R^(D13)R^(D26) H L_(C329) R^(D13) R^(D27) H L_(C330) R^(D13) R^(D28) H L_(C331)R^(D13) R^(D29) H L_(C332) R^(D13) R^(D30) H L_(C333) R^(D13) R^(D31) HL_(C334) R^(D13) R^(D32) H L_(C335) R^(D13) R^(D33) H L_(C336) R^(D13)R^(D34) H L_(C337) R^(D13) R^(D35) H L_(C338) R^(D13) R^(D40) H L_(C339)R^(D13) R^(D41) H L_(C340) R^(D13) R^(D42) H L_(C341) R^(D13) R^(D64) HL_(C342) R^(D13) R^(D66) H L_(C343) R^(D13) R^(D68) H L_(C344) R^(D13)R^(D76) H L_(C345) R^(D14) R^(D5) H L_(C346) R^(D14) R^(D6) H L_(C347)R^(D14) R^(D9) H L_(C348) R^(D14) R^(D10) H L_(C349) R^(D14) R^(D12) HL_(C350) R^(D14) R^(D15) H L_(C351) R^(D14) R^(D16) H L_(C352) R^(D14)R^(D17) H L_(C353) R^(D14) R^(D18) H L_(C354) R^(D14) R^(D19) H L_(C355)R^(D14) R^(D20) H L_(C356) R^(D14) R^(D21) H L_(C357) R^(D14) R^(D22) HL_(C358) R^(D14) R^(D23) H L_(C359) R^(D14) R^(D24) H L_(C360) R^(D14)R^(D25) H L_(C361) R^(D14) R^(D26) H L_(C362) R^(D14) R^(D27) H L_(C363)R^(D14) R^(D28) H L_(C364) R^(D14) R^(D29) H L_(C365) R^(D14) R^(D30) HL_(C366) R^(D14) R^(D31) H L_(C367) R^(D14) R^(D32) H L_(C368) R^(D14)R^(D33) H L_(C369) R^(D14) R^(D34) H L_(C370) R^(D14) R^(D35) H L_(C371)R^(D14) R^(D40) H L_(C372) R^(D14) R^(D41) H L_(C373) R^(D14) R^(D42) HL_(C374) R^(D14) R^(D64) H L_(C375) R^(D14) R^(D66) H L_(C376) R^(D14)R^(D68) H L_(C377) R^(D14) R^(D76) H L_(C378) R^(D22) R^(D5) H L_(C379)R^(D22) R^(D6) H L_(C380) R^(D22) R^(D9) H L_(C381) R^(D22) R^(D10) HL_(C382) R^(D22) R^(D12) H L_(C383) R^(D22) R^(D15) H L_(C384) R^(D22)R^(D16) H L_(C385) R^(D22) R^(D17) H L_(C386) R^(D22) R^(D18) H L_(C387)R^(D22) R^(D19) H L_(C388) R^(D22) R^(D20) H L_(C389) R^(D22) R^(D21) HL_(C390) R^(D22) R^(D23) H L_(C391) R^(D22) R^(D24) H L_(C392) R^(D22)R^(D25) H L_(C393) R^(D22) R^(D26) H L_(C394) R^(D22) R^(D27) H L_(C395)R^(D22) R^(D28) H L_(C396) R^(D22) R^(D29) H L_(C397) R^(D22) R^(D30) HL_(C398) R^(D22) R^(D31) H L_(C399) R^(D22) R^(D32) H L_(C400) R^(D22)R^(D33) H L_(C401) R^(D22) R^(D34) H L_(C402) R^(D22) R^(D35) H L_(C403)R^(D22) R^(D40) H L_(C404) R^(D22) R^(D41) H L_(C405) R^(D22) R^(D42) HL_(C406) R^(D22) R^(D64) H L_(C407) R^(D22) R^(D66) H L_(C408) R^(D22)R^(D68) H L_(C409) R^(D22) R^(D76) H L_(C410) R^(D26) R^(D5) H L_(C411)R^(D26) R^(D6) H L_(C412) R^(D26) R^(D9) H L_(C413) R^(D26) R^(D10) HL_(C414) R^(D26) R^(D12) H L_(C415) R^(D26) R^(D15) H L_(C416) R^(D26)R^(D16) H L_(C417) R^(D26) R^(D17) H L_(C418) R^(D26) R^(D18) H L_(C419)R^(D26) R^(D19) H L_(C420) R^(D26) R^(D20) H L_(C421) R^(D26) R^(D21) HL_(C422) R^(D26) R^(D23) H L_(C423) R^(D26) R^(D24) H L_(C424) R^(D26)R^(D25) H L_(C425) R^(D26) R^(D27) H L_(C426) R^(D26) R^(D28) H L_(C427)R^(D26) R^(D29) H L_(C428) R^(D26) R^(D30) H L_(C429) R^(D26) R^(D31) HL_(C430) R^(D26) R^(D32) H L_(C431) R^(D26) R^(D33) H L_(C432) R^(D26)R^(D34) H L_(C433) R^(D26) R^(D35) H L_(C434) R^(D26) R^(D40) H L_(C435)R^(D26) R^(D41) H L_(C436) R^(D26) R^(D42) H L_(C437) R^(D26) R^(D64) HL_(C438) R^(D26) R^(D66) H L_(C439) R^(D26) R^(D68) H L_(C440) R^(D26)R^(D76) H L_(C441) R^(D35) R^(D5) H L_(C442) R^(D35) R^(D6) H L_(C443)R^(D35) R^(D9) H L_(C444) R^(D35) R^(D10) H L_(C445) R^(D35) R^(D12) HL_(C446) R^(D35) R^(D15) H L_(C447) R^(D35) R^(D16) H L_(C448) R^(D35)R^(D17) H L_(C449) R^(D35) R^(D18) H L_(C450) R^(D35) R^(D19) H L_(C451)R^(D35) R^(D20) H L_(C452) R^(D35) R^(D21) H L_(C453) R^(D35) R^(D23) HL_(C454) R^(D35) R^(D24) H L_(C455) R^(D35) R^(D25) H L_(C456) R^(D35)R^(D27) H L_(C457) R^(D35) R^(D28) H L_(C458) R^(D35) R^(D29) H L_(C459)R^(D35) R^(D30) H L_(C460) R^(D35) R^(D31) H L_(C461) R^(D35) R^(D32) HL_(C462) R^(D35) R^(D33) H L_(C463) R^(D35) R^(D34) H L_(C464) R^(D35)R^(D40) H L_(C465) R^(D35) R^(D41) H L_(C466) R^(D35) R^(D42) H L_(C467)R^(D35) R^(D64) H L_(C468) R^(D35) R^(D66) H L_(C469) R^(D35) R^(D68) HL_(C470) R^(D35) R^(D76) H L_(C471) R^(D40) R^(D5) H L_(C472) R^(D40)R^(D6) H L_(C473) R^(D40) R^(D9) H L_(C474) R^(D40) R^(D10) H L_(C475)R^(D40) R^(D12) H L_(C476) R^(D40) R^(D15) H L_(C477) R^(D40) R^(D16) HL_(C478) R^(D40) R^(D17) H L_(C479) R^(D40) R^(D18) H L_(C480) R^(D40)R^(D19) H L_(C481) R^(D40) R^(D20) H L_(C482) R^(D40) R^(D21) H L_(C483)R^(D40) R^(D23) H L_(C484) R^(D40) R^(D24) H L_(C485) R^(D40) R^(D25) HL_(C486) R^(D40) R^(D27) H L_(C487) R^(D40) R^(D28) H L_(C488) R^(D40)R^(D29) H L_(C489) R^(D40) R^(D30) H L_(C490) R^(D40) R^(D31) H L_(C491)R^(D40) R^(D32) H L_(C492) R^(D40) R^(D33) H L_(C493) R^(D40) R^(D34) HL_(C494) R^(D40) R^(D41) H L_(C495) R^(D40) R^(D42) H L_(C496) R^(D40)R^(D64) H L_(C497) R^(D40) R^(D66) H L_(C498) R^(D40) R^(D68) H L_(C499)R^(D40) R^(D76) H L_(C500) R^(D41) R^(D5) H L_(C501) R^(D41) R^(D6) HL_(C502) R^(D41) R^(D9) H L_(C503) R^(D41) R^(D10) H L_(C504) R^(D41)R^(D12) H L_(C505) R^(D41) R^(D15) H L_(C506) R^(D41) R^(D16) H L_(C507)R^(D41) R^(D17) H L_(C508) R^(D41) R^(D18) H L_(C509) R^(D41) R^(D19) HL_(C510) R^(D41) R^(D20) H L_(C511) R^(D41) R^(D21) H L_(C512) R^(D41)R^(D23) H L_(C513) R^(D41) R^(D24) H L_(C514) R^(D41) R^(D25) H L_(C515)R^(D41) R^(D27) H L_(C516) R^(D41) R^(D28) H L_(C517) R^(D41) R^(D29) HL_(C518) R^(D41) R^(D30) H L_(C519) R^(D41) R^(D31) H L_(C520) R^(D41)R^(D32) H L_(C521) R^(D41) R^(D33) H L_(C522) R^(D41) R^(D34) H L_(C523)R^(D41) R^(D42) H L_(C524) R^(D41) R^(D64) H L_(C525) R^(D41) R^(D66) HL_(C526) R^(D41) R^(D68) H L_(C527) R^(D41) R^(D76) H L_(C528) R^(D64)R^(D5) H L_(C529) R^(D64) R^(D6) H L_(C530) R^(D64) R^(D9) H L_(C531)R^(D64) R^(D10) H L_(C532) R^(D64) R^(D12) H L_(C533) R^(D64) R^(D15) HL_(C534) R^(D64) R^(D16) H L_(C535) R^(D64) R^(D17) H L_(C536) R^(D64)R^(D18) H L_(C537) R^(D64) R^(D19) H L_(C538) R^(D64) R^(D20) H L_(C539)R^(D64) R^(D21) H L_(C540) R^(D64) R^(D23) H L_(C541) R^(D64) R^(D24) HL_(C542) R^(D64) R^(D25) H L_(C543) R^(D64) R^(D27) H L_(C544) R^(D64)R^(D28) H L_(C545) R^(D64) R^(D29) H L_(C546) R^(D64) R^(D30) H L_(C547)R^(D64) R^(D31) H L_(C548) R^(D64) R^(D32) H L_(C549) R^(D64) R^(D33) HL_(C550) R^(D64) R^(D34) H L_(C551) R^(D64) R^(D42) H L_(C552) R^(D64)R^(D64) H L_(C553) R^(D64) R^(D66) H L_(C554) R^(D64) R^(D68) H L_(C555)R^(D64) R^(D76) H L_(C556) R^(D66) R^(D5) H L_(C557) R^(D66) R^(D6) HL_(C558) R^(D66) R^(D9) H L_(C559) R^(D66) R^(D10) H L_(C560) R^(D66)R^(D12) H L_(C561) R^(D66) R^(D15) H L_(C562) R^(D66) R^(D16) H L_(C563)R^(D66) R^(D17) H L_(C564) R^(D66) R^(D18) H L_(C565) R^(D66) R^(D19) HL_(C566) R^(D66) R^(D20) H L_(C567) R^(D66) R^(D21) H L_(C568) R^(D66)R^(D23) H L_(C569) R^(D66) R^(D24) H L_(C570) R^(D66) R^(D25) H L_(C571)R^(D66) R^(D27) H L_(C572) R^(D66) R^(D28) H L_(C573) R^(D66) R^(D29) HL_(C574) R^(D66) R^(D30) H L_(C575) R^(D66) R^(D31) H L_(C576) R^(D66)R^(D32) H L_(C577) R^(D66) R^(D33) H L_(C578) R^(D66) R^(D34) H L_(C579)R^(D66) R^(D42) H L_(C580) R^(D66) R^(D68) H L_(C581) R^(D66) R^(D76) HL_(C582) R^(D68) R^(D5) H L_(C583) R^(D68) R^(D6) H L_(C584) R^(D68)R^(D9) H L_(C585) R^(D68) R^(D10) H L_(C586) R^(D68) R^(D12) H L_(C587)R^(D68) R^(D15) H L_(C588) R^(D68) R^(D16) H L_(C589) R^(D68) R^(D17) HL_(C590) R^(D68) R^(D18) H L_(C591) R^(D68) R^(D19) H L_(C592) R^(D68)R^(D20) H L_(C593) R^(D68) R^(D21) H L_(C594) R^(D68) R^(D23) H L_(C595)R^(D68) R^(D24) H L_(C596) R^(D68) R^(D25) H L_(C597) R^(D68) R^(D27) HL_(C598) R^(D68) R^(D28) H L_(C599) R^(D68) R^(D29) H L_(C600) R^(D68)R^(D30) H L_(C601) R^(D68) R^(D31) H L_(C602) R^(D68) R^(D32) H L_(C603)R^(D68) R^(D33) H L_(C604) R^(D68) R^(D34) H L_(C605) R^(D68) R^(D42) HL_(C606) R^(D68) R^(D76) H L_(C607) R^(D76) R^(D5) H L_(C608) R^(D76)R^(D6) H L_(C609) R^(D76) R^(D9) H L_(C610) R^(D76) R^(D10) H L_(C611)R^(D76) R^(D12) H L_(C612) R^(D76) R^(D15) H L_(C613) R^(D76) R^(D16) HL_(C614) R^(D76) R^(D17) H L_(C615) R^(D76) R^(D18) H L_(C616) R^(D76)R^(D19) H L_(C617) R^(D76) R^(D20) H L_(C618) R^(D76) R^(D21) H L_(C619)R^(D76) R^(D23) H L_(C620) R^(D76) R^(D24) H L_(C621) R^(D76) R^(D25) HL_(C622) R^(D76) R^(D27) H L_(C623) R^(D76) R^(D28) H L_(C624) R^(D76)R^(D29) H L_(C625) R^(D76) R^(D30) H L_(C626) R^(D76) R^(D31) H L_(C627)R^(D76) R^(D32) H L_(C628) R^(D76) R^(D33) H L_(C629) R^(D76) R^(D34) HL_(C630) R^(D76) R^(D42) H L_(C631) R^(D1) R^(D1) R^(D1) L_(C632) R^(D2)R^(D2) R^(D1) L_(C633) R^(D3) R^(D3) R^(D1) L_(C634) R^(D4) R^(D4)R^(D1) L_(C635) R^(D5) R^(D5) R^(D1) L_(C636) R^(D6) R^(D6) R^(D1)L_(C637) R^(D7) R^(D7) R^(D1) L_(C638) R^(D8) R^(D8) R^(D1) L_(C639)R^(D9) R^(D9) R^(D1) L_(C640) R^(D10) R^(D10) R^(D1) L_(C641) R^(D11)R^(D11) R^(D1) L_(C642) R^(D12) R^(D12) R^(D1) L_(C643) R^(D13) R^(D13)R^(D1) L_(C644) R^(D14) R^(D14) R^(D1) L_(C645) R^(D15) R^(D15) R^(D1)L_(C646) R^(D16) R^(D16) R^(D1) L_(C647) R^(D17) R^(D17) R^(D1) L_(C648)R^(D18) R^(D18) R^(D1) L_(C649) R^(D19) R^(D19) R^(D1) L_(C650) R^(D20)R^(D20) R^(D1) L_(C651) R^(D21) R^(D21) R^(D1) L_(C652) R^(D22) R^(D22)R^(D1) L_(C653) R^(D23) R^(D23) R^(D1) L_(C654) R^(D24) R^(D24) R^(D1)L_(C655) R^(D25) R^(D25) R^(D1) L_(C656) R^(D26) R^(D26) R^(D1) L_(C657)R^(D27) R^(D27) R^(D1) L_(C658) R^(D28) R^(D28) R^(D1) L_(C659) R^(D29)R^(D29) R^(D1) L_(C660) R^(D30) R^(D30) R^(D1) L_(C661) R^(D31) R^(D31)R^(D1) L_(C662) R^(D32) R^(D32) R^(D1) L_(C663) R^(D33) R^(D33) R^(D1)L_(C664) R^(D34) R^(D34) R^(D1) L_(C665) R^(D35) R^(D35) R^(D1) L_(C666)R^(D40) R^(D40) R^(D1) L_(C667) R^(D41) R^(D41) R^(D1) L_(C668) R^(D42)R^(D42) R^(D1) L_(C669) R^(D64) R^(D64) R^(D1) L_(C670) R^(D66) R^(D66)R^(D1) L_(C671) R^(D68) R^(D68) R^(D1) L_(C672) R^(D76) R^(D76) R^(D1)L_(C673) R^(D1) R^(D2) R^(D1) L_(C674) R^(D1) R^(D3) R^(D1) L_(C675)R^(D1) R^(D4) R^(D1) L_(C676) R^(D1) R^(D5) R^(D1) L_(C677) R^(D1)R^(D6) R^(D1) L_(C678) R^(D1) R^(D7) R^(D1) L_(C679) R^(D1) R^(D8)R^(D1) L_(C680) R^(D1) R^(D9) R^(D1) L_(C681) R^(D1) R^(D10) R^(D1)L_(C682) R^(D1) R^(D11) R^(D1) L_(C683) R^(D1) R^(D12) R^(D1) L_(C684)R^(D1) R^(D13) R^(D1) L_(C685) R^(D1) R^(D14) R^(D1) L_(C686) R^(D1)R^(D15) R^(D1) L_(C687) R^(D1) R^(D16) R^(D1) L_(C688) R^(D1) R^(D17)R^(D1) L_(C689) R^(D1) R^(D18) R^(D1) L_(C690) R^(D1) R^(D19) R^(D1)L_(C691) R^(D1) R^(D20) R^(D1) L_(C692) R^(D1) R^(D21) R^(D1) L_(C693)R^(D1) R^(D22) R^(D1) L_(C694) R^(D1) R^(D23) R^(D1) L_(C695) R^(D1)R^(D24) R^(D1) L_(C696) R^(D1) R^(D25) R^(D1) L_(C697) R^(D1) R^(D26)R^(D1) L_(C698) R^(D1) R^(D27) R^(D1) L_(C699) R^(D1) R^(D28) R^(D1)L_(C700) R^(D1) R^(D29) R^(D1) L_(C701) R^(D1) R^(D30) R^(D1) L_(C702)R^(D1) R^(D31) R^(D1) L_(C703) R^(D1) R^(D32) R^(D1) L_(C704) R^(D1)R^(D33) R^(D1) L_(C705) R^(D1) R^(D34) R^(D1) L_(C706) R^(D1) R^(D35)R^(D1) L_(C707) R^(D1) R^(D40) R^(D1) L_(C708) R^(D1) R^(D41) R^(D1)L_(C709) R^(D1) R^(D42) R^(D1) L_(C710) R^(D1) R^(D64) R^(D1) L_(C711)R^(D1) R^(D66) R^(D1) L_(C712) R^(D1) R^(D68) R^(D1) L_(C713) R^(D1)R^(D76) R^(D1) L_(C714) R^(D2) R^(D1) R^(D1) L_(C715) R^(D2) R^(D3)R^(D1) L_(C716) R^(D2) R^(D4) R^(D1) L_(C717) R^(D2) R^(D5) R^(D1)L_(C718) R^(D2) R^(D6) R^(D1) L_(C719) R^(D2) R^(D7) R^(D1) L_(C720)R^(D2) R^(D8) R^(D1) L_(C721) R^(D2) R^(D9) R^(D1) L_(C722) R^(D2)R^(D10) R^(D1) L_(C723) R^(D2) R^(D11) R^(D1) L_(C724) R^(D2) R^(D12)R^(D1) L_(C725) R^(D2) R^(D13) R^(D1) L_(C726) R^(D2) R^(D14) R^(D1)L_(C727) R^(D2) R^(D15) R^(D1) L_(C728) R^(D2) R^(D16) R^(D1) L_(C729)R^(D2) R^(D17) R^(D1) L_(C730) R^(D2) R^(D18) R^(D1) L_(C731) R^(D2)R^(D19) R^(D1) L_(C732) R^(D2) R^(D20) R^(D1) L_(C733) R^(D2) R^(D21)R^(D1) L_(C734) R^(D2) R^(D22) R^(D1) L_(C735) R^(D2) R^(D23) R^(D1)L_(C736) R^(D2) R^(D24) R^(D1) L_(C737) R^(D2) R^(D25) R^(D1) L_(C738)R^(D2) R^(D26) R^(D1) L_(C739) R^(D2) R^(D27) R^(D1) L_(C740) R^(D2)R^(D28) R^(D1) L_(C741) R^(D2) R^(D29) R^(D1) L_(C742) R^(D2) R^(D30)R^(D1) L_(C743) R^(D2) R^(D31) R^(D1) L_(C744) R^(D2) R^(D32) R^(D1)L_(C745) R^(D2) R^(D33) R^(D1) L_(C746) R^(D2) R^(D34) R^(D1) L_(C747)R^(D2) R^(D35) R^(D1) L_(C748) R^(D2) R^(D40) R^(D1) L_(C749) R^(D2)R^(D41) R^(D1) L_(C750) R^(D2) R^(D42) R^(D1) L_(C751) R^(D2) R^(D64)R^(D1) L_(C752) R^(D2) R^(D66) R^(D1) L_(C753) R^(D2) R^(D68) R^(D1)L_(C754) R^(D2) R^(D76) R^(D1) L_(C755) R^(D3) R^(D4) R^(D1) L_(C756)R^(D3) R^(D5) R^(D1) L_(C757) R^(D3) R^(D6) R^(D1) L_(C758) R^(D3)R^(D7) R^(D1) L_(C759) R^(D3) R^(D8) R^(D1) L_(C760) R^(D3) R^(D9)R^(D1) L_(C761) R^(D3) R^(D10) R^(D1) L_(C762) R^(D3) R^(D11) R^(D1)L_(C763) R^(D3) R^(D12) R^(D1) L_(C764) R^(D3) R^(D13) R^(D1) L_(C765)R^(D3) R^(D14) R^(D1) L_(C766) R^(D3) R^(D15) R^(D1) L_(C767) R^(D3)R^(D16) R^(D1) L_(C768) R^(D3) R^(D17) R^(D1) L_(C769) R^(D3) R^(D18)R^(D1) L_(C770) R^(D3) R^(D19) R^(D1) L_(C771) R^(D3) R^(D20) R^(D1)L_(C772) R^(D3) R^(D21) R^(D1) L_(C773) R^(D3) R^(D22) R^(D1) L_(C774)R^(D3) R^(D23) R^(D1) L_(C775) R^(D3) R^(D24) R^(D1) L_(C776) R^(D3)R^(D25) R^(D1) L_(C777) R^(D3) R^(D26) R^(D1) L_(C778) R^(D3) R^(D27)R^(D1) L_(C779) R^(D3) R^(D28) R^(D1) L_(C780) R^(D3) R^(D29) R^(D1)L_(C781) R^(D3) R^(D30) R^(D1) L_(C782) R^(D3) R^(D31) R^(D1) L_(C783)R^(D3) R^(D32) R^(D1) L_(C784) R^(D3) R^(D33) R^(D1) L_(C785) R^(D3)R^(D34) R^(D1) L_(C786) R^(D3) R^(D35) R^(D1) L_(C787) R^(D3) R^(D40)R^(D1) L_(C788) R^(D3) R^(D41) R^(D1) L_(C789) R^(D3) R^(D42) R^(D1)L_(C790) R^(D3) R^(D64) R^(D1) L_(C791) R^(D3) R^(D66) R^(D1) L_(C792)R^(D3) R^(D68) R^(D1) L_(C793) R^(D3) R^(D76) R^(D1) L_(C794) R^(D4)R^(D5) R^(D1) L_(C795) R^(D4) R^(D6) R^(D1) L_(C796) R^(D4) R^(D7)R^(D1) L_(C797) R^(D4) R^(D8) R^(D1) L_(C798) R^(D4) R^(D9) R^(D1)L_(C799) R^(D4) R^(D10) R^(D1) L_(C800) R^(D4) R^(D11) R^(D1) L_(C801)R^(D4) R^(D12) R^(D1) L_(C802) R^(D4) R^(D13) R^(D1) L_(C803) R^(D4)R^(D14) R^(D1) L_(C804) R^(D4) R^(D15) R^(D1) L_(C805) R^(D4) R^(D16)R^(D1) L_(C806) R^(D4) R^(D17) R^(D1) L_(C807) R^(D4) R^(D18) R^(D1)L_(C808) R^(D4) R^(D19) R^(D1) L_(C809) R^(D4) R^(D20) R^(D1) L_(C810)R^(D4) R^(D21) R^(D1) L_(C811) R^(D4) R^(D22) R^(D1) L_(C812) R^(D4)R^(D23) R^(D1) L_(C813) R^(D4) R^(D24) R^(D1) L_(C814) R^(D4) R^(D25)R^(D1) L_(C815) R^(D4) R^(D26) R^(D1) L_(C816) R^(D4) R^(D27) R^(D1)L_(C817) R^(D4) R^(D28) R^(D1) L_(C818) R^(D4) R^(D29) R^(D1) L_(C819)R^(D4) R^(D30) R^(D1) L_(C820) R^(D4) R^(D31) R^(D1) L_(C821) R^(D4)R^(D32) R^(D1) L_(C822) R^(D4) R^(D33) R^(D1) L_(C823) R^(D4) R^(D34)R^(D1) L_(C824) R^(D4) R^(D35) R^(D1) L_(C825) R^(D4) R^(D40) R^(D1)L_(C826) R^(D4) R^(D41) R^(D1) L_(C827) R^(D4) R^(D42) R^(D1) L_(C828)R^(D4) R^(D64) R^(D1) L_(C829) R^(D4) R^(D66) R^(D1) L_(C830) R^(D4)R^(D68) R^(D1) L_(C831) R^(D4) R^(D76) R^(D1) L_(C832) R^(D4) R^(D1)R^(D1) L_(C833) R^(D7) R^(D5) R^(D1) L_(C834) R^(D7) R^(D6) R^(D1)L_(C835) R^(D7) R^(D8) R^(D1) L_(C836) R^(D7) R^(D9) R^(D1) L_(C837)R^(D7) R^(D10) R^(D1) L_(C838) R^(D7) R^(D11) R^(D1) L_(C839) R^(D7)R^(D12) R^(D1) L_(C840) R^(D7) R^(D13) R^(D1) L_(C841) R^(D7) R^(D14)R^(D1) L_(C842) R^(D7) R^(D15) R^(D1) L_(C843) R^(D7) R^(D16) R^(D1)L_(C844) R^(D7) R^(D17) R^(D1) L_(C845) R^(D7) R^(D18) R^(D1) L_(C846)R^(D7) R^(D19) R^(D1) L_(C847) R^(D7) R^(D20) R^(D1) L_(C848) R^(D7)R^(D21) R^(D1) L_(C849) R^(D7) R^(D22) R^(D1) L_(C850) R^(D7) R^(D23)R^(D1) L_(C851) R^(D7) R^(D24) R^(D1) L_(C852) R^(D7) R^(D25) R^(D1)L_(C853) R^(D7) R^(D26) R^(D1) L_(C854) R^(D7) R^(D27) R^(D1) L_(C855)R^(D7) R^(D28) R^(D1) L_(C856) R^(D7) R^(D29) R^(D1) L_(C857) R^(D7)R^(D30) R^(D1) L_(C858) R^(D7) R^(D31) R^(D1) L_(C859) R^(D7) R^(D32)R^(D1) L_(C860) R^(D7) R^(D33) R^(D1) L_(C861) R^(D7) R^(D34) R^(D1)L_(C862) R^(D7) R^(D35) R^(D1) L_(C863) R^(D7) R^(D40) R^(D1) L_(C864)R^(D7) R^(D41) R^(D1) L_(C865) R^(D7) R^(D42) R^(D1) L_(C866) R^(D7)R^(D64) R^(D1) L_(C867) R^(D7) R^(D66) R^(D1) L_(C868) R^(D7) R^(D68)R^(D1) L_(C869) R^(D7) R^(D76) R^(D1) L_(C870) R^(D8) R^(D5) R^(D1)L_(C871) R^(D8) R^(D6) R^(D1) L_(C872) R^(D8) R^(D9) R^(D1) L_(C873)R^(D8) R^(D10) R^(D1) L_(C874) R^(D8) R^(D11) R^(D1) L_(C875) R^(D8)R^(D12) R^(D1) L_(C876) R^(D8) R^(D13) R^(D1) L_(C877) R^(D8) R^(D14)R^(D1) L_(C878) R^(D8) R^(D15) R^(D1) L_(C879) R^(D8) R^(D16) R^(D1)L_(C880) R^(D8) R^(D17) R^(D1) L_(C881) R^(D8) R^(D18) R^(D1) L_(C882)R^(D8) R^(D19) R^(D1) L_(C883) R^(D8) R^(D20) R^(D1) L_(C884) R^(D8)R^(D21) R^(D1) L_(C885) R^(D8) R^(D22) R^(D1) L_(C886) R^(D8) R^(D23)R^(D1) L_(C887) R^(D8) R^(D24) R^(D1) L_(C888) R^(D8) R^(D25) R^(D1)L_(C889) R^(D8) R^(D26) R^(D1) L_(C890) R^(D8) R^(D27) R^(D1) L_(C891)R^(D8) R^(D28) R^(D1) L_(C892) R^(D8) R^(D29) R^(D1) L_(C893) R^(D8)R^(D30) R^(D1) L_(C894) R^(D8) R^(D31) R^(D1) L_(C895) R^(D8) R^(D32)R^(D1) L_(C896) R^(D8) R^(D33) R^(D1) L_(C897) R^(D8) R^(D34) R^(D1)L_(C898) R^(D8) R^(D35) R^(D1) L_(C899) R^(D8) R^(D40) R^(D1) L_(C900)R^(D8) R^(D41) R^(D1) L_(C901) R^(D8) R^(D42) R^(D1) L_(C902) R^(D8)R^(D64) R^(D1) L_(C903) R^(D8) R^(D66) R^(D1) L_(C904) R^(D8) R^(D68)R^(D1) L_(C905) R^(D8) R^(D76) R^(D1) L_(C906) R^(D11) R^(D5) R^(D1)L_(C907) R^(D11) R^(D6) R^(D1) L_(C908) R^(D11) R^(D9) R^(D1) L_(C909)R^(D11) R^(D10) R^(D1) L_(C910) R^(D11) R^(D12) R^(D1) L_(C911) R^(D11)R^(D13) R^(D1) L_(C912) R^(D11) R^(D14) R^(D1) L_(C913) R^(D11) R^(D15)R^(D1) L_(C914) R^(D11) R^(D16) R^(D1) L_(C915) R^(D11) R^(D17) R^(D1)L_(C916) R^(D11) R^(D18) R^(D1) L_(C917) R^(D11) R^(D19) R^(D1) L_(C918)R^(D11) R^(D20) R^(D1) L_(C919) R^(D11) R^(D21) R^(D1) L_(C920) R^(D11)R^(D22) R^(D1) L_(C921) R^(D11) R^(D23) R^(D1) L_(C922) R^(D11) R^(D24)R^(D1) L_(C923) R^(D11) R^(D25) R^(D1) L_(C924) R^(D11) R^(D26) R^(D1)L_(C925) R^(D11) R^(D27) R^(D1) L_(C926) R^(D11) R^(D28) R^(D1) L_(C927)R^(D11) R^(D29) R^(D1) L_(C928) R^(D11) R^(D30) R^(D1) L_(C929) R^(D11)R^(D31) R^(D1) L_(C930) R^(D11) R^(D32) R^(D1) L_(C931) R^(D11) R^(D33)R^(D1) L_(C932) R^(D11) R^(D34) R^(D1) L_(C933) R^(D11) R^(D35) R^(D1)L_(C934) R^(D11) R^(D40) R^(D1) L_(C935) R^(D11) R^(D41) R^(D1) L_(C936)R^(D11) R^(D42) R^(D1) L_(C937) R^(D11) R^(D64) R^(D1) L_(C938) R^(D11)R^(D66) R^(D1) L_(C939) R^(D11) R^(D68) R^(D1) L_(C940) R^(D11) R^(D76)R^(D1) L_(C941) R^(D13) R^(D5) R^(D1) L_(C942) R^(D13) R^(D6) R^(D1)L_(C943) R^(D13) R^(D9) R^(D1) L_(C944) R^(D13) R^(D10) R^(D1) L_(C945)R^(D13) R^(D12) R^(D1) L_(C946) R^(D13) R^(D14) R^(D1) L_(C947) R^(D13)R^(D15) R^(D1) L_(C948) R^(D13) R^(D16) R^(D1) L_(C949) R^(D13) R^(D17)R^(D1) L_(C950) R^(D13) R^(D18) R^(D1) L_(C951) R^(D13) R^(D19) R^(D1)L_(C952) R^(D13) R^(D20) R^(D1) L_(C953) R^(D13) R^(D21) R^(D1) L_(C954)R^(D13) R^(D22) R^(D1) L_(C955) R^(D13) R^(D23) R^(D1) L_(C956) R^(D13)R^(D24) R^(D1) L_(C957) R^(D13) R^(D25) R^(D1) L_(C958) R^(D13) R^(D26)R^(D1) L_(C959) R^(D13) R^(D27) R^(D1) L_(C960) R^(D13) R^(D28) R^(D1)L_(C961) R^(D13) R^(D29) R^(D1) L_(C962) R^(D13) R^(D30) R^(D1) L_(C963)R^(D13) R^(D31) R^(D1) L_(C964) R^(D13) R^(D32) R^(D1) L_(C965) R^(D13)R^(D33) R^(D1) L_(C966) R^(D13) R^(D34) R^(D1) L_(C967) R^(D13) R^(D35)R^(D1) L_(C968) R^(D13) R^(D40) R^(D1) L_(C969) R^(D13) R^(D41) R^(D1)L_(C970) R^(D13) R^(D42) R^(D1) L_(C971) R^(D13) R^(D64) R^(D1) L_(C972)R^(D13) R^(D66) R^(D1) L_(C973) R^(D13) R^(D68) R^(D1) L_(C974) R^(D13)R^(D76) R^(D1) L_(C975) R^(D14) R^(D5) R^(D1) L_(C976) R^(D14) R^(D6)R^(D1) L_(C977) R^(D14) R^(D9) R^(D1) L_(C978) R^(D14) R^(D10) R^(D1)L_(C979) R^(D14) R^(D12) R^(D1) L_(C980) R^(D14) R^(D15) R^(D1) L_(C981)R^(D14) R^(D16) R^(D1) L_(C982) R^(D14) R^(D17) R^(D1) L_(C983) R^(D14)R^(D18) R^(D1) L_(C984) R^(D14) R^(D19) R^(D1) L_(C985) R^(D14) R^(D20)R^(D1) L_(C986) R^(D14) R^(D21) R^(D1) L_(C987) R^(D14) R^(D22) R^(D1)L_(C988) R^(D14) R^(D23) R^(D1) L_(C989) R^(D14) R^(D24) R^(D1) L_(C990)R^(D14) R^(D25) R^(D1) L_(C991) R^(D14) R^(D26) R^(D1) L_(C992) R^(D14)R^(D27) R^(D1) L_(C993) R^(D14) R^(D28) R^(D1) L_(C994) R^(D14) R^(D29)R^(D1) L_(C995) R^(D14) R^(D30) R^(D1) L_(C996) R^(D14) R^(D31) R^(D1)L_(C997) R^(D14) R^(D32) R^(D1) L_(C998) R^(D14) R^(D33) R^(D1) L_(C999)R^(D14) R^(D34) R^(D1) L_(C1000) R^(D14) R^(D35) R^(D1) L_(C1001)R^(D14) R^(D40) R^(D1) L_(C1002) R^(D14) R^(D41) R^(D1) L_(C1003)R^(D14) R^(D42) R^(D1) L_(C1004) R^(D14) R^(D64) R^(D1) L_(C1005)R^(D14) R^(D66) R^(D1) L_(C1006) R^(D14) R^(D68) R^(D1) L_(C1007)R^(D14) R^(D76) R^(D1) L_(C1008) R^(D22) R^(D5) R^(D1) L_(C1009) R^(D22)R^(D6) R^(D1) L_(C1010) R^(D22) R^(D9) R^(D1) L_(C1011) R^(D22) R^(D10)R^(D1) L_(C1012) R^(D22) R^(D12) R^(D1) L_(C1013) R^(D22) R^(D15) R^(D1)L_(C1014) R^(D22) R^(D16) R^(D1) L_(C1015) R^(D22) R^(D17) R^(D1)L_(C1016) R^(D22) R^(D18) R^(D1) L_(C1017) R^(D22) R^(D19) R^(D1)L_(C1018) R^(D22) R^(D20) R^(D1) L_(C1019) R^(D22) R^(D21) R^(D1)L_(C1020) R^(D22) R^(D23) R^(D1) L_(C1021) R^(D22) R^(D24) R^(D1)L_(C1022) R^(D22) R^(D25) R^(D1) L_(C1023) R^(D22) R^(D26) R^(D1)L_(C1024) R^(D22) R^(D27) R^(D1) L_(C1025) R^(D22) R^(D28) R^(D1)L_(C1026) R^(D22) R^(D29) R^(D1) L_(C1027) R^(D22) R^(D30) R^(D1)L_(C1028) R^(D22) R^(D31) R^(D1) L_(C1029) R^(D22) R^(D32) R^(D1)L_(C1030) R^(D22) R^(D33) R^(D1) L_(C1031) R^(D22) R^(D34) R^(D1)L_(C1032) R^(D22) R^(D35) R^(D1) L_(C1033) R^(D22) R^(D40) R^(D1)L_(C1034) R^(D22) R^(D41) R^(D1) L_(C1035) R^(D22) R^(D42) R^(D1)L_(C1036) R^(D22) R^(D64) R^(D1) L_(C1037) R^(D22) R^(D66) R^(D1)L_(C1038) R^(D22) R^(D68) R^(D1) L_(C1039) R^(D22) R^(D76) R^(D1)L_(C1040) R^(D26) R^(D5) R^(D1) L_(C1041) R^(D26) R^(D6) R^(D1)L_(C1042) R^(D26) R^(D9) R^(D1) L_(C1043) R^(D26) R^(D10) R^(D1)L_(C1044) R^(D26) R^(D12) R^(D1) L_(C1045) R^(D26) R^(D15) R^(D1)L_(C1046) R^(D26) R^(D16) R^(D1) L_(C1047) R^(D26) R^(D17) R^(D1)L_(C1048) R^(D26) R^(D18) R^(D1) L_(C1049) R^(D26) R^(D19) R^(D1)L_(C1050) R^(D26) R^(D20) R^(D1) L_(C1051) R^(D26) R^(D21) R^(D1)L_(C1052) R^(D26) R^(D23) R^(D1) L_(C1053) R^(D26) R^(D24) R^(D1)L_(C1054) R^(D26) R^(D25) R^(D1) L_(C1055) R^(D26) R^(D27) R^(D1)L_(C1056) R^(D26) R^(D28) R^(D1) L_(C1057) R^(D26) R^(D29) R^(D1)L_(C1058) R^(D26) R^(D30) R^(D1) L_(C1059) R^(D26) R^(D31) R^(D1)L_(C1060) R^(D26) R^(D32) R^(D1) L_(C1061) R^(D26) R^(D33) R^(D1)L_(C1062) R^(D26) R^(D34) R^(D1) L_(C1063) R^(D26) R^(D35) R^(D1)L_(C1064) R^(D26) R^(D40) R^(D1) L_(C1065) R^(D26) R^(D41) R^(D1)L_(C1066) R^(D26) R^(D42) R^(D1) L_(C1067) R^(D26) R^(D64) R^(D1)L_(C1068) R^(D26) R^(D66) R^(D1) L_(C1069) R^(D26) R^(D68) R^(D1)L_(C1070) R^(D26) R^(D76) R^(D1) L_(C1071) R^(D35) R^(D5) R^(D1)L_(C1072) R^(D35) R^(D6) R^(D1) L_(C1073) R^(D35) R^(D9) R^(D1)L_(C1074) R^(D35) R^(D10) R^(D1) L_(C1075) R^(D35) R^(D12) R^(D1)L_(C1076) R^(D35) R^(D15) R^(D1) L_(C1077) R^(D35) R^(D16) R^(D1)L_(C1078) R^(D35) R^(D17) R^(D1) L_(C1079) R^(D35) R^(D18) R^(D1)L_(C1080) R^(D35) R^(D19) R^(D1) L_(C1081) R^(D35) R^(D20) R^(D1)L_(C1082) R^(D35) R^(D21) R^(D1) L_(C1083) R^(D35) R^(D23) R^(D1)L_(C1084) R^(D35) R^(D24) R^(D1) L_(C1085) R^(D35) R^(D25) R^(D1)L_(C1086) R^(D35) R^(D27) R^(D1) L_(C1087) R^(D35) R^(D28) R^(D1)L_(C1088) R^(D35) R^(D29) R^(D1) L_(C1089) R^(D35) R^(D30) R^(D1)L_(C1090) R^(D35) R^(D31) R^(D1) L_(C1091) R^(D35) R^(D32) R^(D1)L_(C1092) R^(D35) R^(D33) R^(D1) L_(C1093) R^(D35) R^(D34) R^(D1)L_(C1094) R^(D35) R^(D40) R^(D1) L_(C1095) R^(D35) R^(D41) R^(D1)L_(C1096) R^(D35) R^(D42) R^(D1) L_(C1097) R^(D35) R^(D64) R^(D1)L_(C1098) R^(D35) R^(D66) R^(D1) L_(C1099) R^(D35) R^(D68) R^(D1)L_(C1100) R^(D35) R^(D76) R^(D1) L_(C1101) R^(D40) R^(D5) R^(D1)L_(C1102) R^(D40) R^(D6) R^(D1) L_(C1103) R^(D40) R^(D9) R^(D1)L_(C1104) R^(D40) R^(D10) R^(D1) L_(C1105) R^(D40) R^(D12) R^(D1)L_(C1106) R^(D40) R^(D15) R^(D1) L_(C1107) R^(D40) R^(D16) R^(D1)L_(C1108) R^(D40) R^(D17) R^(D1) L_(C1109) R^(D40) R^(D18) R^(D1)L_(C1110) R^(D40) R^(D19) R^(D1) L_(C1111) R^(D40) R^(D20) R^(D1)L_(C1102) R^(D40) R^(D21) R^(D1) L_(C1103) R^(D40) R^(D23) R^(D1)L_(C1104) R^(D40) R^(D24) R^(D1) L_(C1105) R^(D40) R^(D25) R^(D1)L_(C1106) R^(D40) R^(D27) R^(D1) L_(C1107) R^(D40) R^(D28) R^(D1)L_(C1118) R^(D40) R^(D29) R^(D1) L_(C1119) R^(D40) R^(D30) R^(D1)L_(C1120) R^(D40) R^(D31) R^(D1) L_(C1121) R^(D40) R^(D32) R^(D1)L_(C1122) R^(D40) R^(D33) R^(D1) L_(C1123) R^(D40) R^(D34) R^(D1)L_(C1124) R^(D40) R^(D41) R^(D1) L_(C1125) R^(D40) R^(D42) R^(D1)L_(C1126) R^(D40) R^(D64) R^(D1) L_(C1127) R^(D40) R^(D66) R^(D1)L_(C1128) R^(D40) R^(D68) R^(D1) L_(C1129) R^(D40) R^(D76) R^(D1)L_(C1130) R^(D41) R^(D5) R^(D1) L_(C1131) R^(D41) R^(D6) R^(D1)L_(C1132) R^(D41) R^(D9) R^(D1) L_(C1133) R^(D41) R^(D10) R^(D1)L_(C1134) R^(D41) R^(D12) R^(D1) L_(C1135) R^(D41) R^(D15) R^(D1)L_(C1136) R^(D41) R^(D16) R^(D1) L_(C1137) R^(D41) R^(D17) R^(D1)L_(C1138) R^(D41) R^(D18) R^(D1) L_(C1139) R^(D41) R^(D19) R^(D1)L_(C1140) R^(D41) R^(D20) R^(D1) L_(C1141) R^(D41) R^(D21) R^(D1)L_(C1142) R^(D41) R^(D23) R^(D1) L_(C1143) R^(D41) R^(D24) R^(D1)L_(C1144) R^(D41) R^(D25) R^(D1) L_(C1145) R^(D41) R^(D27) R^(D1)L_(C1146) R^(D41) R^(D28) R^(D1) L_(C1147) R^(D41) R^(D29) R^(D1)L_(C1148) R^(D41) R^(D30) R^(D1) L_(C1149) R^(D41) R^(D31) R^(D1)L_(C1150) R^(D41) R^(D32) R^(D1) L_(C1151) R^(D41) R^(D33) R^(D1)L_(C1152) R^(D41) R^(D34) R^(D1) L_(C1153) R^(D41) R^(D42) R^(D1)L_(C1154) R^(D41) R^(D64) R^(D1) L_(C1155) R^(D41) R^(D66) R^(D1)L_(C1156) R^(D41) R^(D68) R^(D1) L_(C1157) R^(D41) R^(D76) R^(D1)L_(C1158) R^(D64) R^(D5) R^(D1) L_(C1159) R^(D64) R^(D6) R^(D1)L_(C1160) R^(D64) R^(D9) R^(D1) L_(C1161) R^(D64) R^(D10) R^(D1)L_(C1162) R^(D64) R^(D12) R^(D1) L_(C1163) R^(D64) R^(D15) R^(D1)L_(C1164) R^(D64) R^(D16) R^(D1) L_(C1165) R^(D64) R^(D17) R^(D1)L_(C1166) R^(D64) R^(D18) R^(D1) L_(C1167) R^(D64) R^(D19) R^(D1)L_(C1168) R^(D64) R^(D20) R^(D1) L_(C1169) R^(D64) R^(D21) R^(D1)L_(C1170) R^(D64) R^(D23) R^(D1) L_(C1171) R^(D64) R^(D24) R^(D1)L_(C1172) R^(D64) R^(D25) R^(D1) L_(C1173) R^(D64) R^(D27) R^(D1)L_(C1174) R^(D64) R^(D28) R^(D1) L_(C1175) R^(D64) R^(D29) R^(D1)L_(C1176) R^(D64) R^(D30) R^(D1) L_(C1177) R^(D64) R^(D31) R^(D1)L_(C1178) R^(D64) R^(D32) R^(D1) L_(C1179) R^(D64) R^(D33) R^(D1)L_(C1180) R^(D64) R^(D34) R^(D1) L_(C1181) R^(D64) R^(D42) R^(D1)L_(C1182) R^(D64) R^(D64) R^(D1) L_(C1183) R^(D64) R^(D66) R^(D1)L_(C1184) R^(D64) R^(D68) R^(D1) L_(C1185) R^(D64) R^(D76) R^(D1)L_(C1186) R^(D66) R^(D5) R^(D1) L_(C1187) R^(D66) R^(D6) R^(D1)L_(C1188) R^(D66) R^(D9) R^(D1) L_(C1189) R^(D66) R^(D10) R^(D1)L_(C1190) R^(D66) R^(D12) R^(D1) L_(C1191) R^(D66) R^(D15) R^(D1)L_(C1192) R^(D66) R^(D16) R^(D1) L_(C1193) R^(D66) R^(D17) R^(D1)L_(C1194) R^(D66) R^(D18) R^(D1) L_(C1195) R^(D66) R^(D19) R^(D1)L_(C1196) R^(D66) R^(D20) R^(D1) L_(C1197) R^(D66) R^(D21) R^(D1)L_(C1198) R^(D66) R^(D23) R^(D1) L_(C1199) R^(D66) R^(D24) R^(D1)L_(C1200) R^(D66) R^(D25) R^(D1) L_(C1201) R^(D66) R^(D27) R^(D1)L_(C1202) R^(D66) R^(D28) R^(D1) L_(C1203) R^(D66) R^(D29) R^(D1)L_(C1204) R^(D66) R^(D30) R^(D1) L_(C1205) R^(D66) R^(D31) R^(D1)L_(C1206) R^(D66) R^(D32) R^(D1) L_(C1207) R^(D66) R^(D33) R^(D1)L_(C1208) R^(D66) R^(D34) R^(D1) L_(C1209) R^(D66) R^(D42) R^(D1)L_(C1210) R^(D66) R^(D68) R^(D1) L_(C1211) R^(D66) R^(D76) R^(D1)L_(C1212) R^(D68) R^(D5) R^(D1) L_(C1213) R^(D68) R^(D6) R^(D1)L_(C1214) R^(D68) R^(D9) R^(D1) L_(C1215) R^(D68) R^(D10) R^(D1)L_(C1216) R^(D68) R^(D12) R^(D1) L_(C1217) R^(D68) R^(D15) R^(D1)L_(C1218) R^(D68) R^(D16) R^(D1) L_(C1219) R^(D68) R^(D17) R^(D1)L_(C1220) R^(D68) R^(D18) R^(D1) L_(C1221) R^(D68) R^(D19) R^(D1)L_(C1222) R^(D68) R^(D20) R^(D1) L_(C1223) R^(D68) R^(D21) R^(D1)L_(C1224) R^(D68) R^(D23) R^(D1) L_(C1225) R^(D68) R^(D24) R^(D1)L_(C1226) R^(D68) R^(D25) R^(D1) L_(C1227) R^(D68) R^(D27) R^(D1)L_(C1228) R^(D68) R^(D28) R^(D1) L_(C1229) R^(D68) R^(D29) R^(D1)L_(C1230) R^(D68) R^(D30) R^(D1) L_(C1231) R^(D68) R^(D31) R^(D1)L_(C1232) R^(D68) R^(D32) R^(D1) L_(C1233) R^(D68) R^(D33) R^(D1)L_(C1234) R^(D68) R^(D34) R^(D1) L_(C1235) R^(D68) R^(D42) R^(D1)L_(C1236) R^(D68) R^(D76) R^(D1) L_(C1237) R^(D76) R^(D5) R^(D1)L_(C1238) R^(D76) R^(D6) R^(D1) L_(C1239) R^(D76) R^(D9) R^(D1)L_(C1240) R^(D76) R^(D10) R^(D1) L_(C1241) R^(D76) R^(D12) R^(D1)L_(C1242) R^(D76) R^(D15) R^(D1) L_(C1243) R^(D76) R^(D16) R^(D1)L_(C1244) R^(D76) R^(D17) R^(D1) L_(C1245) R^(D76) R^(D18) R^(D1)L_(C1246) R^(D76) R^(D19) R^(D1) L_(C1247) R^(D76) R^(D20) R^(D1)L_(C1248) R^(D76) R^(D21) R^(D1) L_(C1249) R^(D76) R^(D23) R^(D1)L_(C1250) R^(D76) R^(D24) R^(D1) L_(C1251) R^(D76) R^(D25) R^(D1)L_(C1252) R^(D76) R^(D27) R^(D1) L_(C1253) R^(D76) R^(D28) R^(D1)L_(C1254) R^(D76) R^(D29) R^(D1) L_(C1255) R^(D76) R^(D30) R^(D1)L_(C1256) R^(D76) R^(D31) R^(D1) L_(C1257) R^(D76) R^(D32) R^(D1)L_(C1258) R^(D76) R^(D33) R^(D1) L_(C1259) R^(D76) R^(D34) R^(D1)L_(C1260) R^(D76) R^(D42) R^(D1)

wherein R to R have the following structures:


11. The compound of claim 1, wherein the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) wherein L_(B) and L_(C) are each abidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0,1, or 2; and x+y+z is the oxidation state of the metal M.
 12. Thecompound of claim 11, wherein L_(B) and L_(C) are each independentlyselected from the group consisting of:

wherein each Y¹ to Y¹³ are independently selected from the groupconsisting of carbon and nitrogen; wherein Y′ is selected from the groupconsisting of B R_(e), N R_(e), P R_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); wherein R_(e) and R_(f) areoptionally fused or joined to form a ring; wherein each R_(e) and R_(f)is independently selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof; wherein each R_(a), R_(b), R_(e), and R_(d) mayindependently represent from mono substitution to the maximum possiblenumber of substitution, or no substitution; wherein each R_(a), R_(b),R_(c), and R_(d) is independently hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl,carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, and combinations thereof; and wherein any twoadjacent substituents of R_(a), R_(b), R_(c), and R_(d) are optionallyfused or joined to form a ring or form a multidentate ligand.
 13. Thecompound of claim 1, wherein the compound has the formula:

wherein rings E and F each independently represents a 5-membered or6-membered carbocyclic or heterocyclic ring; wherein R^(E) and R^(F)each independently represents mono to the maximum possible number ofsubstitutions, or no substitution; wherein m₁, m₂, and m₃ are eachindependently an integer of 0 or 1; when m₂ is 0, both m₁ and m₃ are 1;when m₂ is 1, each m₁ and m₃ independently can be 0 or 1; wherein whenm₁ is 0, L¹ is not present; when m₂ is 0, L² is not present; when m₃ is0, L³ is not present; wherein L¹, L², and L³ are each independentlyselected from the group consisting of a direct bond, BR, NR, PR, O, S,Se, C═O, S═O, SO₂, CRR′, SiRR′, GeRR′, alkyl, cycloalkyl, andcombinations thereof; wherein R^(E) and R^(F) are each independentlyhydrogen or a substituent selected from the group consisting ofdeuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof; wherein R and R′ are each independently selectedfrom the group consisting of hydrogen, deuterium, halogen, alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile,sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; andwherein any adjacent R^(E), R^(F), R, and R′ can be joined to form aring.
 14. The compound of claim 13, wherein the compound has theformula:

wherein R^(G) is selected from the group consisting of alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl,partially or fully deuterated variants thereof, partially or fullyfluorinated variants thereof, and combinations thereof.
 15. The compoundof claim 13, wherein the compound has the formula selected from thegroup consisting of:


16. An organic light emitting device (OLED) comprising: an anode; acathode; and an organic layer, disposed between the anode and thecathode, comprising a compound comprising a first ligand L_(A) ofFormula I

wherein X¹-X⁸ are each independently C or N; wherein no more than two Natoms are bonded to each other; wherein at least one pair of X¹ and X²,X² and X³, X⁶ and X⁷, or X⁷ and X⁸ is C—C, and is joined to a structureG of Formula II

wherein A is selected from the group consisting of C(CH₃)₂, O, S, Se,and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution; wherein each R^(A), R^(B), R^(C), R^(D), and R′ isindependently hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof; wherein any two substituents may bejoined or fused together to form an aromatic ring; wherein L_(A) iscomplexed to a metal M; wherein M is optionally coordinated to otherligands; wherein the ligand LA is optionally linked with other ligandsto comprise a tridentate, tetradentate, pentadentate, or hexadentateligand.
 17. The OLED of claim 16, wherein the organic layer is anemissive layer and the compound is an emissive dopant or a non-emissivedopant.
 18. The OLED of claim 16, wherein the organic layer furthercomprises a host, wherein the host comprises at least one chemical groupselected from the group consisting of triphenylene, carbazole,dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene,azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, andaza-dibenzoselenophene.
 19. The OLED of claim 18, wherein the host isselected from the group consisting of:

and combinations thereof.
 20. A consumer product comprising an organiclight-emitting device comprising: an anode; a cathode; and an organiclayer, disposed between the anode and the cathode, comprising a compoundcomprising a first ligand LA of Formula I

wherein X¹-X⁸ are each independently C or N; wherein no more than two Natoms are bonded to each other; wherein at least one pair of X¹ and X²,X² and X³, X⁶ and X⁷, or X⁷ and X⁸ is C—C, and is joined to a structureG of Formula II

wherein A is selected from the group consisting of C(CH₃)₂, O, S, Se,and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independentlyrepresents mono to the maximum number of allowable substitutions, or nosubstitution; wherein each R_(A), R^(B), R^(C), R^(D), and R′ isindependently hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof; wherein any two substituents may bejoined or fused together to form an aromatic ring; wherein L_(A) iscomplexed to a metal M; wherein M is optionally coordinated to otherligands; wherein the ligand L_(A) is optionally linked with otherligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand.